Manual Ultra Clear plus Rev.: 090722 Subject to alternations Catalogue No.: 2 0 0 3 SG Wasseraufbereitung und Regenerierstation GmbH Fahrenberg 8 * 22885 Barsbüttel Germany Tel.: +49(0)40/670868-6 * Fax: +49(0)40/670868-44 www.sgwater.de
Table of Contents 1 General...1 1.1 About this user manual... 1 1.2 Symbols used in this manual... 1 1.3 Liability and warranty... 2 1.4 Copyright... 2 1.5 Spare parts... 2 1.6 Disposal... 3 2 Safety...3 2.1 Intended use... 3 2.2 Contents of this manual... 3 2.3 Changes and modifications to the equipment... 4 2.4 User responsibility... 4 2.5 Personnel requirements... 4 2.6 Health and safety at work... 5 2.7 Personal protective equipment (PPE)... 5 2.8 Potential hazards... 5 3 System Features...6 3.1 Water Purification Process... 7 4 Installation and Start Up...8 4.1 Delivered parts... 8 4.2 Feed Water Requirements... 9 4.3 Pretreatment methods for the feed water... 9 4.4 Installation - Sealing Plugs... 10 4.5 Installation - Connections... 10 4.6 Disinfectant Filling... 11 4.7 Installation - Sterile filter and first module attachment... 11 4.8 Installation - disinfectant flushing... 12 4.9 Installation - Second module attachment... 12 5 System control...13 5.1 Display and function keys... 13 5.2 Flushing... 13 5.3 Operation... 14 5.4 Start Selection Screen Main Menu... 14 5.5 Main menu Settings... 15 5.6 Main Menu Settings Interval Mode... 18 5.7 Main Menu Maintenance... 21 5.8 Main Menu Maintenance Disinfection Procedure... 22 Content
6 Error Messages...26 6.1 Troubles and Corrections... 27 7 Maintenance and Servicing...28 7.1 Interval... 28 7.2 System Setting table... 28 7.3 Disinfection of the System... 28 7.4 Sterile Filter Disinfection and Replacement... 29 7.5 Replacement of the modules... 30 7.6 Ultra-filtration Module Replacement... 31 7.7 Contrast Adjustment... 32 8 Technical Data...33 8.1 Feed Water Requirements... 33 8.2 System Data... 33 9 Appendix... I 9.1 Flow Chart...I 9.2 Circuit Diagram... II 9.3 Consumables and spare parts... III 9.4 Disinfectant Safety Data Sheet...IV Content
1 General 1.1 About this user manual This user manual describes how to use the equipment safely and correctly. When operating this equipment, it is essential that the user adhere to the safety instructions and operating instructions, the local accident prevention regulations and general safety regulations. Before using the equipment, the user must read the user manual, particularly the section on safety and the relevant safety warnings. The user must fully understand the instructions before proceeding. The user manual is a part of the equipment. It must be kept close to the equipment and be accessible at any time for all users. Should the equipment be passed on to a third party, the manual must also be passed on to the third party. 1.2 Symbols used in this manual Issues relevant to safety are characterized in this manual according to the following symbols. These warnings must be observed in order to operate the equipment safely and avoid accidents, damage or injury. WARNING! Risk of serious or fatal injury! This symbol alerts the user to potential sources of hazards to health, injuries or fatal injuries. Do not operate the equipment until you have completely understood the instructions and proceed accordingly. WARNING! Risk of electric shock! This symbol alerts the user to the presence of uninsulated voltage that has the potential to cause serious or even fatal injuries. Do not operate the equipment until you have completely understood the instructions and proceed accordingly. All maintenance work must be performed by qualified service personnel. IMPORTANT! This symbol alerts the user to potential sources of malfunctions or damage to the equipment if operated improperly. Note! This symbol alerts the user to advice on efficient und trouble-free operation. General Page 1 of 33
1.3 Liability and warranty With the benefit of many years of experience and expertise, this user manual and all the facts and instructions in it have been written taking current legislation, state-of-the-art technology into account. The user manual must be kept close to the equipment and available at all times for anyone intending to use the equipment. The user manual must be read before any work is carried out using the equipment! The manufacturer does not accept liability for damage or faults that arise due to disregard for the instructions in the manual. The text and diagrams depicted in this manual do not necessarily match the equipment you have received. The diagrams and images are not on a scale of 1:1. The equipment delivered to you may be slightly different to the equipment described and depicted here due to specialized features, additional options or due to changes in technology. If you have any queries, please contact the manufacturer. We reserve the right to make technical changes to product and further develop it in order to improve its functionality. 1.4 Copyright This manual must be treated as a confidential document. It is only intended for use by those operating the equipment. All contents of this manual text, diagrams, images etc. are protected by copyright law and industrial property rights. Anyone found violating these rights will be prosecuted. The manual may not be passed on to third parties, copied either in part or whole or used for any other purpose without the express and written consent of the manufacturers. Anyone found violating these copyright laws must pay compensation. The manufacturer may also prosecute. We reserve the right to exercise all industrial protection rights. 1.5 Spare parts Only use original spare parts supplied by the manufacturer. IMPORTANT! The wrong or faulty spare parts can lead to damage, malfunction or a complete breakdown of the equipment. All guarantee, service, damages and third party liability claims against the manufacturer, the manufacturer s representatives and dealers become null and void once unauthorized spare parts are used in the equipment. General Page 2 of 33
1.6 Disposal If no return or disposal contract has been agreed on, please dispose of the disassembled components as follows: Recycle scrap metal parts, Recycle plastic parts, Dispose of other components according to the material. IMPORTANT! Electrical and electronic scrap and components, lubricants and other process materials must be treated as hazardous waste and can only be disposed of by authorized waste disposal facilities. 2 Safety At the time this equipment was developed and produced, it complied with the current state-of-the-art technology and is accepted as reliable and safe. The equipment can represent a hazard if it is not operated by untrained personnel, if operated improperly or not according to the manual. The section on safety provides an overview of all the important issues relevant to personal safety and safe and trouble-free operation. The other sections of the manual also contain specific safety warnings and warning symbols that highlight the possible hazards. Please also comply with the pictograms, signs, markings and inscriptions on the equipment. These may not be removed and must always be visible. 2.1 Intended use The equipment is only safe if operated as intended by this manual. IMPORTANT! Any form of use or operation other than the intended use is improper and prohibited. Claims of any kind made against the manufacturer or the manufacturer s representatives are null and void if the equipment is not operated as intended. The operating company is liable for all damages caused by improper use. The intended use is described in the manual and includes compliance with the operating conditions. The equipment may only be operated together with the parts supplied. 2.2 Contents of this manual Anyone intending to work with or use the equipment must read and understand the user manual before operating the equipment. This also applies if the user has already operated similar equipment or devices of a similar nature or has been trained by the manufacturer. Reading and understanding the manual is the only way to protect against hazards, prevent mistakes and operate the equipment safely and trouble-free. Safety Page 3 of 33
We recommend that the operating company obtain written confirmation from each user that he/she has read and understood the manual. 2.3 Changes and modifications to the equipment In order to avoid hazards and ensure that the equipment operates at its best, do not make any changes or modifications to the equipment that have not been expressly authorized by the manufacturer. Ensure that all pictograms, signs, markings and inscriptions on the equipment are always be visible and never removed. Damaged, missing or illegible pictograms, signs, markings and inscriptions must be replaced immediately. 2.4 User responsibility The user manual must be kept close to the equipment and available at all times for anyone intending to use the equipment. The equipment may only be operated in a technically flawless and safe state. The equipment must be checked for damage before each start-up. The instructions in the manual must be followed completely and without restriction! When operating this equipment, it is essential that the user adhere to the safety instructions and operating instructions, the local accident prevention regulations, general safety regulations and the relevant environmental protection legislation. The operating company and the authorized personnel within that company are responsible for operating the equipment trouble-free and must define who is responsible for installing, operating, servicing and cleaning the equipment. 2.5 Personnel requirements Only authorized and trained personnel are allowed to operate the equipment. The user must have been instructed about the potential hazards involved in using the equipment. Authorized personnel are persons who sufficient training, knowledge, experience and understanding of the relevant regulations to be able to assess the task given to him/her and identify potential hazards. If a potential user does not have sufficient knowledge at his/her disposal, this person must be trained/qualified. It must be clear who is responsible for equipment installation, operation, maintenance and servicing. These competencies must be clearly defined and conformed to in order to prevent any uncertainties that may compromise safety. Only reliable personnel may work with and operate the equipment. Do not allow anyone to operate the equipment in a way that compromises the safety of others or the environment or damages the equipment. No one under the influence of drugs, alcohol or medication that impairs the ability to respond/react is allowed to operate the equipment. Please consider all other directives related to age and qualification when selecting potential users. The user must ensure that other, unauthorized personnel keep a safe distance from the equipment. Safety Page 4 of 33
Personnel must report to the operating company immediately if any changes become apparent which may impair the safe operation of the equipment. 2.6 Health and safety at work Follow the safety and operating instructions given in this manual in order to avoid causing harm or damage to persons and property while working with and on the equipment. If these instructions are not observed, the equipment may become damaged or destroyed or may harm persons. The manufacturer is not liable for third party damages or compensation if the safety and operating instructions in this manual or the local accident prevention regulations and general safety regulations are not observed. 2.7 Personal protective equipment (PPE) When working with this equipment, please wear goggles or another form of protective eyewear. 2.8 Potential hazards This equipment has been subjected to a risk analysis. The subsequent equipment design and execution corresponds to state-of-the-art technology. The equipment is safe for use, provided it is operated as intended. A minimal residual risk cannot be eliminated completely. The equipment is run at high electrical voltage. WARNING! Risk of electric shock! Electrical energy in the equipment can lead to serious injuries. The equipment presents a danger to life if the insulation or individual components become damaged. Switch off the main power switch before carrying out maintenance, cleaning or repair work and and ensure that it cannot be switched on again while carrying out this work. Eliminate all voltage from the equipment when working on the electrical equipment. Do not remove or deactivate any safety equipment. The manufacturer does not take any responsibility for injuries to third parties caused by improper use of the system. Safety Page 5 of 33
3 System Features This system is designed for the production of analytical grade, pyrogens free water out of Permeate from a Reverse-Osmosis or out of deionized feed water. The Ultra-Pure Water will be produced with purification modules, Ultra-filtration and Sterile filter. Product water will be supplied with the dispenser at the front side, which can be opened for small volumes, for permanent outlet, or volume controlled outlet. If no water is supplied, it circulates inside the system to deliver Ultra-Pure Water in permanent best quality. The product water can be drawn off up to 2 liter per minute. Typical characteristics are: Conductivity 0.055 µs/cm / resistivity 18.2 MΩ-cm, TOC (total organic carbon) concentration between 5...10 ppb, bacteria less than 1 cfu/ml, endotoxins less than 0.001 EU/ml and less than 1 particle per ml above 0.1 µm. Currently recorded data and warning messages are displayed on the system monitor. All components of the system are assembled in a designed plastic housing, which can be used either as bench device or wall mounted. The front door can easily be opened for the access of the modules. The system corresponds to the latest technology and to recent safety regulations. It can be installed and put into operation without the help of service engineers. Dispenser Monitor and function keys Purification modules Sterile filter Front view Opened front door System Features Page 6 of 33
