Page 1 of 7 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME AGL Natural Gas SYNONYMS "high methane", "natural gas NG" PROPER SHIPPING NAME METHANE, COMPRESSED or NATURAL GAS, COMPRESSED with high methane content PRODUCT USE Commercial heating and cooking gas fuel, fuel for vehicles. Fractionated and used as base raw material for the manufacture of many chemicals ammonia, acetylene. etc. SUPPLIER Company: AGL Energy Limited Company: AGL Energy Limited Address: Address: Locked Bag 1837 Level 22, 101 Miller Street St. Leonards North Sydney NSW, 2065 NSW, 2060 Australia Australia Telephone: +61 2 9921 2999 Emergency Tel:000 Section 2 - HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE DANGEROUS GOODS. NON-HAZARDOUS SUBSTANCE. According to NOHSC Criteria, and ADG Code. CHEMWATCH HAZARD RATINGS Flammability Toxicity Body Contact Reactivity Chronic SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4 RISK SAFETY Extremely flammable. Keep away from sources of ignition. No smoking. Risk of explosion if heated Do not breathe gas/fumes/vapour/spray. under confinement. Inhalation may produce health Avoid contact with skin. damage*. May produce discomfort of the Avoid contact with eyes. eyes*. Vapours potentially cause Wear eye/face protection. drowsiness and dizziness*. * (limited evidence). Use only in well ventilated areas. Keep container in a well ventilated place.
Page 2 of 7 Section 2 - HAZARDS IDENTIFICATION Keep container tightly closed. In case of contact with eyes, rinse with plenty of water and contact Doctor or Poisons Information Centre. This material and its container must be disposed of as hazardous waste. Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS NAME CAS RN % natural gas 8006-14-2 100 Section 4 - FIRST AID MEASURES SWALLOWED Not considered a normal route of entry. EYE If product comes in contact with eyes remove the patient from gas source or contaminated area. Take the patient to the nearest eye wash, shower or other source of clean water. Open the eyelid(s) wide to allow the material to evaporate. Gently rinse the affected eye(s) with clean, cool water for at least 15 minutes. Have the patient lie or sit down and tilt the head back. Hold the eyelid(s) open and pour water slowly over the eyeball(s) at the inner corners, letting the water run out of the outer corners. SKIN Generally not applicable. INHALED Following exposure to gas, remove the patient from the gas source or contaminated area. NOTE: Personal Protective Equipment (PPE), including positive pressure self-contained breathing apparatus may be required to assure the safety of the rescuer. Prostheses such as false teeth, which may block the airway, should be removed, where possible, prior to initiating first aid procedures. If the patient is not breathing spontaneously, administer rescue breathing. NOTES TO PHYSICIAN Treat symptomatically. Section 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA DO NOT EXTINGUISH BURNING GAS UNLESS LEAK CAN BE STOPPED SAFELY: OTHERWISE: LEAVE GAS TO BURN. FOR SMALL FIRE: Dry chemical, CO2 or water spray to extinguish gas (only if absolutely necessary and safe to do so). DO NOT use water jets. FOR LARGE FIRE: Cool cylinder by direct flooding quantities of water onto upper surface until well after fire is out. DO NOT direct water at source of leak or venting safety devices as icing may occur. FIRE FIGHTING -------------------------------------------------------------- GENERAL -------------------------------------------------------------- Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves. Consider evacuation.
