MATERIAL SAFETY DATA SHEET Page 1 of 7 KLINGERsoft-chem

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Transcription:

MATERIAL SAFETY DATA SHEET Page 1 of 7 1 - IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product Name Other Names Expanded PTFE Sheeting/Jointing/Gaskets Recommended Use High temperature gasket material Supplier KLINGER Limited (ABN 95 008 679 838) 38 McDowell St Welshpool WA 6106 AUSTRALIA Tel +61 (0)8 9350 1100 (0800 1700 Australian Western Standard Time GMT +8 hrs) Fax +61 (0)8 9350 6200 2 - HAZARDS IDENTIFICATION Not classified as hazardous according to the criteria of NOHSC. The product is considered harmless to health and the environment in the form supplied and if stored and handled in the correct manner see Section 7. No hazards are known based on present information. 3 - COMPOSITION/INFORMATION ON INGREDIENTS Ingredient CAS Proportion PTFE (Polytetrafluoroethylene) 9002-84-0 100% 4 - FIRST AID MEASURES

MATERIAL SAFETY DATA SHEET Page 2 of 7 Inhalation Skin Eye Ingestion Dust arising from working the product should be treated as nuisance particulate material. Inhalation of dust may cause irritation to the mucous membranes and upper respiratory tract. Movement of exposed individual to fresh air is recommended. When material is heated to above 300 C thermal decomposition begins to occur. Thermal decomposition products of fluorinated products may cause polymer fume fever with flu-like symptoms which subside within 36 to 48 hours Generation of dust may cause mechanical abrasion. Wash skin with soap and water. Launder heavily contaminated clothing before reuse. Seek medical advice if irritation develops. May cause mechanical irritation in contact with eyes. Remove small solid particles and rinse with water for a minimum of 15 minutes. In all cases of eye contamination it is a sensible precaution to seek medical advice. Not hazardous. Not a likely source of exposure. If ingested, give plenty of fluid to assist passage through system. Seek medical attention if irritation occurs. 5 - FIRE FIGHTING MEASURES Suitable Extinguishing Media Hazards from Combustion Products Precautions for Firefighters and Special Protective Equipment Water, carbon dioxide, powder extinguishers, foam extinguishers Fluorinated olefins, Carbonyl fluoride, Hydrogen Fluoride. At temperatures exceeding 400 C the quantity of pyrolysis product increases rapidly and so does their toxic nature. Small amounts of octafluroisobutylene have been identified. Breathing apparatus and eye protection must be worn to protect from dust and fumes. 6 - ACCIDENTAL RELEASE MEASURES Emergency Procedures Fire: See Section 5

MATERIAL SAFETY DATA SHEET Page 3 of 7 Personal: See Section 4 Environmental: No known environmental hazards exist. Methods and Materials for Containment and Cleanup Approved vacuum cleaners with high efficiency filters (HEPA) conforming to AS3544 or equivalent must be used to clean areas. Spills which involve powder, dusts or granules may create a slip hazard and should be cleaned up immediately. Sweep up but avoid generating dusts. Additional In the case of improper use (see Section 8) fine dust may result. Adequate suction and filtering of the exhaust air should be ensured. 7 - HANDLING AND STORAGE Handling Storage No special precautions necessary when handling the material in its finished form However, whenever further processing of the product is undertaken, potential for the generation of dust exists. See Section 8. Store in a cool, dry, well ventilated area removed from foodstuffs. Material is only flammable through the effects of intensive heat. Excessive heat in the storage area may diminish the product s performance in its intended application. 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION National Exposure Standards PTFE Dust 10mg/m3 ES-TWA (Time-Weighted Averages) (Recommended - Note that PTFE has no current assigned exposure standard, however as a general safety precaution the above guideline may be used.) Biological Limit Value No Biological Limit Value allocated.

MATERIAL SAFETY DATA SHEET Page 4 of 7 Engineering Controls Personal Protective Equipment Ensure adequate ventilation exists to maintain air concentrations below exposure standards. Do not inhale dust. Use localised extraction or wet methods of work to control dust levels. No special precautions necessary when handling the material in its finished form. However, whenever further processing of gaskets is undertaken, the potential for the release of particulates that may cause mechanical abrasion exists. In the case of particle generation exceeding the above-noted National Exposure Standards, recommended PPE are rubber/pvc gloves, coveralls, safety glasses and a P2 particulate (AS1716 or equivalent) respirator. When removing embrittled or spent material or when high levels or dust exist a full-face class H particulate cartridge respirator or full-face positive pressure demand airline respirator (AS1716 or equivalent) is recommended. Good hygiene practices must always be maintained. 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance Form: Sheets or cut gaskets Colour: White Odour ph Vapour Pressure Vapour Density Boiling Point/Range Freezing/Melting Point Flashpoint Solubility (water) None Insoluble Specific Gravity/Density 0.8g/cc

MATERIAL SAFETY DATA SHEET Page 5 of 7 Additional None 10 - STABILITY AND REACTIVITY Chemical stability Conditions to Avoid Stable under intended operating conditions. Not known Incompatible Materials Not known Hazardous Decomposition Products When material is heated to above 300 C thermal decomposition begins to occur. Thermal decomposition products of fluorinated products may cause polymer fume fever with flu-like symptoms which subside within 36 to 48 hours. 11 - TOXICOLOGICAL INFORMATION The most common source of exposure is experienced when smoking cigarettes contaminated with PTFE dust. No toxicity was observed in male/female rats when fed PTFE (up to 25%) for a period of 90 days. Rats were implanted with PTFE. Local sarcomas were induced during this testing procedure, however this is not considered relevant under normal industrial usage. The agent is not classifiable as to its carcinogenicity to humans. 12 - ECOLOGICAL INFORMATION Ecotoxicity Not known. Insoluble in water, precipitates. Although inert as a finished product, avoid contamination of drains or waterways to prevent accumulation in the aquatic environment.

MATERIAL SAFETY DATA SHEET Page 6 of 7 Persistence and Degradability Mobility Not known. Not biologically degradable (selfclassification). Not known 13 - DISPOSAL CONSIDERATIONS Disposal Methods Special Precautions No special requirements exist. This is a thermoplastic material, hence recycling is preferable to landfill disposal. Do not dispose of in an incineration system under any circumstance. Local, state and federal statutory regulations must be observed 14 - TRANSPORT INFORMATION UN Number UN Proper Shipping Name Class and Subsidiary Risks Not Packing Group None allocated None allocated relevant Not relevant Special Precautions for User Hazchem Code Do not transport with Explosives, Oxidising agents, Organic peroxides and foodstuffs. In sheet and cut gasket form there is no risk associated with the product under normal transport conditions. Not defined as a Dangerous Good by the Australian Code for the Transport of Dangerous Goods by Road and Rail. None allocated 15 - REGULATORY INFORMATION Regulations for dangerous materials not applicable.

MATERIAL SAFETY DATA SHEET Page 7 of 7 16 - OTHER INFORMATION The information presented is based on the present level of knowledge and experience. All information and recommendations contained in this publication are to the best of our knowledge. Since the conditions of use are beyond our control, users must satisfy themselves that products are suitable for the intended processes and applications. No warranty is given or implied in respect of information and recommendations or that any use of the products will not infringe rights belonging to other parties. In any event or occurrence, our liability is limited to our invoice value of the goods delivered and properties without notice. END OF MSDS