3.1 Water Purification Process The process flow with all components is illustrated on the flow sheet, see the appendix. System parameters can be adjusted within the system control menu. When the system is started in operation mode, the inlet valve (V4.1) opens and the circulation pump (P4.1) starts to feed water into the system. When the system is switched off, the pump stops and inlet valve closes. The flow transmitter (FT4.1) monitors the flow rate into the system. The first purification module (F4.1) will be used to reduce the salt content of the feed water. For inorganic applications the VMD module can be chosen, for organic applications with low TOC values the DTO module is recommended. The conductivity of deionized water is monitored with a sensor (QIA+ Q1) and indicated with value Q1. If the conductivity exceeds the adjusted limit, a warning message will be displayed on the system monitor. The circulation pump (P4.1) feeds the water to the Dispenser (V4.3) and into purification circulation, if no water is used. The second purification module (F4.2) extracts last salt contents, particles and organics out of the water. For inorganic applications the ILT module can be chosen. It is filled with high grade mixed bed resins in semiconductor quality to reduce mainly the salt content out the water. For organic applications with low TOC values the MF-III-D module is recommended which is filled with the same resin to reduce the salt content and a special activated carbon to remove organics and particles out of the water. To wash impurities out of this module, it can be rinsed out with a flushing program. To wash impurities out of this module, it can be rinsed out with a flushing program. Then the solenoid valve (V4.6) opens to drain the contaminated water. The Ultra-filtration module (F4.4) removes Endotoxins, Pyrogens and viruses out of the water. This module will be flushed automatically every 12 hours for a short moment to wash out impurities. The flushing valve (V4.5) opens to drain the contaminated water. A manual flushing program can be started within the maintenance menu. The product water conductivity is monitored with a sensor (QIA+ Q2) and indicated with value Q2. If the conductivity exceeds the adjusted limit, a warning message will be displayed on the system monitor. A sensor (TA+ 4.1) monitors the temperature of the product water. If the temperature exceeds the set point, the outlet valve (V4.5) opens in interval to drain the overheated water and to reduce the temperature. The sterile filter (F4.3) protects the system against germs formation. Bacteria and germs over 0.1 microns are filtered out of the water. Product water will be supplied with the dispenser at the front side of the system. For a small volume of product water the dispenser button has to be pressed slightly, for a higher volume the dispenser can be switched into permanent position. A defined volume of product water can be supplied using the volume operation. If no product water is supplied, it circulates inside the system for a permanent cleaning to deliver Ultra-Pure Water in best quality. For an economic use the system can be operated in interval mode. In this mode 2 separate intervals or day/ night operation can be selected. System Features Page 7 of 33
4 Installation and Start Up 4.1 Delivered parts 1 x Ultra Clear System 1 x VMD (Art. Nr.: 2050 1 x DTO (Art. Nr.: 2094 1 x MFIIID (Art. Nr.: 2051 1 x ILT (Art. Nr.: 2092 1 x Connector ¼ Art. Nr.: 04861-2 1 x Connector 5 / 16 Art. Nr.: 04983-2 1 x Disinfection tube (Art. Nr.: 20007) 1 x Tap adapter ¾ ½ (Art. Nr.: 06843) 1x Sterile Filter (Art. Nr.: 2052) 1 x Tube blue 5 / 16 with ¾ union nut (Art. Nr.: 08635-1) 1 x Netzkabel / Power cabel 1 x D Art. Nr.::70033 1 x,ch Art. 80703 1 x UK: Art 80704 1 x USA Art: 80705 1 x Flushing tube 1/ 4 (Art.-Nr.: 02577-2 Installation and Start Up Page 8 of 33
4.2 Feed Water Requirements The feed water must be pre-treated and has to fulfill the following specifications: Feed pressure bar 0.1 5 Conductivity µs/cm < 20 TOC ppb < 50 4.3 Pretreatment methods for the feed water Pre-treatment with one or two deionizers Ultra Clear Deionizer Conductivity meter Deionizer Pre-treatment with Reverse-Osmosis system euro system Storage tank Ultra Clear Pre-treatment with Reverse-Osmosis system and the deionizer in series euro system Storage tank Deionizer Conductivity meter Ultra Clear Installation and Start Up Page 9 of 33
4.4 Installation - Sealing Plugs To loosen the plugs, slightly depress the fastening ring. Sealing ring Depress the sealing ring Pull out the sealing plug 4.5 Installation - Connections Remove sealing plugs after depressing the fastening ring. Caution: Disinfectant may leak out! IMPORTANT! Plug in the tubes to their stop positions. Connect the power cable to the mains. The flushing tube must slope downwards toward the waste water disposal. To prevent damage to the system, do not allow anything to reduce the tube diameter, remove loops and siphons and avoid bends in the tubes. A minimum safety distance of 2 cm (equal to more than twice the tube inside diameter) is required between the end of the outlet tube and the waste water disposal inlet. Feed water (in) Power supply (in) Rear view Flushing (out) Installation and Start Up Page 10 of 33
4.6 Disinfectant Filling The system is delivered with a disinfectant solution filling! Attention! The disinfection tube is attached on the position of the MF-III-D module. Before normal operation the disinfectant must be rinsed out! Safety precautions in handling with the disinfection solution have to be observed. For the safety data sheet see the appendix! 4.7 Installation - Sterile filter and first module attachment VMD/ DTO module Couplers Sterile filter Disinfectant syringe connector Disinfection tube Couplers Open the front panel. Plug the couplers into the sterile filter connectors until they audibly snap into place. The arrow on the sterile filter must point in the same direction as the arrow on the device housing. Attach the filter with fastener. Plug the couplers into the VMD/ DTO module connectors until they audibly snap into place. Insert the module into holder. Installation and Start Up Page 11 of 33
4.8 Installation - disinfectant flushing IMPORTANT! The system has been delivered with a disinfectant solution filling! The disinfectant must be rinsed out before beginning normal operation and before inserting the MF-III-D/ ILT module! Observe the safety precautions (see safety data sheet in appendix) when handling the disinfection solution. Turn on water supply and start the system using the ON key. Use the function keys to enter the disinfection program (see chapter on disinfection: Main menu maintenance disinfection) Execute the step-by-step disinfection program without a new disinfectant, as described in the chapter on disinfection, until the program is finished and the disinfectant has been rinsed out. Return to this sub menu. Stop the system using the OFF key Briefly open the dispenser over the drain to reduce the pressure. Unplug the disinfectant tube. 4.9 Installation - Second module attachment Plug the couplers into the MF-III-D/ ILT module connectors until they audibly snap into place. Start the system using the ON key. Select Flush in the menu to briefly flush out the modules. Confirm to start normal operation after flushing. Open the sterile filter screw and the dispenser until pure water flows out to de-aerate the system. Check for leaks at all connection points. Close the front panel. System is ready for use. After installation, after changing modules or after a few days Note! switched off (e.g. at weekends), start the flush program as described above. If conductivity does not reach ultra pure water quality after installation or changing a module, allow the resin in the modules to swell up in order to reach full capacity. Installation and Start Up Page 12 of 33
