Issue Date 04-Apr-2014 Revision date 24-Jan-2015 Version 2. SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 SAFETY DATA SHEET Issue Date 04-Apr-2014 Version 2 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product Code SU-043 Product name DAPHNE SUPER GEAR OIL 68 Pure substance/mixture mixture 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Uses advised against Lubricant 1.3. Details of the supplier of the safety data sheet Manufacturer Idemitsu Lube (Singapore) Pte. Ltd. 37, Pandan Road Singapore, Telephone: Fax: Supplier Idemitsu Lube (Malaysia) Sdn. Bhd. No.21, Lorong Teknologi B Nouvelle Industrial Park Tamas Sains Selangor 1 Kota Damansara PJU , Petaring Jaya Selangor Malaysia Telephone: Fax: For further information, please contact 1.4. Emergency telephone number Emergency Telephone 24 Hour Emergency Phone Number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Chronic aquatic toxicity Category Label elements Product identifier Hazard statements H412 - Harmful to aquatic life with long lasting effects Contains Precautionary Statements P273 - Avoid release to the environment P501 - Dispose of contents/ container to an approved waste disposal plant 2.3. Other hazards Page 1 / 7

2 Harmful to aquatic life Harmful to aquatic life with long lasting effects 3.1 Substances 3.2 Mixtures SECTION 3: Composition/information on ingredients chemical name CAS No weight-% PETROLEUM HYDROCARBON (MINERAL OIL) - >=95 LUBRICATING OIL ADDITIVE - <2 2,6-Di-tert-butyl-p-cresol <0.4 MOLYBDENUM, BIS(DITRIDECYLCARBAMODITHIOATO)DI-.MU.-OXODI OXO-DI-, SULFURIZED < Description of first aid measures SECTION 4: First aid measures INHALATION Skin Contact Eye contact INGESTION Move to fresh air in case of accidental inhalation of vapors or decomposition products. (Get medical attention immediately if symptoms occur.). Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label Most important symptoms and effects, both acute and delayed Symptoms 4.3. Indication of any immediate medical attention and special treatment needed Note to physicians 5.1. Extinguishing media SECTION 5: FIRE FIGHTING MEASURES Suitable Extinguishing Media CO2, dry chemical, dry sand, alcohol-resistant foam. Unsuitable Extinguishing Media Do not use straight streams 5.2. Special hazards arising from the substance or mixture The product causes burns of eyes, skin and mucous membranes Thermal decomposition can lead to release of irritating and toxic gases and vapors In the event of fire and/or explosion do not breathe fumes 5.3. Advice for firefighters Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required. Page 2 / 7

3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas For emergency responders Use personal protection recommended in Section Environmental precautions Should not be released into the environment Methods and material for containment and cleaning up Methods for containment Methods for cleaning up Prevent further leakage or spillage if safe to do so. Use personal protective equipment as required Dam up Cover liquid spill with sand, earth or other non-combustible absorbent material Take up mechanically, placing in appropriate containers for disposal Clean contaminated surface thoroughly 6.4. Reference to other sections See Section 12: ECOLOGICAL INFORMATION Precautions for safe handling SECTION 7: Handling and storage Advice on safe handling Use personal protective equipment as required. Avoid breathing vapors or mists. General Hygiene Considerations Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Storage Conditions Store at ambient conditions. Store in accordance with local regulations Specific end use(s) Risk Management Methods (RMM) The information required is contained in this Material Safety Data Sheet Control parameters SECTION 8: Exposure controls/personal protection Derived No Effect Level (DNEL) Predicted No Effect Concentration (PNEC) No information available 8.2. Exposure controls Page 3 / 7

4 Engineering Controls Ensure adequate ventilation, especially in confined areas. Personal protective equipment Eye/face protection Hand Protection Skin and body protection Respiratory protection Environmental exposure controls Tight sealing safety goggles. Wear protective nitrile rubber gloves. Suitable protective clothing. No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. In case of inadequate ventilation wear respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state liquid Appearance No information available Odor characteristic Color No information available Odor Threshold No information available Property Values Remarks Method ph No information available melting point No information available flash point 232 C / 428 F Cleveland Open Cup Water solubility Insoluble in water Kinematic viscosity 40 C mm2/s Kinematic viscosity 100 C mm2/s 9.2. Other information Pour point C Dropping point C g/cm Reactivity Chemical stability Stable under normal conditions. SECTION 10: Stability and reactivity Explosion Data Sensitivity to Mechanical Impact Sensitivity to Static Discharge none Possibility of hazardous reactions Possibility of Hazardous Reactions None under normal processing Conditions to avoid Strong oxidizing agents. Heat, flames and sparks Incompatible materials Strong oxidizing agents Strong bases Page 4 / 7

5 10.6. Hazardous decomposition products Thermal decomposition can lead to release of irritating and toxic gases and vapors Information on toxicological effects Acute toxicity SECTION 11: Toxicological information Product Information Product does not present an acute toxicity hazard based on known or supplied information. INHALATION Eye contact Skin Contact INGESTION Unknown Acute toxicity 0.6% of the mixture consists of ingredient(s) of unknown toxicity. The following values are calculated based on chapter 3.1 of the GHS document chemical name Acute toxicity (LD50) -Oral- Acute toxicity (LD50) -Dermall- Inhalation LC50 2,6-Di-tert-butyl-p-cresol >2000mg/kg bw 546mg/m 3 skin corrosion/irritation Serious eye damage/eye irritation Sensitization Germ cell mutagenicity Carcinogenicity The petroleum base oils contained in this product have been highly refined by a variety of processes including solvent extraction, hydrotreating, and dewaxing to remove aromatics and improve performance characteristics. All of the oils meet the IP-346 criteria of less than 3 percent PAHs and therefore none are listed as a carcinogen by NTP, IARC, or OSHA. chemical name IARC 2,6-Di-tert-butyl-p-cresol Group 3 Reproductive toxicity STOT - single exposure STOT - repeated exposure Aspiration hazard Not classified. SECTION 12: Ecological information Toxicity Harmful to aquatic life 0.7% of the mixture consists of components(s) of unknown hazards to the aquatic environment chemical name Algae/aquatic plants Fish Crustacea Page 5 / 7

6 2,6-Di-tert-butyl-p-cresol 6: 72 h Pseudokirchneriella subcapitata mg/l EC : 72 h Desmodesmus subspicatus mg/l EC50 5: 48 h Oryzias latipes mg/l LC Persistence and degradability Bioaccumulative potential Mobility in soil Waste treatment methods SECTION 13: Disposal considerations Waste from Residues / Unused Products Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Improper disposal or reuse of this container may be dangerous and illegal. SECTION 14: Transport information IMDG 14.5 Marine pollutant RID 14.5 environmental hazard ADR 14.5 environmental hazard IATA 14.5 environmental hazard Page 6 / 7

7 ADN 14.5 environmental hazard IBC Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Proper shipping name CATEGORY Not regulated Not regulated Not regulated National Regulations Occupational Safety and Health Act Factories and Machinery Act Environment Quality Act Pesticides Act Environmentally Hazardous Substances(EHS) Notification and Registration Poisons Act Food Act SECTION 15: Regulatory information International Inventories ENCS TSCA EINECS/ELINCS DSL AICS KECL PICCS China (IECSC) NZIoC SECTION 16: Other information Issue Date Revision date Revision Note 04-Apr Jan Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 7 / 7