Issue Date 18-Sep-2014 Revision date 10-Apr-2015 Version 4. SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 SAFETY DATA SHEET Issue Date 18-Sep-2014 Revision date 10-Apr-2015 Version 4 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product Code Product name DAPHNE BIOS HYDRO 32SE Pure substance/mixture mixture 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Uses advised against Lubricant 1.3. Details of the supplier of the safety data sheet Manufacturer Idemitsu Kosan Co., Ltd Chome Marunouchi Chiyoda-ku Tokyo, , Japan Telephone: Fax: Supplier Idemitsu Lube (Malaysia) Sdn. Bhd , Lorong Teknologi B Nouvelle Industrial Park Tamas Sains Selangor , Petaling Jaya Selangor Malaysia Telephone: Fax: For further information, please contact 1.4. Emergency telephone number Emergency Telephone 24 Hour Emergency Phone Number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Acute toxicity - Oral Category 4 Skin sensitization Category 1 Chronic aquatic toxicity Category Label elements Product identifier Contains N-PHENYL-1-NAPHTHYLAMINE Page 1 / 8

2 SIGNAL WORD Warning Hazard statements H302 - Harmful if swallowed H317 - May cause an allergic skin reaction H412 - Harmful to aquatic life with long lasting effects Contains Precautionary Statements P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P330 - Rinse mouth P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves/protective clothing/eye protection/face protection P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention P321 - Specific treatment (see supplemental first aid instructions on this label) P363 - Wash contaminated clothing before reuse P273 - Avoid release to the environment P501 - Dispose of contents/ container to an approved waste disposal plant 2.3. Other hazards Harmful to aquatic life Harmful to aquatic life with long lasting effects 3.1 Substances 3.2 Mixtures SECTION 3: Composition/information on ingredients chemical name CAS No weight-% SYNTHETIC OIL ESTER OIL LUBRICATING OIL ADDITIVE - <2 N-PHENYL-1-NAPHTHYLAMINE <1.2 2,6-Di-tert-butyl-p-cresol < Description of first aid measures SECTION 4: First aid measures INHALATION Skin Contact Eye contact INGESTION Move to fresh air in case of accidental inhalation of vapors or decomposition products. (Get medical attention immediately if symptoms occur.). Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label Most important symptoms and effects, both acute and delayed Page 2 / 8

3 Symptoms 4.3. Indication of any immediate medical attention and special treatment needed Note to physicians 5.1. Extinguishing media SECTION 5: FIRE FIGHTING MEASURES Suitable Extinguishing Media CO2, dry chemical, dry sand, alcohol-resistant foam. Unsuitable Extinguishing Media Do not use straight streams 5.2. Special hazards arising from the substance or mixture Thermal decomposition can lead to release of toxic/corrosive gases and vapors In the event of fire and/or explosion do not breathe fumes 5.3. Advice for firefighters Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas For emergency responders Use personal protection recommended in Section Environmental precautions Should not be released into the environment Methods and material for containment and cleaning up Methods for containment Methods for cleaning up Prevent further leakage or spillage if safe to do so. Use personal protective equipment as required Dam up Cover liquid spill with sand, earth or other non-combustible absorbent material Take up mechanically, placing in appropriate containers for disposal Clean contaminated surface thoroughly 6.4. Reference to other sections See Section 12: ECOLOGICAL INFORMATION Precautions for safe handling SECTION 7: Handling and storage Advice on safe handling Use personal protective equipment as required. Avoid breathing vapors or mists. Page 3 / 8

4 General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice Conditions for safe storage, including any incompatibilities Storage Conditions Store at ambient conditions. Store in accordance with local regulations Specific end use(s) Risk Management Methods (RMM) The information required is contained in this Material Safety Data Sheet Control parameters SECTION 8: Exposure controls/personal protection Derived No Effect Level (DNEL) Predicted No Effect Concentration (PNEC) No information available 8.2. Exposure controls Engineering Controls Personal protective equipment Eye/face protection Hand Protection Skin and body protection Respiratory protection Environmental exposure controls Ensure adequate ventilation, especially in confined areas. Tight sealing safety goggles. Wear protective nitrile rubber gloves. Suitable protective clothing. No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. In case of inadequate ventilation wear respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state liquid Appearance clear Odor characteristic Color orange Odor Threshold No information available Property Values Remarks Method ph No information available melting point No information available flash point 270 C / 482 F Cleveland Open Cup Water solubility Insoluble in water Kinematic viscosity 40 C mm2/s Kinematic viscosity 100 C mm2/s 9.2. Other information Pour point -50.0> C Dropping point C g/cm Reactivity SECTION 10: Stability and reactivity Page 4 / 8

5 10.2. Chemical stability Stable under normal conditions. Explosion Data Sensitivity to Mechanical Impact Sensitivity to Static Discharge none Possibility of hazardous reactions Possibility of Hazardous Reactions None under normal processing Conditions to avoid Strong oxidizing agents. Heat, flames and sparks Incompatible materials Strong oxidizing agents Strong bases Hazardous decomposition products Thermal decomposition can lead to release of irritating and toxic gases and vapors Information on toxicological effects Acute toxicity SECTION 11: Toxicological information Product Information Product does not present an acute toxicity hazard based on known or supplied information. INHALATION Eye contact Skin Contact INGESTION Unknown Acute toxicity 97.6% of the mixture consists of ingredient(s) of unknown toxicity. The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) chemical name Acute toxicity (LD50) -Oral- Acute toxicity (LD50) -Dermall- Inhalation LC50 2,6-Di-tert-butyl-p-cresol >2000mg/kg bw 546mg/m 3 skin corrosion/irritation Serious eye damage/eye irritation Sensitization Germ cell mutagenicity Carcinogenicity chemical name IARC Page 5 / 8

6 2,6-Di-tert-butyl-p-cresol Group 3 Reproductive toxicity STOT - single exposure STOT - repeated exposure Aspiration hazard SECTION 12: Ecological information Toxicity 0.3% of the mixture consists of components(s) of unknown hazards to the aquatic environment chemical name Algae/aquatic plants Fish Crustacea 2,6-Di-tert-butyl-p-cresol 6: 72 h Pseudokirchneriella subcapitata mg/l EC : 72 h Desmodesmus subspicatus mg/l EC50 5: 48 h Oryzias latipes mg/l LC Persistence and degradability Bioaccumulative potential Mobility in soil Waste treatment methods SECTION 13: Disposal considerations Waste from Residues / Unused Products Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Improper disposal or reuse of this container may be dangerous and illegal. SECTION 14: Transport information IMDG 14.5 Marine pollutant RID Page 6 / 8

7 14.5 environmental hazard ADR 14.5 environmental hazard IATA 14.5 environmental hazard ADN 14.5 environmental hazard IBC Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Proper shipping name CATEGORY Not regulated Not regulated Not regulated National Regulations Occupational Safety and Health Act SECTION 15: Regulatory information Applicable Factories and Machinery Act Environment Quality Act Pesticides Act Environmentally Hazardous Substances(EHS) Notification and Registration Poisons Act Applicable International Inventories ENCS TSCA EINECS/ELINCS DSL AICS KECL PICCS Not Listed Not Listed Page 7 / 8

8 China (IECSC) Not Listed Taiwan SECTION 16: Other information Issue Date Revision date Revision Note 18-Sep Apr Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 8