Page 3 of 7 Section 5 - FIRE FIGHTING MEASURES FIRE/EXPLOSION HAZARD HIGHLY FLAMMABLE: will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air Fire exposed containers may vent contents through pressure relief valves thereby increasing fire intensity and/ or vapour concentration. Vapours may travel to source of ignition and flash back. On combustion, emits toxic fumes of: carbon monoxide (CO), carbon dioxide (CO2). FIRE INCOMPATIBILITY Explosion hazard may follow contact with incompatible materials. HAZCHEM 2SE Section 6 - ACCIDENTAL RELEASE MEASURES MINOR SPILLS Avoid breathing vapour and any contact with liquid or gas. Protective equipment including respirator should be used. DO NOT enter confined spaces where gas may have accumulated. Shut off all sources of possible ignition and increase ventilation. Clear area of personnel. MAJOR SPILLS Clear area of all unprotected personnel and move upwind. Alert Emergency Authority and advise them of the location and nature of hazard. May be violently or explosively reactive. Wear full body clothing with breathing apparatus. Personal Protective Equipment advice is contained in Section 8 of the MSDS. Section 7 - HANDLING AND STORAGE PROCEDURE FOR HANDLING Consider use in closed pressurised systems, fitted with temperature, pressure and safety relief valves which are vented for safe dispersal. The tubing network design connecting gas cylinders to the delivery system should include appropriate pressure indicators and vacuum or suction lines. Fully-welded types of pressure gauges, where the bourdon tube sensing element is welded to the gauge body, are recommended. Before connecting gas cylinders, ensure manifold is mechanically secure and does not containing another gas. Before disconnecting gas cylinder, isolate supply line segment proximal to cylinder, remove trapped gas in supply line with aid of vacuum pump. Avoid generation of static electricity. Earth all lines and equipment. DO NOT transfer gas from one cylinder to another. SUITABLE CONTAINER Cylinder: Ensure the use of equipment rated for cylinder pressure. Ensure the use of compatible materials of construction. Valve protection cap to be in place until cylinder is secured, connected. Check that containers are clearly labelled. Packaging as recommended by manufacturer. STORAGE INCOMPATIBILITY Segregate from oxygen gas, oxidising agents. STORAGE REQUIREMENTS Store in a cool, dry place Store in a flame proof area. No smoking, naked lights, heat or ignition sources. Store in a cool area and away from sunlight Store below 45 deg. C.
Page 4 of 7 Section 7 - HANDLING AND STORAGE Store in a well-ventilated area Store away from incompatible materials. Store in an upright position Outside or detached storage is preferred. Protect containers against physical damage. Rotate all stock to prevent ageing. Use on FIFO (First In-First Out) basis. Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE CONTROLS The following materials had no OELs on our records natural gas: CAS:8006-14- 2 MATERIAL DATA AGL NATURAL GAS: Not available NATURAL GAS: TLV TWA: 1000 ppm as aliphatic hydrocarbon gases, alkane C1-C4 ES TWA: simple asphyxiant PERSONAL PROTECTION EYE Safety glasses with side shields; or as required, Chemical goggles. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent]. HANDS/FEET When handling sealed and suitably insulated cylinders wear cloth or leather gloves. OTHER Protective overalls, closely fitted at neck and wrist. Eye-wash unit. IN CONFINED SPACES: Non-sparking protective boots Static-free clothing. Operators should be trained in correct use. Ensure that there is ready access to breathing apparatus. Ensure ready access to a burns first aid kit. ENGINEERING CONTROLS Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment.