5 System control 5.1 Display and function keys Display of device type, Serial Number and control version Function keys ON : System Start and Error Reset : Selection and number input ENTER: Confirmation : Selection and number input Menu : Menu selection and superior menu OFF : Switch OFF key (Attention: the system is still power connected) 5.2 Flushing Flush Confirmation starts the flushing program to wash out impurities. This program should be used after installation, after replacement of cartridges or after a system stop for several days. The flushing time can individually be chosen. Press ENTER to confirm the program, to confirm the time and to start the flushing. Flushing Time Choose a flushing time with the arrow keys (e.g. 60 seconds) and confirm with ENTER. Flushing Display Display of the remaining flushing time. System control Page 13 of 33
5.3 Operation Operation Confirmation starts the Normal Operation display Normal Operation Display Q1: DI-water conductivity or resistivity [µs/cm or MΩ-cm] Q2. Ultra-Pure Water conductivity or resistivity [µs/cm or MΩ-cm] Temp: Water temperature Note: Parameter for each row and water quality unit can be chosen within the main menu settings 5.4 Start Selection Screen Main Menu ON Start selection screen Main Menu Confirmation starts the main menu Main Menu Settings: System configuration and interval mode settings Maintenance: Disinfection, Ultra-Filtration flushing, operation counter Service: Technical service configuration System control Page 14 of 33
5.5 Main menu Settings Items Parameter settings for the system, display, and interval-mode Language German English Date Input of the date: month / day / year (MM/DD/YY) Time Input of the time: hours : minutes (hh:mm) µs/cm MΩ-cm Display Selection of the water quality unit (conductivity / resistivity) conductivity unit: µs/cm resistivity unit: MΩ-cm Temperature compensation Compensation of temperature variations and display of the compensated temperature for 25 C automatic compensation compensation off System control Page 15 of 33
5.5 Main menu Settings Quality Q1 Conductivity limit for an alarm message on the screen Quality Q1 Critical Value Input of the conductivity limit. The measuring range depends on the settings. If this limit is exceeded, the alarm Values exceeded will be displayed. Main Menu Settings Temperature Limit of the temperature with alarm message Limit of the temperature with product water drainage (flushing valve will be opened and product water will be drained) Main Menu Settings Temperature Alarm Input of the temperature limit for an alarm message. If this limit is exceeded, the alarm Values exceed will be displayed. Main Menu Settings Temperature Drainage Input of the temperature limit for the drainage. If this limit is exceeded, the flushing valve will be opened and product water will be drained, until the temperature is in the limit again. After reaching normal temperature, the valve will be closed delayed. Main Menu Settings Main display Parameter selection for each row displayed in normal operation Main Menu Settings Main display Row 1 3 Parameter selection for row 1 Q1: Permeate Water quality Q2: Deionized Water quality Q3: Ultra Pure water quality Temp: Temperature Inactive System control Page 16 of 33
5.5 Main menu Settings Main Menu Settings 24hrs. Operation (Interval-mode) The pump/uv-oxidizer can be operated with: 2 separate interval periods Each period with permanent day operation and without night operation Each period with individual day and night settings Day and night operation with pauses, while the pump/uv is stopped ( see chapter 5.7 Main Menu Settings Interval Mode ) Main Menu Settings Data Port Selection of the data output signal Signal for PC connection Signal for printer connection Main Menu Settings Data Port Printer Period of the data output for the printer Main Menu Settings Data Port Printer Interval Input of the period in minutes System control Page 17 of 33
5.6 Main Menu Settings Interval Mode Main Menu Settings 24hrs. Operation (Interval-mode) Interval settings for 2 interval periods Example: 1 st Interval: Working week Permanent operation from Monday to Friday, each day from 08:00 17:00 o clock, stopped pump/uv 17:00 08:00 o clock 2 nd Interval: Weekend: Saturday and Sunday without pump/uv operation Main Menu Settings 24hrs. Operation Week day 1 Display of the days from Sunday to Saturday. Input of the number 1 for the first interval period Example: 1 st Interval, Working Week Selection of Monday to Friday Main Menu Settings 24hrs. Operation Start Time 1 Input of the Day time - start moment Example: 1 st Interval, Working Week Selection of 08:00 o clock Main Menu Settings 24hrs. Operation Finish Time 1 Input of the Day time - end Example: 1 st Interval, Working Week Selection of 17:00 o clock Main Menu Settings 24hrs. Operation Interval 1 Interval mode Operation (days and nights), pump/uv is running Pauses (days and nights), pump/uv is stopped System control Page 18 of 33
5.6 Main Menu Settings Interval Mode Main Menu Settings 24hrs. Operation Interval 1 Mode Selection of the mode for the first interval period: Permanent operation during the selected day time without night operation Interval operation with individual day and night settings Example: 1 st Interval, Working Week Selection of permanent operation Main Menu Settings 24hrs. Operation Interval 1 Day Operation Input of the period in minutes for normal operation during the days, valid in case of interval operation mode, pump/uv is switched on. Main Menu Settings 24hrs. Operation Interval 1 Day Pauses Input of the period in minutes for pauses during the days, valid in case of interval operation mode, pump/uv is switched off. Main Menu Settings 24hrs. Operation Interval 1 Night Operation Input of the period in minutes for normal operation during the nights, valid in case of interval operation mode, pump/uv is switched on. Main Menu Settings 24hrs. Operation Interval 1 Night Pauses Input of the period in minutes for pauses during the nights, valid in case of interval operation mode, pump/uv is switched off. Main Menu Settings 24hrs. Operation Week Day 2 Display of the days from Sunday to Saturday. Input of the number 1 for the second interval period Example: 2 nd Interval, Weekend Selection of Saturday and Sunday System control Page 19 of 33
