Chronic aquatic toxicity Category 3

Transcription

1 Printdate:05/28/2015 SAFETYDATASHEET 1.COMPANYANDPRODUCTIDENTIFICATION RevisionNumber:1 Productidentifier ProductName: QUINTOLUBRICÒ 865 Productcode: Othermeansofidentification Synonyms Application RecommendedUse Usesadvisedagainst Supplier/Manufacturer: Supplier: Quaker Chemical Corporation Quaker Park One 901 Hector Street Conshohocken, PA Fire-Resistant Hydraulic Fluid For industrial use only Emergencytelephonenumber: * 24 HOUR TRANSPORTATION: **CHEMTREC: (Call collect outside of US) * 24 HOUR EMERGENCY HEALTH & SAFETY: **QUAKER CHEMICAL CORPORATION: (800) (Within US only) Outside of US call (703) HAZARDSIDENTIFICATION Classification OSHARegulatoryStatus This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Chronic aquatic toxicity Category 3 LabelElements EmergencyOverview HazardStatements Harmful to aquatic life with long lasting effects Appearance Clear Amber PrecautionaryStatements-Prevention Avoid release to the environment PhysicalState Liquid OdorMild Ester-like QUINTOLUBRICÒ 865 1/8

2 PrecautionaryStatements-Disposal Dispose of contents/container to an approved waste disposal plant Hazardsnototherwiseclassified(HNOC) ne known OtherInformation Harmful to aquatic life. Unknownacutetoxicity % of the mixture consists of ingredient(s) of unknown toxicity 3.COMPOSITION/INFORMATIONONINGREDIENTS CAS. Weight% Antioxidant Proprietary <1% The exact percentage (concentration) of composition has been withheld as a trade secret. If CAS number is "proprietary", the specific chemical identity and percentage of composition has been withheld as a trade secret. 4.FIRSTAIDMEASURES Generaladvice: Eyecontact: Skincontact: Ingestion: Inhalation: tetophysician: Medicalcondition aggravatedbyexposure: Show this safety data sheet to the doctor in attendance. Remove contaminated clothing and shoes. Wash contaminated clothing before re-use. Wash off with soap and water. If symptoms persist, call a physician. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contaminated clothing and shoes. Wash contaminated clothing before re-use. Rinse immediately with plenty of water for at least 15 minutes. If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Move to fresh air in case of accidental inhalation of vapors. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Consult a physician. Treat symptomatically. Dermatitis. 5.FIRE-FIGHTINGMEASURES Suitableextinguishingmedia: Specifichazards: Specialprotectiveequipmentfor fire-fighters: Specificmethods: Use dry chemical, CO2, water spray or `alcohol` foam. Do not allow material to contaminate ground water system. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Water mist may be used to cool closed containers QUINTOLUBRICÒ 865 2/8

3 6.ACCIDENTALRELEASEMEASURES Personalprecautions: Environmentalprecautions: Methodsforcleaningup: Ensure adequate ventilation. Use personal protective equipment. Avoid contact with skin, eyes and clothing. Do not breathe vapour/dust. Wash thoroughly after handling Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up and shovel into suitable containers for disposal. 7.HANDLINGANDSTORAGE Handling Technical measures/precautions: Safehandlingadvice: Provide sufficient air exchange and/or exhaust in work rooms. Do not breathe vapors or spray mist. In case of insufficient ventilation, wear suitable respiratory equipment. Wear personal protective equipment. Avoid contact with skin and eyes. Wash thoroughly after handling. Storage Technicalmeasures/storage conditions: Incompatibleproducts: Store at room temperature in the original container Strong oxidizing agents Safestoragetemperature: F Shelflife: 2 years 8.EXPOSURECONTROLS/PERSONALPROTECTION ACGIHExposureLimits OSHATWA(final) NIOSH-PocketGuide Mineral Oil* 5 mg/m³ 5mg/m³ 5mg/m³ Engineeringmeasures: Ensure adequate ventilation. PersonalProtectiveEquipment: General: Respiratoryprotection: Eyeprotection: Eye Wash and Safety Shower If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, a NIOSH-certified respirator with organic vapor/p100 filter should be worn. Safety glasses with side-shields Handprotection: Neoprene gloves QUINTOLUBRICÒ 865 3/8

4 Skinandbodyprotection: Hygienemeasures: Long sleeved clothing Avoid contact with skin, eyes and clothing. 9.PHYSICALANDCHEMICALPROPERTIES PhysicalState Appearance Odor OdorThreshold phconcentrate: phdilution Melting/freezingpoint BoilingPoint/Range Liquid Clear Amber Mild Ester-like NA FlashPoint 357 C / 675 F Method Evaporationrate FlammabilityLimitsinAir upperflammabilitylimit lowerflammabilitylimit VOCContent Vaporpressure Vapordensity Cleveland Open Cup (COC) SpecificGravity(g/cc,15C) BulkDensity(lb/gal,15C) 7.70 WaterSolubility Solubilityinothersolvents Partitioncoeficient:n-octanol/water Autoignitiontemperature DecompositionTemperature Insoluble Kinematicviscosity QUINTOLUBRICÒ 865 4/8