Page 5 of 7 Section 9 - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Invisible, highly flammable gas which readily forms explosive mixtures in air. Odourant in the form of tertiary butylmercaptan (TBM) 30% and tetrahydrothiophene (THT) 70% is added to allow detection, recognition. Gas is less dense than air. Burns with a pale, luminous flame. Practically insoluble in water. Soluble in alcohol, ether, hydrocarbons Packed as a gas under pressure. Sudden release of pressure or leakage will result in generation of a large volume of highly flammable / explosive gas. PHYSICAL PROPERTIES Gas. Does not mix with water. Floats on water. State Compressed gas Molecular Weight 16.04 Melting Range ( C) - 182 Viscosity Not available Boiling Range ( C) - 162 Solubility in water (g/l) Immiscible Flash Point ( C) - 218 ph (1% solution) Not applicable. Decomposition Temp ( C) Not available ph (as supplied) Not applicable Autoignition Temp ( C) 540 Vapour Pressure (kpa) Not applicable. Upper Explosive Limit (%) 15.0 Specific Gravity (water=1) 0.615 (Air = 1) Lower Explosive Limit (%) 5.0 Relative Vapour Density 0.615 (air=1) Volatile Component (%vol) 100 Evaporation Rate Not applicable Section 10 - STABILITY AND REACTIVITY CONDITIONS CONTRIBUTING TO INSTABILITY Presence of incompatible materials Presence of elevated temperatures. Presence of heat source and ignition source. Product is considered stable under normal handling conditions. Hazardous polymerisation will not occur. For incompatible materials - refer to Section 7 - Handling and Storage. Section 11 - TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS SWALLOWED Not normally a hazard due to physical form of product. EYE Generally not applicable. Not considered to be a risk because of the extreme volatility of the gas. SKIN Generally not applicable. INHALED Inhalation of non-toxic gases may cause: CNS effects: headache, confusion, dizziness, stupor, seizures and coma; respiratory: shortness of breath and rapid breathing; cardiovascular: collapse and irregular heart beats; gastrointestinal: mucous membrane irritation, nausea and vomiting. The paraffin gases are practically not harmful at low doses. Higher doses may produce reversible brain and nerve depression and
Page 6 of 7 Section 11 - TOXICOLOGICAL INFORMATION irritation. CHRONIC HEALTH EFFECTS Principal route of occupational exposure to the gas is by inhalation. Long-term exposure to the product is not thought to produce chronic effects adverse to the health (as classified by EC Directives using animal models); nevertheless exposure by all routes should be minimised as a matter of course. TOXICITY AND IRRITATION Not available. Refer to individual constituents. Section 12 - ECOLOGICAL INFORMATION This material and its container must be disposed of as hazardous waste. Ecotoxicity Ingredient Persistence: Persistence: Air Bioaccumulation Mobility Water/Soil natural gas No Data No Data No Data No Data Available Available Available Available Section 13 - DISPOSAL CONSIDERATIONS Discharge to burning flare. Ensure damaged or non-returnable cylinders are gas-free before disposal. Section 14 - TRANSPORTATION INFORMATION Labels Required: FLAMMABLE GAS HAZCHEM: 2SE (ADG7) ADG7: Class or Division: 2.1 Subsidiary Risk: None UN No.: 1971 Packing Group: None Special Provision: None Limited Quantity: 0 Portable Tanks & Bulk None Portable Tanks & Bulk None Containers - Instruction: Containers - Special Provision: Packagings & IBCs - Packing P200 Packagings & IBCs - Special None Instruction: Packing Provision: Name and Description: METHANE, COMPRESSED or NATURAL GAS, COMPRESSED with high methane content Air Transport IATA: ICAO/IATA Class: 2.1 ICAO/IATA Subrisk: None UN/ID Number: 1971 Packing Group: - Special provisions: A1 Cargo Only Packing Instructions: 200 Maximum Qty/Pack: 150 kg Passenger and Cargo Passenger and Cargo Packing Instructions: Forbidden Maximum Qty/Pack: Forbidden Passenger and Cargo Limited Quantity Passenger and Cargo Limited Quantity
Page 7 of 7 Section 14 - TRANSPORTATION INFORMATION Packing Instructions: Forbidden Maximum Qty/Pack: Forbidden Shipping name:methane, COMPRESSED or NATURAL GAS, COMPRESSED with high methane content Maritime Transport IMDG: IMDG Class: 2.1 IMDG Subrisk: None UN Number: 1971 Packing Group: None EMS Number: F-D,S-U Special provisions: None Limited Quantities: 0 Shipping name:methane, COMPRESSED or NATURAL GAS, COMPRESSED with high methane content Section 15 - REGULATORY INFORMATION Indications of Danger: F+ Extremely flammable POISONS SCHEDULE None REGULATIONS Regulations for ingredients natural gas (CAS: 8006-14-2) is found on the following regulatory lists; "Australia High Volume Industrial Chemical List (HVICL)", "Australia Inventory of Chemical Substances (AICS)", "OECD List of High Production Volume (HPV) Chemicals" No data for AGL Natural Gas (CW: 65706) Section 16 - OTHER INFORMATION Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references. The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700. Issue Date: 11-Feb-2013 Print Date: 16-Apr-2013 This is the end of the MSDS.