5.6 Main Menu Settings Interval Mode Main Menu Settings 24hrs. Operation Start Time 2 Input of the Day time - start moment Example: 2 nd Interval, Weekend Selection of 00:00 o clock Main Menu Settings 24hrs. Operation Finish Time 1 Input of the Day time - end Example: 2 nd Interval, Weekend Selection of 00:00 o clock Main Menu Settings 24hrs. Operation Interval 1 Selection of the mode for the second interval period: Permanent operation during the selected day time without night operation Interval operation with individual day and night settings Example: 2 nd Interval, Weekend Selection of Permanent Operation, day time is set to ZERO, pump/uv is stopped all time System control Page 20 of 33
5.7 Main Menu Maintenance Maintenance Confirmation starts the maintenance menu Items Disinfection: Step-by-step instruction for disinfection procedure UF module rinse: Intensive flushing of the Ultra-filtration module Op.hours: Display and reset of the operating hours Disinfection Start Confirmation starts the disinfection procedure, described next paragraph. Note: The disinfection procedure can be stopped with the MENU function key UF Module rinse Confirmation starts a manual flushing program for the Ultra- Filtration module. This program should be used for an intensive cleaning. The time can be selected at the next menu item. Note: The Ultra-Filtration module is rinsed automatically all 12 hours Main Menu Maintenance UF Module flushing time Input of the flushing time in seconds Flushing Display Display of the remaining seconds during the flushing System control Page 21 of 33
5.7 Main Menu Maintenance Main Menu Maintenance UV-Oxidizer reset Display of the operation hours Note: After replacement of the UV-Oxidizer the operation counter has to be reset Main Menu Maintenance UV-Oxidizer password For reset the user password 1111 has to be entered Main Menu Maintenance UV-Oxidizer reset confirmation Confirmation of the reset 5.8 Main Menu Maintenance Disinfection Procedure Main Menu Maintenance Disinfection Confirmation starts a step-by-step procedure for the system disinfection. Auxiliaries: 2 litre cup Disinfection tube SG disinfection syringes with special disinfectant solution Attention: Safety precaution advises of the disinfectant safety data sheet have to be observed! The disinfection procedure can be stopped with the MENU function key. Main Menu Maintenance Disinfection Start Confirmation starts the disinfection procedure. Note: The disinfection procedure can be stopped with the MENU function key System control Page 22 of 33
5.7 Main Menu Maintenance 1. Open Dispenser Hang the dispenser into the cup Open the dispenser in permanent position 2. Remove the right cartridge (MF-III-D Module) The disinfection tube has to be connected with the couplers of the MF- III-D module ILT/ MF-III-D module Remove the couplers from the right cartridge (MF-III-D Module), Plug the couplers of the cartridge in the disinfection tube sockets (Attention: the couplers have to snap in) Socket Socket coupler Injection opening with protective cap coupler 3. Connect the disinfection syringe 4. Inject the disinfectant solution Remove the protection cap of disinfection syringe and disinfection tube, screw the disinfection syringe on the injection opening System control Page 23 of 33
5.7 Main Menu Maintenance 5. - Finishing Injection Remove the syringe Close injection opening with protection cap Close the dispenser and hang it into the holder 6. Confirm the disinfection start 7. Circulation time and reaction time are displayed 8. Finished disinfection is displayed 9. Disinfectant flushing Confirm the clear water flushing with ENTER Open the dispenser for approx. 1 minute Close the dispenser and hang it into the holder 10. Remaining flushing time is displayed During the flushing process the system will be rinsed out with clear water, which is drained automatically by the flushing valve. 11. Finishing the flushing process Finally the dispenser has to be flushed again: Confirm the clear water flushing with ENTER The system control automatically leaves the disinfection menu without displaying the remaining time Open the dispenser for approx. 1 minute Close the dispenser and hang it into the holder System control Page 24 of 33
5.7 Main Menu Maintenance 12. End of Disinfection Procedure Stop the system with the OFF function key For pressure reduction open the dispenser for a short moment Remove the couplers from the disinfection tube Attach the couplers to the MF-III-D module (Attention: the couplers have to snap in) Start the system with the ON function key Move to the flushing program within the start selection screen Confirm the flushing After the flushing the system automatically turns into normal operation Check for impermeability System is ready System control Page 25 of 33
6 Error Messages Warning 1: Conductivity Q1 limit exceeded Check of limit Q1 settings Check of and correct feed water quality Check of VMD module Error reset with ON function key Warning 2 Conductivity Q2 limit exceeded Check of limit Q2 settings Replace the ILT/ MF-III-D module Error reset with ON function key Warning 5 Maximum temperature limit exceeded, product water will be drained Check of the temperature limit Check of ambient and system temperature Install a cooling system water to drain Error reset with ON function key Warning 6 Lower temperature limit exceeded, the system turns into interval mode Check of the temperature limit Check of ambient and system temperature Install a cooling system Error reset with ON function key Warning message Error 7; UV-lamp, Replace UV-lamp Maximum operation time of the UV-lamp has been reached The oxidizer s UV-lamp and external UV-lamp has to be replaced. Warning 10 The tank is empty, Ultra Pure Water production will be stopped. The circulation pump stops Wait for tank filling Error reset with ON function key Error Messages Page 26 of 33
6 Error Messages Warning 11 Connection fault of level measurement, system will be stopped Check of level measurement connection Check of level measurement function Inform customer service Replace level measurement and recalibrate the system Error reset with ON function key Warning 13 Operation time without service exceeded Inform customer service Warning message Error 16; sterile filter replacement Maximum operation time of the sterile filter has been reached. The sterile filter has to be replaced. Warning 20 Conductivity measurement error, e.g. caused by air inside sensors, ect Deaerate the system Inform customer service 6.1 Troubles and Corrections Trouble Reason Correction Temperature too high Feed water temperature Ambient temperature System temperature by UV lamp or pump too high Conductivity Q1 too high Conductivity Q2 too high Feed water quality VMD module function Feed water quality MF-III-D module function Cooling Cooling Interval-Mode Check of pre-treatment Check of VMD module Check of pre-treatment Check of MF-III-D Module Error Messages Page 27 of 33
7 Maintenance and Servicing 7.1 Interval Material Time of Operation Alarm Message Counter Reset VMD/ DTO module replacement Recommended every 6-12 months, depending on feed water impurities Q1 Value exceeded NO ILT/ MF-III-D module replacement Recommended every 12 months Q2 Value exceeded NO Sterile Filter autoclaving max. 6 times none NO Sterile Filter disinfection max. 12 times none NO Sterile Filter replacement Recommended every 6 months none NO Ultra filtration module replacement Recommended every 12 months none NO 7.2 System Setting table Parameter Unit Setting Temperature compensation auto Temperature limit alarm C 30 Temperature limit to drain C 35 Limit quality Q1 µs/cm 20 Limit quality Q2 µs/cm 0.2 Limit quality Q3 µs/cm 0.2 Module flushing seconds 120 7.3 Disinfection of the System The disinfection of the system should be realized with SG disinfection syringes (Art.No. 2055). With these syringes a user-friendly disinfection is possible: 1) The syringes are filled with a suitable concentration of the disinfectant 2) Potential injuries or damages using the disinfectant are prevented 3) The disinfection procedure is easy with the programming-controlled step-by-step instruction For the disinfection a special disinfection tube (Art.No. 20007) has to be installed instead of the left cartridge module (MF-III-D module). Then one syringe has to be fixed to the tube and the disinfectant only has to be injected. Finally the disinfectant has to be rinsed out. The disinfection procedure will be done by the step-by-step instruction: See chapter Main Menu Maintenance Disinfection Maintenance and Servicing Page 28 of 33
7.4 Sterile Filter Disinfection and Replacement The replacement of the sterile filter is recommended all 6 months as a minimum! Coupler Deaeration screw Coupler The sterile filter (F4.3) protects the system against germination, as bacteria and germs over a size of 0.1 microns are filtered out of the water. Depending on feed water quality, ambient conditions and utilization germs are accumulated in the sterile filter and will contaminate the system. For disinfection the sterile filter can be autoclaved up to 6 times for 20 minutes at 121 C by 2 bar. After 6 times of autoclaving the sterile filter needs to be exchanged. The sterile filter can also be disinfected with the disinfection program of the system control. Another method is a separate flushing inside a disinfectant solution. Stop the system with the OFF function key Depressurize the system by opening dispenser for a moment and open the front door Pull off the couplers from the sterile filter Disinfect or exchange the sterile filter and insert again Start the system with the ON function key Select the menu item Flush for a short flushing of the modules After the flushing the system automatically jumps into normal operation Deaerate the system with sterile filter and Dispenser: Open sterile filter deaeration screw and Dispenser, until pure water flows out (The deaeration might be repeated form some times) Check for impermeability on all connections Close the front door System is ready for use Front inside Note! After module replacement the flushing program within the start selection screen should be selected for a short flushing. Maintenance and Servicing Page 29 of 33
7.5 Replacement of the modules ILT/ MF-III-D module Coupler VMD/ DTO module Sterile filter Coupler Attached modules Stop the system with the OFF function key Depressurize the system by opening dispenser for a moment and open the front door Pull off the couplers from the module Insert the new cartridge and plug in the quick couplers, until a click for the snap in can be heard Start the system with the ON function key Deaerate the system with the sterile filter ventilation until pure water flows out Deaerate the system with the dispenser until pure water flows out Check for impermeability on all connections Close the front door System is ready for use Note! After installation, after module replacement, and after a weekend the flushing program within the start selection screen should be selected for a short flushing. If the conductivity does not reach Ultra-Pure Water quality after installation or module replacement, the resin in the modules has to swell for some time to achieve the full capacity. Maintenance and Servicing Page 30 of 33
7.6 Ultra-filtration Module Replacement Warning! Danger by electric current! Before opening the rear side of the device the mains connection cable must be removed! Coupler Flushing Tube Coupler Stop the system with the OFF function key, disconnect power supply and turn off water supply Depressurize the system by opening dispenser for a moment Unscrew the back side and remove it Pull off the couplers and the flushing tube from the Ultra-filtration module Connect the couplers and flushing tube to the new module Attention: the flowing direction has to comply with the flowing direction marked on the device housing Connect the power supply, turn ON water supply Start the system with the ON function key Select the menu item Flush for a short flushing of the modules After the flushing the system automatically turns into normal operation Deaerate the system with sterile filter and Dispenser: Open sterile filter deaeration screw and Dispenser, until pure water flows out (The deaeration might be repeated form some times) Check for impermeability on all connections Close the rear side System is ready for use Note! After replacement the flushing program within the start selection screen should be selected for a short flushing. Maintenance and Servicing Page 31 of 33
7.7 Contrast Adjustment IMPORTANT! Risk of damage to system! Avoid contact with resistors and other devices mounted on the circuit board. Contrast adjustment The contrast of the display must be adjusted during normal operation. Take care not to touch the circuits. Open the front panel. Remove the lid of the system control box, which is mounted on the rear of the front panel. Adjust the contrast by turning the regulating screw using a small screwdriver. Reattach the lid. Close the front panel. System is ready for use. Maintenance and Servicing Page 32 of 33
8 Technical Data 8.1 Feed Water Requirements Feed pressure bar 0.1 5 Conductivity µs/cm < 20 TOC ppb < 50 Temperature C + 5 + 35 In case of higher feed pressures an optional pressure regulator is available. 8.2 System Data Ultra-Pure Water Output LPM 2 Conductivity at 25 C µs/cm 0,055 Resistivity at 25 C MΩ cm 18,2 TOC concentration ppb 5 10 Bacteria cfu/ ml < 1 Endotoxins EU/ml < 0.001 Particles > 0.1 µm per ml < 1 Temperature C + 5 + 35 Feed water union nut R ¾ Tap adapter R ½ Feed water inlet 5 / 16 Flushing tube connector R ¼ Power supply V / Hz 100-240 / 50-60 Height x Width x Depth mm 530 x 340 x 320 Weight kg 25 Technical Data Page 33 of 33