5 Dynamicviscosity MolecularWeight 10.STABILITYANDREACTIVITY Stability: Conditionstoavoid: Materialstoavoid: Stable under recommended storage conditions. ne known. Strong oxidizing agents. Hazardousdecompositionproducts:Carbon oxides. Nitrogen oxides (nox). Sulphur oxides. Oxides of phosphorus. HazardousPolymerization: t applicable. 11.TOXICOLOGICALINFORMATION toxicological information is available on the product. Data obtained on components are summarized below. Informationonlikelyroutesofexposure Inhalation EyeContact SkinContact Ingestion May cause irritation of respiratory tract. Contact with eyes may cause irritation. Prolonged contact may cause redness and irritation. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. LD50Oral Antioxidant > 5000 mg/kg ( Rat ) Oral LD50 Rat >5000 mg/kg (Source: IUCLID) LD50Dermal > 10 g/kg ( Rabbit ) Dermal LD50 Rabbit >10 g/kg (Source: NLM_CIP) LC50Inhalation - Delayedandimmediateefectsaswelaschronicefectsfrom shortandlong-term exposure Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen IARCCarcinogens NTP OSHA- SelectCarcinogens Antioxidant t listed t listed t listed Sensitization Mutagenicefects: ReproductiveToxicity DevelopmentalToxicity Teratogenic QUINTOLUBRICÒ 865 5/8

6 Specifictargetorgansystemic toxicity(singleexposure) Specifictargetorgansystemic toxicity(repeatedexposure) Aspirationhazard Additionalinformationontoxicologicalefects This product contains no toxic ingredients, as defined under 29 CFR ECOLOGICALINFORMATION Ecotoxicity-FishSpecies Ecotoxicity-Freshwater Ecotoxicity-WaterFlea Data: AlgaeData: Data: Antioxidant data =0.45mg/L data % of the mixture consists of components(s) of unknown hazards to the aquatic environment PersistenceandDegradability Bioaccumulation Octanol/waterpartitioncoeficient Antioxidant - Mobility: Ozone: data available data available 13.DISPOSALCONSIDERATIONS Wastefrom residues/unused products: Contaminatedpackaging: Methodsforcleaningup: Waste disposal must be in accordance with appropriate Federal, State, and local regulations. This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority. Do not re-use empty containers Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up and shovel into suitable containers for disposal. 14.TRANSPORTINFORMATION U.S.DEPARTMENTOFTRANSPORTATION: Propershippingname: TDG(CANADA): Propershippingname: t Regulated t Regulated QUINTOLUBRICÒ 865 6/8

7 IMDG/IMO: Propershippingname: IATA/ICAO: Propershippingname: t Regulated t Regulated 15.REGULATORYINFORMATION FederalRegulations OSHAHazardCommunication Standard: This product is considered to be hazardous under the OSHA Hazard Communication Standard. CERCLA/SARAInformation: SARA(311,312)hazardclass: ImmediateHealth(Acute): DelayedHealth(Chronic): Flammability: Pressure: Reactivity: This product possesses the following SARA Hazard Categories: HazardousSubstances andrqs ExtremelyHazardous SubstancesandTPQs SARA313Emission Reporting Antioxidant t listed t listed t listed CleanAirandCleanWaterActs: HazardousAir Polutants CWA-Hazardous Substances CWA-Toxic Polutants CWA-Priority Polutants Antioxidant t listed t listed t listed t listed CleanAirandWaterActs: t regulated U.S.STATEREGULATIONS(RTK): California PARTK MICritical NJRTK MARTK Proposition65 Materials Antioxidant t Listed t Listed t Listed t Listed t Listed CaliforniaProposition65Status:May contain trace amounts of listed chemicals: 1,4-dioxane, ethylene oxide, propylene oxide RCRAStatus: t regulated CANADIANREGULATIONS: Canada-WHMISClassification Information: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the information required by the CPR. CanadianProductClassification: ne Required QUINTOLUBRICÒ 865 7/8

8 ProductClassificationGraphic(s): ComponentClassificationData: WHMIShazardclass CEPAScheduleI ChalengeSubstances Antioxidant ne t listed t listed INVENTORYSTATUS: UnitedStatesTSCA-Sect.8(b)Inventory: CanadaDSL/NDSLInventoryList This product complies with TSCA Compliance has not been determined 16.OTHERINFORMATION Sourcesofkeydatausedtocompile Material safety data sheets of the ingredients. thedatasheet: Preparedby: Quaker Chemical Corporation -Safety, Health and Environmental Affairs Group - US RevisionDate: 04/10/2015 Reasonforrevision: New Format. Personalprotectionrecommendationsshouldbereviewedbypurchasers.Workplaceconditionsareimportantfactorsin specifyingadequateprotection. Disclaimer This product's safety information is provided to assist our customers in assessing compliance with safety/health/environmental regulations. The information contained herein is based on data available to us and is believed to be accurate. However, no warranty of merchantability, fitness for any use, or any other warranty is expressed or implied regarding the accuracy of this data, the results to be obtained from the use thereof, or the hazards connected with the use of the product. Since the use of this product is within the exclusive control of the user, it is the user's obligation to determine the conditions for safe use of the product. Such conditions should comply with all regulations concerning the product. The company referenced in this Safety Data Sheet assumes no liability for any injury or damage, direct or consequential, resulting from the use of this product unless such injury or damage is attributable to the gross negligence of such company. EndofSafetyDataSheet QUINTOLUBRICÒ 865 8/8