SAFETY DATA SHEET. Marisol OC. SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 Page 1 (8) Replaces SDS: Issued: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name 1.2. Relevant identified uses of the substance or mixture and uses advised against Use Alkaline cleaning agent Details of the supplier of the safety data sheet Manufacturer Clemondo AB Marisol Street address Box HELSINGBORG SVERIGE Telephone Fax Web site marisol@clemondo.se Emergency telephone number Emergency phone number 999 Available outside office hours Yes SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008, Annex VI Classification Hazard statements Skin corrosion, hazard category 1C H Label elements GHS labeling of the substance (in accordance with Regulation (EC) No 1272/2008, Annex VI) Pictogram Signal word Hazard statements Danger H314 Causes severe skin burns and eye damage.

2 Page 2 (8) Replaces SDS: Issued: Precaution statements P261 Avoid breathing mist and spray. P280 Wear protective gloves. Choose neoprene or nitrile rubber resistant to alkaline liquids. Wear protective clothing and eye protection / face protection. P303 + P352b IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER/doctor if you feel unwell Other hazards SECTION 3: Composition/information on ingredients 3.2. Mixtures Chemical name CAS No. EC No. REACH No. Concentration Classification Rphrase Hphrase 2(2Butoxyethoxy)ethanol Potassium hydroxide Propylheptanol ethoxylate % Eye Irrit. 2 <5% Skin Corr. 1A, Acute Tox. 4 oral <5% Eye Dam. 1 H319 H290, H302, H314 H318 Quaternary C1214 alkylmethylamine ethoxylate methyl chloride <5% Skin Irrit. 2, Eye Dam. 1, Acute Tox. 4 oral H302, H315, H318 Tetrasodium Glutamate Diacetate <5% Met. Corr. 1 H290 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion Fresh air. Rinse the skin immediately with lots of water. Remove contaminated clothing. Immediately rinse with water for at least 15 minutes (eyelids parted) and consult a physician. Since long rinsing time is required, the water must be lukewarm. If the injured person is fully conscious, give him/her a couple of glasses of milk or water immediately. DO NOT INDUCE VOMITING! Consult a physician for specific advice Most important symptoms and effects, both acute and delayed

3 Page 3 (8) Replaces SDS: Issued: The product is classified as corrosive, which contributes to acid burns to skin and eyes, as well as chemical burns if swallowed Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water mist, foam, carbon dioxide, powder Special hazards arising from the substance or mixture No specific hazards Advice for firefighters Special protective equipment for firefighters Containers in the vicinity of fire should be moved immediately or cooled with water. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear suitable protective equipment 6.2. Environmental precautions Prevent entry to sewers and public waters Methods and material for containment and cleaning up Small quantities may be flushed away with water. Major spillage should be banked with sand, earth or similar material and collected into suitable enclosed containers for further incineration Reference to other sections See Section 1 for contact in case of emergency. Personal protection see section 8 and for disposal see section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Preventive handling precautions Avoid contact with eyes Conditions for safe storage, including any incompatibilities Keep in a frostfree place. Plastic packaging Specific end use(s) No information available SECTION 8: Exposure controls/personal protection

4 Page 4 (8) Replaces SDS: Issued: Control parameters National occupational exposure limits CAS No. EC No. Exposure Limit Values ppm / mg/m3 Short term exposure limit ppm / mg/m3 Ceiling Limit Value ppm / mg/m3 Country , ,2 BA BA 8.2. Exposure controls Technical precaution measures Eye / face protection Safety gloves Other skin protection Eye washes must be available. Wear protective goggles if there is a risk of direct contact or splashes. Use suitable protective gloves made of nitrile rubber. Suitable protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance, colour Appearance, physical state Autoignition temperature Decomposition temperature Density Evaporation rate Explosive properties Flammability (solid, gas) Flash point Form Initial boiling point and boiling range Melting point / freezing point Odour Odour treshold Oxidising properties Partition coefficient: noctanol / water Yellow 1040 kg/m3 Liquid slight ph concentrate 13,3

5 Page 5 (8) Replaces SDS: Issued: ph value Relative density Solubility Upper / lower flammability or explosive limits Vapour density Vapour pressure Viscosity Watersoluble 9.2. Other information SECTION 10: Stability and reactivity Reactivity Reactivity No special safety precautions are required Chemical stability Chemical stability Stable under normal usage and storage conditions Possibility of hazardous reactions Possibility of hazardous reactions No dangerous reactions known Conditions to avoid Conditions to avoid No specific hazards Incompatible materials Incompatible materials None known Hazardous decomposition products Hazardous decomposition products No harmful degradation products during normal handling. SECTION 11: Toxicological information Information on toxicological effects acute toxicity skin corrosion/irritation serious eye damage/irritation Ingestion may result in nausea, vomiting and/or diarrhoea. The product is classified as corrosive. The product is classified as corrosive.

6 Page 6 (8) Replaces SDS: Issued: Respiratory/skin sensitization germ cell mutagenicity Genotoxicity carcinogenicity reproductive toxicity STOTsingle exposure STOTrepeated exposure Harmful if inhaled LD50 Oral LD50(Potassium Hydroxide): 273 mg/kg (rat) SECTION 12: Ecological information Toxicity Acute fish toxicity LC50(96h)(Potassium hydroxide): 80 mg/l (Gambusia affinis) LC50(24h)(Potassium Hydroxide): 165 mg/l (Poecilia reticulata) Persistence and degradability Persistence and degradability The component surfactants are easily biodegradable according to Regulation (EC) No 648/2004 on detergents Bioaccumulative potential Bioaccumulative potential Bioaccumulation is unlikely Mobility in soil Mobility No information available Results of PBT and vpvb assessment Results of PBT and vpvb assessment No information available Other adverse effects Other adverse effects No information available Other The product is not classified as environmentally harmful in accordance with EC Regulation 1272/2008. SECTION 13: Disposal considerations Waste treatment methods Disposal considerations The product should be disposed of as hazardous waste. Emptied and cleaned packaging can be recycled.

7 Page 7 (8) Replaces SDS: Issued: Other Waste code (EWC) The waste code (EWC) is a recommendation detergents containing dangerous substances aqueous washing liquids and mother liquors SECTION 14: Transport information UN number UN number UN UN proper shipping name Name IMDG proper shipping name CORROSIVE LIQUID, BASIC, INORGANIC N.O.S. (POTASSIUM HYDROXIDE) CORROSIVE LIQUID BASIC INORGANIC N.O.S. (POTASSIUM HYDROXIDE) Transport hazard class(es) Label 8 ADR / RID Class 8 ADR / RID hazard identification number IMDG EmS 80 ALKALIS Packing group Packing group III Environmental hazards Special precautions for user Transport in bulk according to Annex II of Marpol and the IBC Code Other Road/railroad (ADRRID) Additional information ADRRID Tunnel restriction code: E SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Safety Data Sheet according to regulation (EC) No 1907/ Chemical safety assessment

8 Page 8 (8) Replaces SDS: Issued: Chemical safety assessment No chemical safety assessment has been performed. SECTION 16: Other information Phrase meaning Acute Tox. 4 oral Acute toxicity, oral, hazard category 4 Eye Dam. 1 Serious eye damage, hazard category 1 Eye Irrit. 2 Eye irritation, hazard category 2 Met. Corr. 1 Corrosive to metals, hazard category 1 Skin Corr. 1A Skin corrosion, hazard category 1A Skin Irrit. 2 Skin irritation, hazard category 2 H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation.