1.Identification of The Substance/Mixture and of The Company

Transcription

1 SiSiB PC7500 SILANE Identification of The Substance/Mixture and of The Company Product Code: SiSiB PC7500 Chemical Name: Vinyltris(methylethylketoximino)silane Manufacturer: Corporation Limited. Post Address: Guanghua Science & Technology Industrial Park, No. 104, Guanghua Road, Nanjing , P.R.China Emergency Telephone Number: Use of Substance: For Industrial Use Alternative Names: VOS 2. Hazardous Identification Risk advice to man and the environment Xi, Irritant R38 Irritating to skin. Irritant Sensitizing See Section 11 for more detailed information on health effects and symptoms. 3. Composition/Information on Ingredients Substances Chemical Name: Vinyl Oximino Silane CAS-No. : EC-No. : Classification: Xi; R38-R41-R43 Occupational Exposure Limit(s), if available, are listed in Section 8. For the full text of the R phrases mentioned in this Section, see Section First Aid Measures Inhalation: Move to fresh air. Artificial respiration and/or oxygen may be necessary. Call a physician immediately. Skin contact: Wash off immediately with plenty of water. If symptoms persist, call a physician. Eye contact: In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

2 SiSiB PC7500 SILANE Ingestion: When swallowed, allow water to be drunk. Do NOT induce vomiting. Call a physician immediately. See Section 11 for more detailed information on health effects and symptoms. 5. Fire Fighting Measures Suitable extinguishing media: Dry chemical Alcohol-resistant foam Extinguishing media which shall not be used for safety reasons: Water Foam Specific hazards during fire fighting: Fire may cause evolution of: Carbon monoxide nitrogen oxides (NOx) Special protective equipment for fire-fighters: In the event of fire, wear self-contained breathing apparatus. No unprotected exposed skin areas. 6. Accidental Release Measures Personal precautions: Ensure adequate ventilation. Environmental precautions: Do not flush into surface water or sanitary sewer system. Methods for cleaning up: Soak up with inert absorbent material. Pick for disposal in tightly closed containers For personal protection see section Handling and Storage Handling Advice on safe handling : Exhaust ventilation at the object is necessary. Keep container tightly closed. Advice on protection against fire and explosion: No special protective measures against fire required. Storage Further information on storage conditions. Keep containers tightly closed in a dry, cool and well-ventilated place Advice on common storage: Do not store together with:

3 SiSiB PC7500 SILANE Oxidizing agents Acids Keep away from water. 8. Exposure Controls and Personal Protection Components with workplace control parameters Contains no substances with occupational exposure limit values. Personal protective equipment Respiratory protection : Remarks: In case of insufficient ventilation wear suitable respiratory equipment. Hand protection: Glove material: butyl-rubber Eye protection: Goggles Skin and body protection: Protective suit 9. Physical and Chemical Properties Appearance Form: liquid Colour: colourless Odour: ether-like Safety data Melting point/range: -59 C Boiling point/boiling range at hpa: > 300 C Flash point: 62 C Method: closed cup Vapour pressure at 117 C: μpa Density at 20 C: 0,988 g/cm3 Water solubility: Remarks: Reacts violently with water. 10. Stability and Reactivity Conditions to avoid: Heat. Protect against water. Materials to avoid: Reactions with water and acids. Reactions with various metals. Iron Hazardous decomposition products: Methyl ethyl ketone Methylethyl ketoxime (MEKO) Carbon monoxide

4 SiSiB PC7500 SILANE Nitrogen oxides (NOx) Silicone oxide Thermal decomposition: Note: No decomposition if used as directed. 11. Toxicological Information Acute oral toxicity: LD50 Species: rat Dose: 1,9-2,5 mg/kg Skin irritation: Result: irritating Eye irritation: Classification: irritant - risk of serious damage to eyes 12. Ecological Effects Additional ecological information: No information on ecology is available. 13. Disposal Considerations Product: Dispose according to legal requirements. Packaging: Legal requirements are to be considered in regard of reuse or disposal of used packaging materials 14. Transport Information ADR IATA IMDG RID Other information: Risk of serious damage to eyes. 15. Regulatory Information Labelling according to EC Directives 1999/45/EC Symbol(s): Xi Irritant R-phrase(s): R38 Irritating to skin. S-phrase(s): S23 Do not breathes spray. S24 Avoid contact with skin.

5 SiSiB PC7500 SILANE S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Hazardous components which must be listed on the label: Butan-2-one O,O',O''-(vinylsilylidyne)trioxime Other Information Text of R-phrases referred to under heading 3 Butan-2-one O,O',O''-(vinylsilylidyne)trioxime: R38 Irritating to skin. Butanone oxime: R40 Limited evidence of a carcinogenic effect. R21 Harmful in contact with skin. It must be recognized that the physical and chemical properties of any product may not be fully understood and that new, possibly hazardous products may arise from reactions between chemicals. The information given in this data sheet is based on our present knowledge and shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.