1 2 3 4 5 6 7 8 A A 0,53[GPM]; 2.0[l/min]; (18.7Hz) range: 60-840L/h; (8-142Hz); max.10bar; 145psi 1/4"female thread 24VDC; 0.2A 1/4"female thread art.06293-1 FT 4.1 input 1/4"female tube connection output 1/4"female tube connection cr.(delay 300s) 20[µS/cm]; (0-0.3/3µS/cm) C=0,1 art.07524 QIA+ Q2 1/2" tube connection cr.(delay 300s) [35 C]; (0-99,9 C) NTC 10kOhm at 25 C range: -80-110 C art.06381-ul TSA+ 4.1 F4.3 art.2052 hose white 5/16" B hose blue 5/16" art.07732 V4.1 hose white 5/16" hose white 5/16" B F4.1 art.2050 hose white 5/16" cr.(delay 300s) 20[µS/cm]; (0-200µS/cm) C=0,2 art.07523 QIA+ Q2 1/2" tube connection hose white 5/16" 3/8" female thread 24VDC; 0,9A max.1,3a P4.1 art.07600 3/8" female thread hose PTFE 5/16" F4.2 art.2051 F4.4 art.2058 1/4"female thread 24VDC; 0.2A 24VDC; 0.2A art.07732 V4.5 1/4"female thread hose white 5/16" Hose nature 1/4 hose nature 1/4" C V4.2 art.06712 delta p=0.7bar 3/8"female 3/8"female hose white 5/16" 1/4"female thread art.07732 V4.6 1/4"female thread 3/8"female delta p=0.8bar art.03175 V4.7 3/8"female hose nature 1/4" V4.3 art.2106 C Hose white 5/16" D D min. 2cm Feed water specification E F Feed water pressure Feed water flow max. 1,0-5,0 1,45-72,5 2 0,53 bar psi l/min GPM Feed water conductivity < 20 µs/cm Free Clorine < 0,1 mg/l CO2 max. < 20 mg/l Silt Density Index < 3 Silica < 15 mg/l Iron (FE) < 0,1 mg/l Manganese (Mn) < 0,05 mg/l ph-range 3-9 Temperature 5-35 45-90 C F Attention: The Langelier-Index must be negative All given flow rates are based on feed water temperature of 59[F]; 15 [C]. V4.1 solenoid valve {24VDC; NC; art.07732} V4.2 check valve circulation {0.7bar; art.06217} V4.3 hand-dispenser {with recirculation; art.2106} V4.5 solenoid valve {24VDC; NC; art.07732} V4.6 solenoid valve {24VDC; NC; art.07732} V4.7 check valve (art.03175) F4.1 pretreatment-module {1xmodule ; art.2094} F4.2 polisher {1xmoduleMF III D ; art.2051} F4.3 sterile filter {0,1 μm; art.2052} F4.4 ultra filtration filter {art.2058} P4.1 membran-pump {72 l/h; 7,5 bar; 24VDC UP-8000; art.07600} UV4.1 UV-light (λ=254nm; art.20001-2-02/2069/05947-1) QIA+ conductivity meter (alarm function; max detection) Q-TOC/Q conductivity sensor {fortoc-monitoring; 07524} TA+ temperature sensor (alarm function) FT- flow turbine (only indication) 1 2 3 4 Designed for: Siemens Water Technologies No. Changing Date NAME 01 xx.xx.xxxx xx 02 03 xx.xx.xxxx xx.xx.xxxx xx xx 04 05 xx.xx.xxxx xx.xx.xxxx xx xx DRAWN CHK'D NAME TK TK APPV'D Dry weight: xxx[kg] SG-Wasseraufbereitung und Regenerierstation GmbH Fahrenberg 8 22885 Barsbüttel Tel.: +49 (0) 40670868-6 Fax. +49 (0) 40670868-44 E-mail: info@siemenswater.com DATE 27.07.2009 27.07.2009 SG-Liefergrenze TITLE: ID.No.: 2003 Standard-Catalog-System DWG NO. SG-Order-No.: DO NOT SCALE DRAWING 2003_P&ID_Rev00 Drain: Drain pipe dimension according to DIN 1988 REVISION Ultra Clear plus Customer-PO-No.: 00 A3 page 1/2
1 2 3 4 5 6 7 8 A A 0,53[GPM]; 2.0[l/min]; (18.7Hz) range: 60-840L/h; (8-142Hz); max.10bar; 145psi 1/4"female thread 24VDC; 0.2A 1/4"female thread art.06293-1 FT 4.1 input 1/4"female tube connection output 1/4"female tube connection cr.(delay 300s) 20[µS/cm]; (0-0.3/3µS/cm) C=0,1 art.07524 QIA+ Q2 1/2" tube connection cr.(delay 300s) [35 C]; (0-99,9 C) NTC 10kOhm at 25 C range: -80-110 C art.06381-ul TSA+ 4.1 F4.3 art.2052 hose white 5/16" B hose blue 5/16" art.07732 V4.1 hose white 5/16" Hose white 5/16" B F4.1 art.2050 cr.(delay 300s) 20[µS/cm]; (0-20µS/cm) C=0,2 art.07523 QIA+ Q1 1/2" tube connection hose white 5/16" 24VDC; xxxa max.xxxa M F4.2 art.2051 F4.4 art.2058 1/4"female thread 24VDC;0,2A art.07732 V4.5 Hose white 5/16" 1/4"female thread hose nature 1/4" hose white 5/16" 3/8" female art.07600 thread P4.1 3/8" female thread hose PTFE 5/16" 24VDC;0,2A Hose nature 1/4 C 3/8"female 1/4"female thread 1/4"female thread 3/8"female tube connection delta p=0.8bar 3/8"female tube connection hose nature 1/4" V4.3 art.2106 C V4.2 art.06712 hose white 5/16" art.07732 V4.6 art.03175 V4.7 3/8"female hose white 5/16" D D min. 2cm E F Feed water specification Feed water pressure Feed water flow max. 1,0-5,0 1,45-72,5 2 0,53 bar psi l/min GPM Feed water conductivity < 20 µs/cm Free Clorine < 0,1 mg/l CO2 max. < 20 mg/l Silt Density Index < 3 Silica < 15 mg/l Iron (FE) < 0,1 mg/l Manganese (Mn) < 0,05 mg/l ph-range 3-9 Temperature 5-35 45-90 C F Attention: The Langelier-Index must be negative All given flow rates are based on feed water temperature of 59[F]; 15 [C]. V4.1 sloenoid valve {24VDC; NC; art.07732} V4.2 check valve circulation {0.7bar; art.06217} V4.3 hand-dispenser {with recirculation; art.2106} V4.5 solenoid valve {24VDC; NC; art.07732} V4.6 solenoid valve {24VDC; NC; art.07732} V4.7 check valve (art.03175) F4.1 pretreatment-module {1xmodule ; art.2050} F4.2 polisher {1xmoduleMF III D ; art.2051} F4.3 sterile filter {0,1 μm; art.2052} F4.4 ultra filtration filter {art.2058} P4.1 membran-pump {72 l/h; 7,5 bar; 24VDC UP-8000; art.07600} UV4.1 UV-light (λ=254nm; art.20001-2-02/2069/05947-1) QIA+ conductivity meter (alarm function; max detection) Q-TOC/Q conductivity sensor {fortoc-monitoring; 07524} TA+ temperature sensor (alarm function) FT flow turbine (only indication) 1 2 3 4 Designed for: Siemens Water Technologies No. Changing Date NAME 01 xxxxx xx.xx.xxxx x.x 02 03 04 05 DRAWN CHK'D APPV'D Dry weight: NAME TK TK xxx[kg] SG-Wasseraufbereitung und Regenerierstation GmbH Fahrenberg 8 22885 Barsbüttel Tel.: +49 (0) 40670868-6 Fax. +49 (0) 40670868-44 E-mail: info@siemenswater.com DATE 27.07.2009 27.07.2009 SG-Liefergrenze TITLE: ID.No.: 2003 Standard-Catalog-System DWG NO. SG-Order-No.: DO NOT SCALE DRAWING 2003_P&ID_Rev00 Drain: Drain pipe dimension according to DIN 1988 REVISION Ultra Clear plus Customer-PO-No.: 00 A3 page 2/2
9.3 Consumables and spare parts Label Description Article No. V4.1 Solenoid valve 07902 none Plug-in connectors (for the modules) 06988 none Elbow connector for modules output 08678-1 F4.1 VMD module for inorganic applications 2050 (F4.1) DTO module for organic applications 2094 QIA Q1 Quality Control Q1 07523 P4.1 Circulation pump 72 l/h 08367-2 TA4.1 Temperature sensor 06381 F4.2 ILT module for inorganic applications 2092 (F4.2) MF-III-D module for organic applications 2051 V4.6 Flushing valve 00055 F4.4 UF Ultra-filtration module 2058 V4.5 Flushing valve 00055 QIA Q2 Quality Control Q2 07524 F4.3 Sterile filter 0.1 µm 2052 V4.3 Dispenser 2104 V4.2 Check valve 0.7 bar 06712 V4.7 Check valve 03175 E1 System control 05697-00 none Switching Power supply 100-240V 08258-2 none Switching Power supply PS-25-12 06281 Please give us always the serial number of your system when ordering consumables and spare parts. Appendix III
Material Safety Data Sheet Last update March 02, 2009 Page 1 (3) 1 PRODUCT AND COMPANY IDENTIFICATION Product name: IMUNELL BA 80 Application of the substance/the preparation: Biocide Manufacturer/Supplier : Dipl.-Ing. Ulrich Grajecki (GmbH & Co.) KG Wurth 6 10, D - 22941 Bargteheide / Postfach 1229, D-22934 Bargteheide, Germany Informing department: Phone +49-4532-20450, Email: msds@imunell.de Emergency information: Phone +49-4532-20 450 2 COMPOSITION/INFORMATION ON INGREDIENTS Description: Microbicide based on Methylisothiazolinone. Dangerous components: 2-Methyl-2H-isothiazol-3-one, CAS: 2682-20-4, EINECS: 220-239-6, NX8157000, Code : M, 0.1% 0.9%, T, C, N, R 22-23-34-43-50. TLV and PEL units: ACGIH-TLV: not established, OSHA-PEL: not established. 3 HAZARDS IDENTIFICATION Description: Microbicide based on Methylisothiazolinone. NFPA ratings (scale 0 4): Health = 1, Fire = 0, Reactivity = 1 Emergency Overview: Prolonged and frequently repeated skin contact could cause allergic skin reactions in some individuals. Acute Exposure: Eye: Prolonged and frequently repeated eye contact could cause reactions in some individual. Inflammation of the eye is characterized by redness, watering and itching. Skin: Prolonged and frequently repeated skin contact could cause allergic skin reactions in some individuals. Inhalation: None required air airborne concentrations are maintained below exposure limits. Ingestion: Ingestion is not expected to be a primary route of exposure. 4 FIRST AID MEASURES General information: Remove or wash clothing soiled by the product. Eye contact: Remove contact lenses if present. Flush with copious amounts of water or normal saline. Skin contact: Remove contaminated clothing. Wash skin with water and soap. Wash contaminated clothing before reuse. Inhalation: Remove to fresh air. Ingestion: Call a physician immediately. Do not induce vomiting. If swallowed, if conscious, give plenty of water immediately. Never give anything by mouth to an unconscious person. 5 FIRE FIGHTING MEASURES Flashpoint: >400 F, >220 C. Extinguishing media: Dry powder, water fog, carbon dioxide, foam. Special Fire Fighting Procedures: Use NIOSH approved positive-pressure self-contained breathing apparatus. 6 ACCIDENTIAL RELEASE MEASURES Important: Before responding to a spill or leak of this product, review each section of this MSDS. Follow the recommendations given in the handling precautions. Check the Fire and Explosion data section to determine if the use of non-sparking tools are merited. Insure that spilled or leaked product does not come into contact with materials listed as incompatible. If irritating fumes are present, consider evacuating the area. SG Wasseraufbereitung und Regenerierstation GmbH Fahrenberg 8 * 22885 Barsbüttel Germany Tel.: +49(0)40/670868-6 * Fax: +49(0)40/670868-44 www.sgwater.de
Material Safety Data Sheet Dipl.-Ing. Ulrich Grajecki (GmbH & Co.) KG IMUNELL BA 80 Page 2 (3) Personal safety measures: Wear protective gloves. Measures for environmental protection: Prevent direct discharge of high amounts (more than 1 l) of concentrated product to sewer or aquatic environment. Measures for cleaning up /collecting Soak up with inert material, (e.g. sand, diatomaceous earth, vermiculite) and place in container for disposal according to local/national regulations (see section 13) or decontaminate small amounts with 5-15% sodium bisulfite solution. 7 HANDLING AND STORAGE Handling: Keep container closed after usage. Storage: Store in tightly closed containers. Preferable maximum storage temperature of 122 F, 50 C for long term. 8 EPOSURE CONTROLS AND PERSONAL PROTECTION Exposure Controls: None respiratory protection required under normal conditions. If over TLV in accordance with 29 CFR 1910.134, use NIOSH approved positive-pressure self-contained breathing apparatus. Personal Protection: Protective clothing, gloves and eye protection is recommended but not necessary. Hand protection: Recommended: gloves. Eye protection: Recommended: eye protection. Skin and body protection: Recommended: protective clothing. Respiratory protection: Use respirator when performing operations involving potential exposure to vapor of the product. Hygiene measures: Wash hands before breaks and immediately after handling the product. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing and gloves. 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance: Brownish liquid. Odor: Mild. ph value: 8 10. Flash point: >400 F, >220 C. Danger of explosion: Product is not explosive. Density: 1.01 g/cc @ 68 F, 20 C. Vapor pressure: 23 hpa for water. Solubility in water: 100% @ 68 F, 20 C, fully miscible. Viscosity: <5 mm2/s @ 68 F, 20 C according to ASTM B 445. 10 STABILITY AND REACTIVITY Chemical Stability: Stable under normal conditions and temperature up to 122 F, 50 C. Materials to avoid: Strong bases, strong acids, contact with strong oxidizing products. Hazardous decomposition or byproducts: Oxides of carbon, nitrogen, and sulfur. Hazardous polymerization: Will not occur under normal conditions. 11 TOXICOLOGICAL INFORMATION Acute hazards: Not tested. Deductive values base on components. Oral, LD50, >2000 mg/kg (rat). Dermal LD50, >2000 mg/kg (rat). Irritant/sensitization effects: Prolonged and frequently repeated skin contact could cause allergic skin reactions in some individuals. SG Wasseraufbereitung und Regenerierstation GmbH Fahrenberg 8 * 22885 Barsbüttel Germany Tel.: +49(0)40/670868-6 * Fax: +49(0)40/670868-44 www.sgwater.de
Material Safety Data Sheet Dipl.-Ing. Ulrich Grajecki (GmbH & Co.) KG IMUNELL BA 80 Page 3 (3) 12 ECOLOGICAL INFORMATION Information about elimination (persistence and degradability): All ingredients are biodegradable. In high dilution the product ingredients can be readilly eliminated in the sewage system. Aquatic toxicity: Low potential to bioaccumulate. Additional ecological information: COD: <100 mg O2/g. The formulation do not contain any heavy metals. AOX indication: The formulation does not affect the AOX value of the effluent water. 13 DISPOSAL CONSIDERATIONS Atomize into a very hot incinerator fire or mix with a suitable flammable solvent, and incinerate where permitted under appropriate Federal, State and local regulations. Always contact a permitted waste disposer (TSD) to assure compliance. 14 TRANSPORT INFORMATION No dangerous goods according to ADR, IMDG, ICAO, IATA-DGR. 15 REGULATORY INFORMATION SARA (Superfund Amendments and Reauthorization Act): Section 302, extremely hazardous substances: Not listed. Section 313, specific toxic chemical listings: Not listed. EPA (Environmental Protection Agency): Not listed. IARC (International Agency for Research on Cancer): Not listed. NTP (National Toxicology Program): Not listed. NIOSH (National Institute for Occupational Safety and Health): Not listed. OSHA (Occupational Safety & Health Administration: Not listed. California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act 1986): This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. 16 Other Information This information provided in this Material Safety Data Sheet represents a compilation of data drawn directly from various sources available to us. However, only safety requirements are characterized and for that this safety data sheet is limited. Users should independently determine the suitability and completeness of information from all sources. While this data is presented in good faith and believed to be accurate, it should be considered only as a supplement to other information gathered by the user. It is the User's responsibility to assure the proper use and disposal of these materials as well as the safety and health of all personnel who may work with or otherwise come in contact with these materials. SG Wasseraufbereitung und Regenerierstation GmbH Fahrenberg 8 * 22885 Barsbüttel Germany Tel.: +49(0)40/670868-6 * Fax: +49(0)40/670868-44 www.sgwater.de