Material Safety Data Sheet According to EU Regulation 1907/2006

Transcription

1 Material Safety Data Sheet According to EU Regulation 1907/2006 Cedarleaf Oil SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product Identifier Product Name Biological Definition INCI Name Synonyms & Trade Names Product Code Cedarleaf Oil Thuja Orientalis Extract is an extract of the leaf of the Thuja, Thuja orientalis L., Cupressaceae Thuja Orientalis Leaf Extract Cedarleaf Oil OECEDA CAS-No EC No EINECS No Details of the supplier of the safety data sheet Company Identification Madar Corporation Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK Tel: sales@madarcorporation.co.uk Page 1

2 SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification (67/548/EEC) May cause lung damage if swallowed. May cause sensitisation by skin contact. Classification (EU 1272/2008) Physical and Chemical Hazards: Flam. Liq. 3 (H226) Human health: Acut. Tox. Oral 4 (H302) Asp. Tox. 1 (H304) Skin Sens. 1 (H317) Environment : Aqu. Chron. 2 (H411) 2.2 Label elements Label in accordance with Regulation (EC) No 1272/2008 GHS Label: Signal word: Contains Hazard Statements: Precautionary Statements: Supplementary Precautionary Statements: GHS07 GHS02 GHS08 GHS09 Danger Contains; alpha-pinene, thujon, limonene, camphene H224 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P280 Wear protective gloves/protective clothing and eye/face protection. P301/P330/P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P310 Immediately call a POISON CENTER or doctor/physician. P273 Avoid release to the environment. P501 Dispose of contents/container to regional, national regulation. None Risk phrases and Safety phrases in full refer to Section 16 Other Information 2.3 Other hazards Adverse physio-chemical properties Adverse effects on human health SECTION 3: Composition/information on ingredients 3.1 Substances 3-8% alpha-pinene CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Liq. 3 H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Asp. Tox. 1 - H % Thujone (alpha + beta) CAS No: EC No: Classification (EC 1272/2008); Acute Tox 4 H % Limonene CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Liq. 3 H226, Skin Irrit 2 H315 Asp Tox. 1 H304, Skin Sens. 1 H317 - Aquatic Acute 1 H400, Aquatic Chronic 1 H % Camphene CAS-No , EC Classification (EC 1272/2008); Flam. Sol. 1 H228, Eye Irrit 2 H319, Aquatic Acute 1 H Mixtures EU INCI US INCI Page 2

3 SECTION 4: First aid measures 4.1 Description of first aid measures General Information Inhalation Ingestion Skin Contact Eye Contact See categories below Remove from exposure area to fresh air. Seek medical attention immediately. DO NOT INDUCE VOMITING! Wash mouth out with water and provide fresh air. Seek medical attention immediately. Remove contaminated clothing wash thoroughly with soap and water. Seek medical attention immediately. Flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Seek medical attention immediately. Continue to rinse. 4.2 Most important symptoms and effects, both acute and delayed Observe risk of aspiration if vomiting occurs. 4.3 Indication of any immediate medical attention and special treatment needed Treat symptomatically SECTION 5: Fire fighting measures 5.1 Extinguishing Media Use CO2, Dry Powder or Foam type extinguishers, spraying extinguishing media to base of flames. Do not use direct water jet on burning material. 5.2 Special hazards arising from the substance or mixture. In case of fire toxic fumes like carbon monoxide and carbon dioxide may be liberated. Burning produces heavy smoke. 5.3 Advice for fire-fighters Move undamaged containers from immediate hazard area if it can be done safely. Wear suitable breathing apparatus. Wear suitable equipment for self-protection. SECTION 6: Accidental release measures 6.1 Personal precautions Wear protective clothing. Give a warning to persons in the hazard area. Remove all sources of ignition. Avoid contact with skin, eyes and clothing. Maintain adequate ventilation in the working area. 6.2 Environmental precautions Do not discharge into drains, water courses or onto the ground. Prevent spread over a wide area. 6.3 Methods and material for containment and cleaning up Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. Avoid open flames or courses of ignition. Ventilate area and wash spill site after material pickup is complete. Dispose of an in accordance with current laws and regulations. 6.4 References to other sections. Please refer to Section 8 - Exposure controls/personal protection for further information on personal precautions Please refer to Section 13 - Disposal Considerations for further information on waste treatment. Page 3

