Safety Data Sheet Sasfroth 10

Transcription

1 1. Identification of the substance/mixture and of the company/undertaking Trade name Synonyms Product code 3283 Company Sasol Solvents A Division of Sasol Chemical Industries 2 Sturdee Avenue Rosebank 2196 Republic of South Africa Information (Product safety) Telephone: Fax: address msds.info@sasol.com Emergency telephone number Europe, Israel, Africa, Americas +44 (0) Middle East, Arabic African +44 (0) countries Asia Pacific China South Africa +27 (0) Australia Hazards identification Identification of the risks R22 Harmful if swallowed. 3. Composition/information on ingredients Preparation on the base: hexan-1-ol Contents: %W/W CAS-No Index-No EC-No Symbol(s) Xn R-phrase(s) -R22 1-pentanol Contents: 9.53 %W/W CAS-No Index-No EC-No Symbol(s) Xn R-phrase(s) -R10 -R20 -R37 -R66 Print Date /7

2 Cyclohexanol Contents: 7.65 %W/W CAS-No Index-No EC-No Symbol(s) Xn R-phrase(s) -R20/22 -R37/38 2-methylcyclohexanol, mixed isomers Contents: 1.27 %W/W CAS-No Index-No EC-No Symbol(s) Xn R-phrase(s) -R20 For the full text of the R-phrases mentioned in this Section, see Section First aid measures General advice Inhalation If you feel unwell, seek medical advice (show the label where possible). Move to fresh air in case of accidental inhalation of vapours. In case of shortness of breath, give oxygen. If breathing is irregular or stopped, administer artificial respiration. Call a physician immediately. Skin contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician. Eye contact Ingestion Rinse immediately with plenty of running water, also under the eyelids, for at least 15 minutes Remove contact lenses. If eye irritation persists, consult a specialist. If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. 5. Firefighting measures Suitable extinguishing media Specific hazards during firefighting Special protective equipment for firefighters Further information Water spray, Dry powder, Foam Do not allow run-off from fire fighting to enter drains or water courses. Wear self-contained breathing apparatus and protective suit. Standard procedure for chemical fires. In the event of fire, cool tanks with water spray. Print Date /7

3 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up 7. Handling and storage Handling Safe handling advice Advice on protection against fire and explosion Storage Requirements for storage areas and containers Use personal protective equipment. Do not breathe vapours or spray mist. Ensure adequate ventilation. Keep away from sources of ignition - No smoking. Avoid subsoil penetration. Do not flush into surface water or sanitary sewer system. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). The material taken up must be disposed of in accordance with regulations. Wear personal protective equipment. Avoid contact with skin and eyes. Keep away from sources of ignition - No smoking. No special protective measures against fire required. Keep containers tightly closed in a cool, well-ventilated place. 8. Exposure controls/personal protection Components with workplace control parameters NATIONAL OCCUPATIONAL EXPOSURE LIMITS Contains no substances with occupational exposure limit values. EUROPEAN OCCUPATIONAL EXPOSURE LIMITS Contains no substances with occupational exposure limit values. Engineering measures Provide sufficient air exchange and/or exhaust in work rooms. Personal protective equipment Respiratory protection Respirator with a vapour filter (EN 141) Hand protection Solvent-resistant gloves Eye protection Safety glasses with side-shields Print Date /7

4 Skin and body protection Hygiene measures Protective measures Protective suit, Safety shoes Wash hands before breaks and immediately after handling the product. Wear suitable protective equipment. 9. Physical and chemical properties Form State of matter Colour Odour ph Liquid Liquid; at 20 C; 1,013 hpa Clear, colourless amber Alcohol-like 7; Neutral Melting point/range -40 C Boiling point/boiling range Flash point 140 C 57 C; Closed cup Density 0.85 g/cm 3 ; 20 C Water solubility Partition coefficient: n-octanol/water Partly soluble No data available Medium: Diethylether; Soluble Medium: Methanol; Soluble Medium: acetone-like; Soluble Medium: n-octanol; slightly soluble Viscosity, dynamic 1.32 mpa.s; 20 C 10. Stability and reactivity Materials to avoid Hazardous decomposition products Oxidizing agents, Reducing agents Carbon dioxide (CO 2 ) Carbon monoxide Print Date /7

5 11. Toxicological information Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity 12. Ecological information Ecotoxicity effects Toxicity to fish 13. Disposal considerations Product Contaminated packaging Hexanol: LD50 rat: 720 mg/kg; literature value n-pentanol: LD50 rat: 370 mg/kg; literature value n-pentanol: LCLo rat: 14,000 mg/m3; literature value; 6 h Hexanol: LD50 rabbit: 3,100 mg/kg; literature value n-pentanol: LDLo rabbit: 4,490 mg/kg; literature value Hexanol: LC50 Pimephales promelas: 97.5 mg/l; 96 h; literature value In accordance with local and national regulations. Packaging that cannot be cleaned must be disposed of in the same way as the material itself. 14. Transport information ADR RID ADNR IMDG ICAO/IATA UN number: 1987; Class: 3; Packaging group: III; F1; Description of the goods: ALCOHOLS, N.O.S. UN number: 1987; Class: 3; Packaging group: III; F1; Description of the goods: ALCOHOLS, N.O.S. UN number: 1987; Class: 3; Packaging group: III; F1; Description of the goods: ALCOHOLS, N.O.S. UN number: 1987; Class: 3; EmS: F-E, S-D; Packaging group: III; Description of the goods: ALCOHOLS, N.O.S. UN number : 1987; Class: 3; Packaging group: III; Description of the goods: Alcohols, n.o.s. Print Date /7

6 15. Regulatory information Labelling Regulatory base Symbol(s) R-phrase(s) S-phrase(s) Hazardous components which must be listed on the label 1999/45/EC Xn: Harmful R22: Harmful if swallowed. S 7/9: Keep container tightly closed and in a well-ventilated place. S16: Keep away from sources of ignition - No smoking. S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. S60: This material and its container must be disposed of as hazardous waste. S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. hexan-1-ol 16. Other information Full text of R-phrases referred to under sections 2 and 3 R10 Flammable. R20 Harmful by inhalation. R20/22 Harmful by inhalation and if swallowed. R22 Harmful if swallowed. R37 Irritating to respiratory system. R37/38 Irritating to respiratory system and skin. R66 Repeated exposure may cause skin dryness or cracking. Print Date /7

7 All reasonable efforts were exercised to compile this SDS in accordance with ISO and ANSIZ The SDS provides information regarding the health, safety and environmental hazards, at the date of issue, to facilitate the safe receipt, use and handling of the product in the workplace. Since Sasol and its subsidiaries cannot anticipate or control all conditions under which the product may be handled, used and received in the workplace, it remains the obligation of each user, receiver or handler to, prior to usage, review this SDS in the context within which the product will be received, handled or used in the workplace. The user, handler or receiver must ensure that the necessary mitigating measures are in place as regards health and safety. This does not substitute the need or requirement for any relevant risk assessments to be conducted. It further remains the responsibility of the receiver, handler or user to communicate such information to all relevant parties that may be involved in the receipt, use or handling of the product. Although all reasonable efforts were exercised in the compilation of this SDS, Sasol does not expressly warrant the accuracy or assume any liability for the incompleteness of the information contained herein or any advice given. The product is sold and risk passes in accordance with the specific terms and conditions of sale. The MSDS was created by: F. SHAI The MSDS was approved by: M. HUYSER Print Date /7