SAFETY DATA SHEET according to 1907/2006/EC, Article 31

Transcription

1 SAFETY DATA SHEET according to 1907/2006/EC, Article 31 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name 1.2. Relevant identified uses of the substance or mixture and uses advised against Product Use 1.3. Details of the supplier of the safety data sheet Company 1/7 [SU3] Industrial uses: Uses of substances as such or in preparations at industrial sites; [PC24] Lubricants, greases, release products; [PROC10] Roller application or brushing; [ERC4] Industrial use of processing aids in processes and products, not becoming part of articles; Marbocote Ltd Address Unit 9 Dalton Way MIddlewich Cheshire CW10 0HU UK Web Telephone +44 (0) Fax +44 (0) Emergency telephone number info@marbocote.co.uk Emergency telephone number +44 (0) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification /45/ЕC Main hazards Classification - EC 1272/ Label elements Hazard pictograms Xn; R65 R10-52/ Symbols: Xn: Harmful. Flammable. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. Flam. Liq. 3: H226; Asp. Tox. 1: H304; STOT SE 3: H336; Aquatic Chronic 3: H412; Signal Word Hazard Statement Danger Flam. Liq. 3: H226 - Flammable liquid and vapour. Asp. Tox. 1: H304 - May be fatal if swallowed and enters airways. STOT SE 3: H336 - May cause drowsiness or dizziness. Aquatic Chronic 3: H412 - Harmful to aquatic life with long lasting effects.

2 2.2. Label elements Precautionary Statement: Prevention Precautionary Statement: Response 2.3. Other hazards Other hazards P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P20 - Wear protective gloves/protective clothing/eye protection/face protection. 2/7 P301+P310 - IF SWALLOWED: IF SWALLOWED: Immediately call a POISON CENTER/doctor/. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P370+P37 - In case of fire: Use powder to extinguish. EUH066 - Repeated exposure may cause skin dryness or cracking. SECTION 3: Composition/information on ingredients 3.2. Mixtures 67/54/EEC / 1999/45/EC Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Hydrocarbons, C9-C10, n-alkanes, % Xn; R65 R10-52/ isoalkanes, cyclics, <2% aromatics M-factor. EC 1272/200 Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Hydrocarbons, C9-C10, n-alkanes, % EUH066; Flam. Liq. 3: H226; isoalkanes, cyclics, <2% aromatics Asp. Tox. 1: H304; STOT SE 3: H336; Aquatic Chronic 3: H412; M-factor. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Eye contact Skin contact Ingestion Note: Any entry in the EC# column that begins with the number "9" is a Provisional List Number provided by ECHA pending publication of the official EC Inventory Number for the substance. See Section 15 for additional CAS number information for the substance. Move the exposed person to fresh air. Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Remove contaminated clothing. Wash off immediately with plenty of soap and water. DO NOT INDUCE VOMITING. Rinse mouth thoroughly Most important symptoms and effects, both acute and delayed Inhalation Eye contact Skin contact Ingestion Vapours may cause drowsiness and dizziness. May cause irritation to eyes. May cause irritation to skin. Harmful: may cause lung damage if swallowed Indication of any immediate medical attention and special treatment needed Inhalation Eye contact Skin contact Ingestion General information SECTION 5: Firefighting measures 5.1. Extinguishing media If medical advice is needed, have product container or label at hand. Seek medical attention if irritation or symptoms persist. Seek medical attention if irritation or symptoms persist. Immediate medical attention is required. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

3 5.1. Extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters SECTION 6: Accidental release measures Use as appropriate: Carbon dioxide (CO2), Dry chemical, Foam. Do NOT use water jet. 3/7 Burning produces irritating, toxic and obnoxious fumes. Risk of explosion by shock, friction, fire or other sources of ignition. Self-contained breathing apparatus. Wear protective gloves/protective clothing/eye protection/face protection. Flammable liquid and vapour. Vapour may travel considerable distance to source of ignition and flash back. Cool fire exposed containers with waterspray. See section for further information Personal precautions, protective equipment and emergency procedures 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Eliminate all sources of ignition. Ensure adequate ventilation of the working area. Evacuate personnel to a safe area. Wear suitable protective equipment. Take precautionary measures against static discharges. Do not allow product to enter drains. Prevent further spillage if safe. Absorb with inert, absorbent material. Use explosion proof equipment. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. Do not allow runoff water to enter sewers or drains. See section and 13 for further information Conditions for safe storage, including any incompatibilities Suitable packaging 7.3. Specific end use(s) Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges. Use explosion proof equipment. Keep container tightly closed. Keep in a cool, dry, well ventilated area. Store in correctly labelled containers. Store in original container. Industrial Mould Release Agent. SECTION : Exposure controls/personal protection.1. Control parameters.1.1. Exposure Limit Values Hydrocarbons, C9-C10, n-alkanes, isoalkanes, cyclics, <2% aromatics WEL -hr limit ppm: 226 WEL -hr limit mg/m3: 1200 WEL 15 min limit ppm: WEL 15 min limit mg/m3: WEL -hr limit mg/m3 total - WEL 15 min limit mg/m3 total - inhalable dust: inhalable dust: WEL -hr limit mg/m3 total - WEL 15 min limit mg/m3 total - respirable dust: respirable dust:

