Safety Data Sheet Section 1: IDENTIFICATION ORANGE SOLVENT Recommended Use: Solvent Cleaner, grease, ink, gum and adhesive remover Product Code: See Manufacturers Code Company: MICHALIS GROUP PTY LTD TRADING AS ALL-PRO CHEMICAL AND CLEANING SUPPLIES Address: 3/7 AYRSHIRE CRESCENT, SANDGATE N.S.W 2304 Telephone Number: (02) 4968 2000 Emergency Telephone Number: Poisons Information Centre: Westmead NSW Australia 131126 Manufacturers Product Code: ORANGESOLVENT (1L) ORANGESOLVENT (5L) ORANGESOLVENT (25L) ORANGESOLVENT (205L) Section 2: HAZARDS Classified as hazardous according to the criteria of the NOHSC. R10 R38 R43 R65 R53 R50 Flammable Irritating to skin. May cause sensitisation by skin contact. Harmful: May cause lung damage if swallowed. May cause long term adverse effects in the aquatic environment. Very toxic to aquatic organisms. Section 3: COMPOSITION INFORMATION Ingredient CAS No Proportion Limonene/Orange Oil 5989-27-5 <90% Anti-oxidant Non Hazardous <0.2% Non-ionic Surfactant Blend Non Hazardous <10% Section 4: FIRST AID Eye (contact) Skin (contact) Inhalation (Breathing) Ingestion (Swallowing) Advice to Doctor Immediately flush eyes with plenty of water holding eyelids open. If eye irritation persists, seek medical advice. Remove contaminated clothing and flush skin and hair with running water. Remove to fresh air. If breathing is difficult, give oxygen. Get medical attention. DO NOT induce vomiting. Give large quantities of water. Never give anything by mouth to unconscious person. For advice, contact a Poisons Information Centre (Phone: 13 11 26) or a doctor. Treat symptomatically ORANGE SOLVENT: Page 1 of 5
Section 5: FIREFIGHTING MEASURE Suitable Extinguishing Media Hazards from Combustion Products Precautions for Fire Fighters and Special Protective Equipment Additional Information Use extinguishing media suited to the materials that are burning. e.g. Foam, dry agent (carbon dioxide, dry chemical powder). Carbon dioxide, carbon monoxide and other toxic gases may be produced in the case of fire. Fire fighters should wear full protective clothing including self contained breathing apparatus and chemical splash suit. Keep container cool with water spray. May form flammable vapour mixture with air. Vapours may travel considerable distance to source of ignition if flashback Hazchem Code- 3[Y] Section 6: ACCIDENTAL RELEASE MEASURES Personal precautions: Environmental precautions: Methods & Materials for Containment & Clean Up: Shut off all sources of ignition. Material can create slippery conditions. Wear appropriate protective equipment, to prevent skin and eye contamination and breathing vapours. CAUTION: Keep spills and cleaning runoff out of drains and open bodies of water. Contain spills with inert absorbent materials (e.g. sand, earth). Transfer liquids and used absorbent material to separate suitable containers for recovery or disposal. Section 7: HANDLING AND STORAGE Precautions for Safe Handling Conditions for Safe Storage Contact ALL-PRO sales representative for advice when using this product for any application other than that outlined on the label. Any non-authorised use of this product may result in personal injury or damage to equipment. Avoid contact with eyes and skin. Avoid breathing vapours. Use away from sources of heat and ignition. Take precautionary measures against static discharge. Store in a cool, dry, well-ventilated area. Keep containers tightly closed when not in use. Inspect regularly for deficiencies such as damage or leaks. Protect against physical damage. Store away from heat and sources of ignition. Do not store near strong acids or oxidising agents. Protect from direct sunlight and moisture. Section 8: EXPOSURE CONTROL/ PERSONAL PROTECTION National Exposure Standards Source: National Exposure Standards for Atmospheric Containments in the Occupational Environment [NOHSC: 1003]. Ingredient CAS No ES-TWA ES-STEL None Available - - - Biological Limit Values Engineering Controls Not Available Use in a well ventilated area. Exhaust ventilation may be necessary in poorly ventilated areas and confined spaces. Fumes are heavier than air, prevent accumulation in hollows or sumps. ORANGE SOLVENT: Page 2 of 5