4 SECTION 7: Handling and Storage 7.1 Precautions for safe handling Handle in accordance with good hygiene and safety practice. Wear personal protective clothing (see chapter 8). Do not breathe gas/fume/vapour/spray. Use only in well-ventilated areas. When using do not eat, drink, smoke, sniff. Provide earthing of containers, equipment, pumps and ventilation facilities. Take precautionary measures against static discharges 7.2 Conditions for safe storage, including any incompatibilities Keep product tightly closed in its original container well sealed, in a dry, ventilated area, away from potential sources of ignition and protected from light. 7.3 Specific end use(s). SECTION 8: Exposure controls/personal protection 8.1 Control Parameters. 8.2 Exposure Controls Eye protection Wear safety goggles according to EN166 Hand protection Wear chemically resistant gloves (PVC) according to EN374 Other protection Wear appropriate clothing to prevent any possibility of skin contact. Wear apron or protective clothing in case of splashes. Avoid contact with skin and eyes. Avoid inhalation of vapours Respiratory Equipment Hygiene Measures Engineering Measures If ventilation is insufficient, use respiratory protection. Good personal hygiene practices are always advisable, especially when working with chemicals/oils. Provide adequate ventilation or respiratory protection. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Mobile oily liquid Colour Colourless to slightly yellow Odour Characteristic Relative Density 20 C Flash Point ( C) > 100 Refractive Index 20 C Melting Point ( C) Boiling Point ( C) Vapour Pressure Solubility in C Auto-ignition temperature ( C) 9.2 Other information Page 4

5 SECTION 10: Stability and reactivity 10.1 Reactivity Avoid contact with strong oxidising agents, strong reducing agents, acids, bases acid anhydrides and alkali metals Chemical stability Stable under the recommended handling and storage conditions Possibility of hazardous reactions No hazardous reactions at proper usage and handling Conditions to avoid Temperatures more than room temperature will benefit the transfer from liquid to vapour phase and formation of explosive atmospheres. Storing the product in open containers will benefit the formation of peroxides and derogate the quality Incompatible materials Hazardous decomposition products No dangerous decomposition products known. SECTION 11: Toxicological information 11.1 Information on toxicological effects. Acute toxicity: LD50 (Oral): LC50 (Dermal): Skin corrosion / irritation: Serious eye damage/irritation: Respiratory or skin sensitisation: Germ cell mutagenicity: Carcinogenicity: Reproductive toxicity: STOT-single exposure: STOT-repeated exposure: Aspiration hazard: Other information: Page 5

6 SECTION 12: Ecological information 12.1 Toxicity 12.2 Persistence and degradability 12.3 Bio-accumulative potential 12.4 Mobility in soil 12.5 Results of PBT and VPVB assessment 12.6 Other adverse effects Do not allow to enter streams, sewers or other waterways. Water hazard Class; WGK-2 SECTION 13: Disposal considerations 13.1 Waste Treatment Methods Collect and dispose of waste product in accordance with local authority guidelines using a hazardous chemical disposal company. Product remainders should not intrude soil or waters. SECTION 14: Transport information Warning Icon Proper Shipping Name EXTRACTS, AROMATIC, LIQUID UN No. Road UN 1169 ADR Class Class 3 Hazard No (ADR) 30 Hazchem Code 3YE UN No. SEA UN 1169 IMDG Class Class 3 IMDG Pack Gr. Pk Gp III EMS F-E, S-D UN No. AIR UN 1169 Air Class Class 3 Air Pack Gr. Pk Gp III Page 6

7 SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Directives Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 th Dec 2006 Concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 199/45/EC and repealing Council Regulation Council Regulation (EEC) No793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, and 93/105/EEC and 2000/21/EC including amendments. Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply Regulations 2009 (S.I No 716). Approved Code of Practice Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG Chemical safety assessment An assessment has not been executed as this is not a hazardous material according to article 31 of REACH 1907/2006. SECTION 16: Other information Training instructions: Refer to possible hazard before use of this product. Abbreviations and acronyms: MSDS INCI CAS IMDG ADR RID ICAO ADN GHS Trem Card STOT Material Safety Data Sheet International Nomenclature of Cosmetic Ingredients Chemical Abstract Service International Maritime Code for Dangerous Goods Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) International Carriage of Dangerous Goods by Rail International Civil Aviation Organization International Carriage of Dangerous Goods by Inland Waterways Globally Harmonized System of Classification and Labelling of Chemicals Transport Emergency Card Specific Target Organ Toxicity Not Available Hazard Statements in full: H224 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. Complies with REACH guidance for SDS as circulated by ECHA Disclaimer This information contained herein is believed to be true and correct at the time of our response. Any views or opinions presented in this document are solely those of the author and do not necessarily represent those of Madar Corporation. Neither can we guarantee the accuracy of any of the information or data contained within. It is not, and should not be construed as, a guarantee or warranty, or a part of our contractual or other legal obligations. Disclosure, reproduction or transmission, in whole or in part, without prior written consent of Madar Corporation is not permitted. Page 7