4 .2. Exposure controls.2.1. Appropriate engineering controls.2.2. Individual protection measures Eye / face protection Skin protection - Handprotection Skin protection - Other Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Adopt best Manual Handling considerations when handling, carrying and dispensing. Wear chemical protective clothing. Suitable foot protection e.g. boots. safety glasses with side-shields. Chemical resistant gloves. After contact with skin, wash immediately with plenty of soap and water. 4/7 Wear suitable respiratory equipment when necessary. Suitable half mask respirator with filter P3 (EN 141A1/A2). SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Liquid Colour Clear/Colourless Odour Characteristic Odour threshold No data available ph No data available Melting point No data available Freezing Point No data available Initial boiling point No data available Flash point 26 C Evaporation rate No data available Flammability (solid, gas) No data available Upper Explosive Limit No data available Lower Explosive Limit No data available Vapour pressure No data available Vapour density KPa/air=1 Miscible in Organic Solvents Partition coefficient No data available Autoignition temperature No data available 9.2. Other information Viscosity No data available Explosive properties No data available Oxidising properties No data available Specific gravity g/cm³ VOC (Volatile organic compounds) g/l SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials See section below for further information. Stable under normal conditions. Will not polymerize. Avoid sparks, flames, heat and sources of ignition. Take precautionary measures against static discharges.

5 10.5. Incompatible materials Strong oxidising agents Hazardous decomposition products Will not decompose if stored and used as recommended. 5/7 SECTION 11: Toxicological information Information on toxicological effects Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard Repeated or prolonged exposure Toxicological Information Prolonged or repeated exposure may cause: Irritant, moderate skin. May cause irritation to eyes. No sensitizaton effects reported. No mutagenic effects reported. No carcinogenic effects reported. No teratogenic effects reported. May cause drowsiness or dizziness. Not expected to cause organ damage from prolonged or repeated exposure. May be fatal if swallowed and enters airways. Prolonged or repeated exposure may cause: Skin irritation and dermatitis. Hydrocarbons, C9-C10, n-alkanes, isoalkanes, cyclics, <2% aromatics Inhalation Rat LC50/4 h: >4951mg/m3 Dermal Rabbit LD50: >5000mg/kg Oral Rat LD50: >5000mg/kg Information on likely routes of exposure Dermal. Inhalation. Exposure above the recommended occupational exposure limit (OEL) may cause adverse health effects. vapour. May cause dizziness and headache. Inhalation is irritating to the respiratory tract and may cause damage to the central nervous system. Irritating to eyes. SECTION 12: Ecological information Toxicity Hydrocarbons, C9-C10, n-alkanes, isoalkanes, cyclics, <2% aromatics Algae LC50/96h: >1000mg/l Rainbow trout LC50/96h: 10-30mg/l Daphnia LC50/4h: 22-46mg/l Persistence and degradability Bioaccumulative potential Readily biodegradable. Partition coefficient No data is available on this product. No data available Mobility in soil No data is available on this product Results of PBT and vpvb assessment This product is not, or does not contain a substance that is a PBT or a vpvb.

6 6/ Other adverse effects None. SECTION 13: Disposal considerations General information Disposal methods Disposal of packaging SECTION 14: Transport information Hazard pictograms Dispose of in compliance with all local and national regulations. Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. This material and its container must be disposed of as hazardous waste. Do NOT reuse empty containers UN number UN UN proper shipping name FLAMMABLE LIQUID, N.O.S. (Hydrocarbons, C9-C10, N-Alkanes, cyclics, <2% aromatics) Transport hazard class(es) ADR/RID 3 Subsidiary risk - IMDG 3 Subsidiary risk - IATA 3 Subsidiary risk Packing group Packing group III Environmental hazards Environmental hazards No Marine pollutant No Special precautions for user Not applicable Transport in bulk according to Annex II of MARPOL 73/7 and the IBC Code Not applicable. ADR/RID Hazard ID 30 Tunnel Category (D/E) IMDG EmS Code F-E S-E IATA

7 7/7 IATA Packing Instruction (Cargo) 366 Maximum quantity 220 L Packing Instruction (Passenger) 355 Maximum quantity 60 L SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Regulations Chemical safety assessment SECTION 16: Other information Other information Text of risk phrases in Section 3 Text of Hazard Statements in Section 3 Maximum content of VOC COMMISSION REGULATION (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 14/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC. REGULATION (EC) No 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 1 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 14/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC. No chemical safety assessment has been processed for the mixture and the substances it contains. The following substance(s) in this product is (are) identified by the CAS number(s) shown in countries not subject to the REACH regulation. Hydrocarbons, C9-C10, n-alkanes, isoalkanes, cyclics, <2% aromatics. ( CAS ). R10 - Flammable R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 - Harmful: may cause lung damage if swallowed. R66 - Repeated exposure may cause skin dryness or cracking. R67 - Vapours may cause drowsiness and dizziness. EUH066 - Repeated exposure may cause skin dryness or cracking. Flam. Liq. 3: H226 - Flammable liquid and vapour. Asp. Tox. 1: H304 - May be fatal if swallowed and enters airways. STOT SE 3: H336 - May cause drowsiness or dizziness. Aquatic Chronic 3: H412 - Harmful to aquatic life with long lasting effects g/l.