: Tissue Marking & Margin Dye - Black
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1 Version: 1.0 SECTION 1: Identification 1.1. Identification Trade name Product code : Recommended use and restrictions on use Recommended use Restrictions on use 1.3. Supplier : Tissue Marking & Margin Dye - Black : Identification of surgical margins : Other uses Leica Biosystems Richmond, Inc 5205 Route 12 Richmond, IL USA T LBSNA-LBS-QA@leicabiosystems.com - leicabiosystems.com 1.4. Emergency telephone number Organisation/Company Emergency number ChemTrec International Calls (call collect) Australia 24 Hr Poisons Information Centre SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Serious eye damage/eye irritation, Category 2A Carcinogenicity, Category 2 Causes serious eye irritation Suspected of causing cancer 2.2. GHS Label elements, including precautionary statements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning GHS08 : Causes serious eye irritation Suspected of causing cancer : Obtain special instructions before use Do not handle until all safety precautions have been read and understood Wash thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If exposed or concerned: Get medical advice/attention If eye irritation persists: Get medical advice/attention Store locked up Dispose of contents/container in accordance with all local/regional/national/international 05/11/2018 EN (English) Page 1
2 regulations 2.3. Other hazards which do not result in classification 2.4. Unknown acute toxicity (GHS US) SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % GHS-US classification Formaldehyde (CAS-No.) < 1 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation:vapour), H331 Skin Corr. 1B, H314 Skin Sens. 1, H317 Muta. 2, H341 Carc. 1A, H350 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : IF exposed or concerned: Get medical advice/attention. : Remove person to fresh air and keep comfortable for breathing. : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. : Rinse eyes with water as a precaution. : Call a poison center or a doctor if you feel unwell Most important symptoms and effects (acute and delayed) 4.3. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media 5.2. Specific hazards arising from the chemical Fire hazard Reactivity : Water spray. Dry powder. Foam. Carbon dioxide. : Highly flammable liquid and vapour. : Highly flammable liquid and vapour Special protective equipment and precautions for fire-fighters Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing For non-emergency personnel Emergency procedures : Ventilate spillage area. No open flames, no sparks, and no smoking. 05/11/2018 EN (English) 2/7
3 For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Other information 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public waters. : Dispose of materials or solid residues at an authorized site Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Flammable vapours may accumulate in the container. Use explosion-proof equipment. Wear personal protective equipment. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Technical measures : Ground/bond container and receiving equipment. Storage conditions : Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Appropriate engineering controls Appropriate engineering controls Environmental exposure controls : Ensure good ventilation of the work station. : Avoid release to the environment Individual protection measures/personal protective equipment Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment 05/11/2018 EN (English) 3/7
4 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Black Odour : ammonia Odour threshold ph : Melting point : Freezing point Boiling point Flash point : 212 F Relative evaporation rate (butylacetate=1) Flammability (solid, gas) :. Vapour pressure Relative vapour density at 20 C Relative density Density : Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosive limits Explosive properties Oxidising properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity Highly flammable liquid and vapour Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition Incompatible materials 05/11/2018 EN (English) 4/7
5 10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity ATE US (oral) 100 mg/kg bodyweight ATE US (dermal) 300 mg/kg bodyweight ATE US (vapours) 3 mg/l/4h Skin corrosion/irritation ph: Serious eye damage/irritation : Causes serious eye irritation. ph: Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity : Suspected of causing cancer. IARC group National Toxicity Program (NTP) Status Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard 1 - Carcinogenic to humans 2 - Known Human Carcinogens SECTION 12: Ecological information Toxicity Ecology - general : Harmful to aquatic life Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Bioaccumulative potential Log Pow Bioaccumulative potential Readily biodegradable in water. No (test)data on mobility of the components available. Photodegradation in the air g O₂/g substance 1.06 g O₂/g substance g O₂/g substance Bioaccumulation: not applicable. 05/11/2018 EN (English) 5/7
6 12.4. Mobility in soil Other adverse effects SECTION 13: Disposal considerations Disposal methods Waste treatment methods Additional information : Dispose of contents/container in accordance with licensed collector s sorting instructions. : Flammable vapours may accumulate in the container. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 CERCLA RQ SARA Section 302 Threshold Planning Quantity (TPQ) 100 lb 500 lb International regulations CANADA Listed on the Canadian DSL (Domestic Substances List) EU-Regulations National regulations 05/11/2018 EN (English) 6/7
7 Listed on IARC (International Agency for Research on Cancer) Listed as carcinogen on NTP (National Toxicology Program) Listed on EPA Hazardous Air Pollutant (HAPS) US State regulations Carcinogens List Developmental Toxicity Reproductive Toxicity - Female Reproductive Toxicity - Male No significant risk level (NSRL) Yes No No No 40 µg/day U.S. - New Jersey - Right to Know Hazardous Substance List SECTION 16: Other information Full text of H-statements: H301 H311 H314 H317 H331 H341 H350 Toxic if swallowed Toxic in contact with skin Causes severe skin burns and eye damage May cause an allergic skin reaction Toxic if inhaled Suspected of causing genetic defects May cause cancer SDS US Leica This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 05/11/2018 EN (English) 7/7
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