Section 9: PHYSICAL AND CHEMICAL PROPERTIES Physical state: Colour: Odour: ph: Boiling point/range: Melting point/range: Flash point: Liquid Yellow. Orange Not applicable 175oC <0oC Water 46-48oC Lower explosion limit: 0.7% Upper explosion limit: 6.1% Vapour pressure: Relative vapour density: Water solubility: 0.19kPa at 20oC Not established Forms an emulsion Relative density: 0.838 0.843 Section 10: STABILITY AND REACTIVITY Chemical Stability Conditions to avoid Incompatible materials Hazardous decomposition products Hazardous reactions Stable under normal ambient storage conditions. Avoid high temperatures (store below 30 C). Protect against physical damage. Incompatible with strong acids and strong oxidizing agents such as chlorine, chlorates, nitrates, chromates and dichromates. Hazardous reactions with polymerization catylists such as aluminium chloride and acidic clays. None known. None known. ORANGE SOLVENT: Page 3 of 5
Section 11: TOXICOLOGICAL INFORMATION Health Effects Acute Swallowed Eye Inhaled Skin Chronic Swallowed Eye Inhaled Skin Harmful: May cause lung damage if swallowed. If swallowed do NOT induce vomiting; seek medical advice immediately. And show this container or label. Ingestion may be irritating to the gastrointestinal tracts, nausea and vomiting. With vomiting there is a danger of aspiration. Splashes and mists cause severe irritation and possible burns. Avoid breathing vapour, spray or fumes. Vapours may be irritating to respiratory system, causing coughing and headache. Avoid contact with skin Irritating to skin. May cause sensitisation by skin contact. Reaped or prolonged skin exposure can cause dryness, de-fatting of skin and lead to dermatitis.. Section 12: ECOLOGICAL INFORMATION Ecotoxicity Persistence and degradability Mobility Additional information Environmental fate (exposure): Not available. Not available. Not Available. Avoid contaminating waterways, drains and sewers. Section 13: DISPOSAL CONSIDERATIONS Disposable method Refer to State/ Territory Land Waste Management Authority. Keep spills and cleaning runoff out of municipal sewers and open bodies of water. Section 14: TRANSPORT INFORMATION Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (AICS). UN Number: 2319 UN Proper Shipping Name: TERPENES HYDROCARBONS N.O.S. Class and subsidiary risk: DG Class 3 Packing Group: III EPG Number: 3A1 Special Precautions for user: Avoid storage or contact with strong oxidising or reducing agents. Hazchem code: 3[Y] IMDG Marine Pollutant (MP): This product is classified as a MARINE POLLUTANT according to the IMDG code. Section 15: REGULATORY INFORMATION Poisons Schedule (SUSDP): Not applicable All ingredients are listed in the Australia Inventory of Chemical Substances (AICS). ORANGE SOLVENT: Page 4 of 5
Section 16: OTHER INFORMATION Prepared By: Position: Ian Barkley Managing Director Date of preparation: 1 st July 2014 Legend to Abbreviations and Acronyms < less than AICS Australian Inventory of Chemical Substances CAS Chemical Abstracts Service (Registry Number) CO2 Carbon Dioxide deg C ( 'C ) degrees Celsius EPG Emergency Procedure Guide ES-STEL Exposure Standard Short Term Exposure Limit ES-TWA Exposure Standard Time Weighted Average G gram IMDG International Maritime Dangerous Goods kpa Kilo pascal metric unit to measure pressure Ltr (L) Litre ml Mililitres N/A Not Applicable NOHSC National Occupational Health and Safety Commission SUSDP Standard for the Uniform Scheduling of Drugs and Poisons UN United Nations (number) ORANGE SOLVENT: Page 5 of 5 V1.06/2012