SAFETY DATA SHEET SULPHURIC ACID 15-50%

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product number Synonyms; trade names VO-PH 8100, 16%, 37%, 50%, 20%, 30%, 37.5% SOL, 25%, 30% SOLUTION, 36%, 34%, 40%, 36 SOLUTION, BATTERY ACID 1350 (45%), 50% UNI 899:2009, IMA MINI LIQUIDE, 15% SOL, ph LESS, BATTERY ACID 1280 (38%), 50% AD, 38.3%, MAX. 40%, PH MINUS ASB, BATTERY ACID % SOL REACH registration number CAS number EU index number EC number Relevant identified uses of the substance or mixture and uses advised against Identified uses Chemical 1.3. Details of the supplier of the safety data sheet Supplier Univar Aquarius House 6 Mid Point Business Park Bradford BD3 7AY sds@univar.com 1.4. Emergency telephone number Emergency Contact Number (Office Hours) Emergency Contact Number (Outside Office Hours) Sds No SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification Physical hazards Not Classified Health hazards Skin Corr. 1A - H314 Environmental hazards Not Classified 1/7

2 Classification (67/548/EEC or 1999/45/EC) C;R Label elements EC number Pictogram Signal word Hazard statements Precautionary statements Danger H314 Causes severe skin burns and eye damage. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P313 Get medical advice/attention Other hazards This substance is not classified as PBT or vpvb according to current EU criteria. SECTION 3: Composition/information on ingredients 3.1. Substances Product name REACH registration number EU index number CAS number EC number Mixtures Chemical Name Sulphuric acid SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Move affected person to fresh air at once. Get medical attention. Ingestion Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Never give anything by mouth to an unconscious person. Do not induce vomiting. Get medical attention. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention immediately. Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes. Get medical attention immediately. Continue to rinse Most important symptoms and effects, both acute and delayed 2/7

3 Inhalation Coughing, chest tightness, feeling of chest pressure. Ingestion May cause chemical burns in mouth and throat. Skin contact May cause serious chemical burns to the skin. Eye contact Severe irritation, burning and tearing Indication of any immediate medical attention and special treatment needed Notes for the doctor No specific recommendations. If in doubt, get medical attention promptly. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog Special hazards arising from the substance or mixture Specific hazards Oxides of the following substances: Sulphur Advice for firefighters Special protective equipment for firefighters Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Follow precautions for safe handling described in this safety data sheet. Avoid inhalation of vapours and contact with skin and eyes. Provide adequate ventilation Environmental precautions Environmental precautions Spillages or uncontrolled discharges into watercourses must be reported immediately to the Environmental Agency or other appropriate regulatory body Methods and material for containment and cleaning up Methods for cleaning up Neutralise spilled material with crushed limestone, slaked lime (calcium hydroxide), soda ash (sodium carbonate) or sodium bicarbonate. Flush contaminated area with plenty of water. Collect and place in suitable waste disposal containers and seal securely. For waste disposal, see Section Reference to other sections Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions Avoid spilling. Avoid contact with skin and eyes. Avoid inhalation of vapours and spray/mists. Provide adequate ventilation Conditions for safe storage, including any incompatibilities Storage precautions Keep container tightly closed. Keep only in the original container. 3/7

4 Storage class Corrosive storage Specific end use(s) Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: Exposure Controls/personal protection 8.1. Control parameters Occupational exposure limits Long-term exposure limit (8-hour TWA): WEL 0,05 mg/m3 Short-term exposure limit (15-minute): WEL WEL = Workplace Exposure Limit Ingredient comments WEL = Workplace Exposure Limits 8.2. Exposure controls Protective equipment Eye/face protection The following protection should be worn: Chemical splash goggles. Hand protection It is recommended that gloves are made of the following material: Rubber (natural, latex). Other skin and body protection Wear rubber apron. Wear rubber footwear. Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Appearance Liquid. Colour Colourless. Odour Odourless. ph ph (concentrated solution): <1 Melting point <-8 C Initial boiling point and range 100 Relative density C Solubility(ies) Soluble in water Other information 4/7

5 Other information Not determined. SECTION 10: Stability and reactivity Reactivity There are no known reactivity hazards associated with this product Chemical stability Stability Stable at normal ambient temperatures and when used as recommended Possibility of hazardous reactions Not determined Conditions to avoid Avoid excessive heat for prolonged periods of time Incompatible materials Materials to avoid Strong alkalis. Strong oxidising agents. Strong reducing agents Hazardous decomposition products Oxides of the following substances: Sulphur. SECTION 11: Toxicological information Information on toxicological effects Inhalation Vapour may irritate respiratory system/lungs. Ingestion May cause chemical burns in mouth, oesophagus and stomach. Skin contact Causes burns. Corrosive. Prolonged contact causes serious tissue damage. Eye contact Causes burns. SECTION 12: Ecological Information Ecotoxicity The product may affect the acidity (ph) of water which may have hazardous effects on aquatic organisms Toxicity Not considered toxic to fish Persistence and degradability Persistence and degradability There are no data on the degradability of this product Bioaccumulative potential The product is not bioaccumulating Mobility in soil Mobility The product is soluble in water Results of PBT and vpvb assessment This substance is not classified as PBT or vpvb according to current EU criteria. 5/7

6 12.6. Other adverse effects Not determined. SECTION 13: Disposal considerations Waste treatment methods General information Waste should be treated as controlled waste. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. Do not puncture or incinerate, even when empty. Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. SECTION 14: Transport information General Wear protective clothing as described in Section 8 of this safety data sheet UN number UN No. (ADR/RID) 2796 UN No. (IMDG) 2796 UN No. (ICAO) UN proper shipping name Proper shipping name (ADR/RID) Proper shipping name (IMDG) Proper shipping name (ICAO) Proper shipping name (ADN) Transport hazard class(es) ADR/RID class 8 ADR/RID subsidiary risk ADR/RID label 8 IMDG class 8 IMDG subsidiary risk ICAO class/division 8 ICAO subsidiary risk Transport labels Packing group ADR/RID packing group IMDG packing group ICAO packing group II II II Environmental hazards Environmentally hazardous substance/marine pollutant No Special precautions for user 6/7

7 EmS Emergency Action Code Hazard Identification Number (ADR/RID) Tunnel restriction code F-A, S-B 2R 80 (E) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code No information required. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009 No. 716). EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended). Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended). Guidance CHIP for everyone HSG228. Safety Data Sheets for Substances and Preparations. Approved Classification and Labelling Guide (Sixth edition) L131. Inventory Information Chemical safety assessment EINECS No chemical safety assessment has been carried out. SECTION 16: Other information Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision. Revision date 24/09/2012 Revision 03 SDS number SDS status Signature Risk phrases in full Hazard statements in full Approved. Jitendra Panchal R35 Causes severe burns. H314 Causes severe skin burns and eye damage. 7/7