Amcos Wavol 10VOL Creme Peroxide

Transcription

1 Amcos hemwatch Hazard Alert ode: 1 Safety Data Sheet according to WHS and ADG requirements S.GHS.AUS.EN SETION 1 IDENTIFIATION OF THE SUBSTANE / MIXTURE AND OF THE OMPAN / UNDERTAKING Product Identifier Product name Other means of identification Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses SDS are intended for use in the workplace. For domestic-use products, refer to consumer labels. For hair dyes. Details of the supplier of the safety data sheet Registered company name Amcos Address Building 3, 129 Long Street Smithfield NSW 2164 Australia Telephone Fax Website Emergency telephone number Association / Organisation Emergency telephone numbers Other emergency telephone numbers SETION 2 HAZARDS IDENTIFIATION lassification of the substance or mixture HAZARDOUS HEMIAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG ode. HEMWATH HAZARD RATINGS Flammability 0 Toxicity 0 Body ontact 1 Reactivity 0 hronic 0 Min Max 0 = Minimum 1 = Low 2 = Moderate 3 = High 4 = Extreme Poisons Schedule lassification [1] Skin orrosion/irritation ategory 1A, Serious Eye Damage ategory 1 1. lassified by hemwatch; 2. lassification drawn from HSIS ; 3. lassification drawn from E Directive 1272/ Annex VI Label elements GHS label elements SIGNAL WORD DANGER Hazard statement(s) H314 H318 auses severe skin burns and eye damage. auses serious eye damage.

2 Page 2 of 7 Precautionary statement(s) Prevention P260 P280 Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Precautionary statement(s) Response P301+P330+P331 P303+P361+P353 P305+P351+P338 P310 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. ontinue rinsing. Immediately call a POISON ENTER or doctor/physician. Precautionary statement(s) Storage P405 Store locked up. Precautionary statement(s) Disposal P501 Dispose of contents/container in accordance with local regulations. SETION 3 OMPOSITION / INFORMATION ON INGREDIENTS Substances See section below for composition of Mixtures Mixtures AS No %[weight] Name <4 hydrogen peroxide >60 Ingredients determined not to be hazardous SETION 4 FIRST AID MEASURES Description of first aid measures Eye ontact Skin ontact Inhalation Ingestion If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin or hair contact occurs: Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SETION 5 FIREFIGHTING MEASURES Extinguishing media There is no restriction on the type of extinguisher which may be used. Special hazards arising from the substrate or mixture Fire Incompatibility Avoid contamination / mixing with oxidising agents as ignition may result Advice for firefighters Fire Fighting Fire/Explosion Hazard Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water courses. Use fire fighting procedures suitable for surrounding area. The material is not readily combustible under normal conditions. However, it will break down under fire conditions and the organic component may burn. Not considered to be a significant fire risk. Heat may cause expansion or decomposition with violent rupture of containers. Decomposes on heating and produces toxic fumes of:, carbon dioxide (O2)

3 Page 3 of 7 HAZHEM, other pyrolysis products typical of burning organic material. May emit poisonous fumes. SETION 6 AIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures See section 8 Environmental precautions See section 12 Methods and material for containment and cleaning up Minor Spills Major Spills Slippery when spilt. lean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. ontrol personal contact with the substance, by using protective equipment. ontain and absorb spill with sand, earth, inert material or vermiculite. Slippery when spilt. Minor hazard. lear area of personnel. Alert Fire Brigade and tell them location and nature of hazard. ontrol personal contact with the substance, by using protective equipment as required. Personal Protective Equipment advice is contained in Section 8 of the SDS. SETION 7 HANDLING AND STORAGE Precautions for safe handling Safe handling Other information Limit all unnecessary personal contact. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. When handling DO NOT eat, drink or smoke. Protect from light. Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers. onditions for safe storage, including any incompatibilities Suitable container Storage incompatibility Plastic container heck that containers are clearly labelled Avoid storage with reducing agents. Avoid metallic bowls and stirrers. SETION 8 EXPOSURE ONTROLS / PERSONAL PROTETION ontrol parameters OUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA Source Ingredient Material name TWA STEL Peak Notes Australia Exposure Standards hydrogen peroxide Hydrogen peroxide 1.4 mg/m3 / 1 ppm EMERGEN LIMITS Ingredient Material name TEEL-1 TEEL-2 TEEL-3 hydrogen peroxide Hydrogen peroxide Ingredient Original IDLH Revised IDLH hydrogen peroxide 75 ppm 75 [Unch] ppm Ingredients determined not to be hazardous Exposure controls Appropriate engineering controls Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment.

4 Page 4 of 7 Personal protection Eye and face protection Skin protection Hands/feet protection Body protection Other protection Thermal hazards No special equipment for minor exposure i.e. when handling small quantities. OTHERWISE: Safety glasses with side shields. ontact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. See Hand protection below Wear protective gloves, e.g. PV. See Other protection below No special equipment needed when handling small quantities. OTHERWISE: Overalls. Barrier cream. Eyewash unit. Recommended material(s) GLOVE SELETION INDEX Glove selection is based on a modified presentation of the: "Forsberg lothing Performance Index". The effect(s) of the following substance(s) are taken into account in the computergenerated selection: Respiratory protection Type AB-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent) Where the concentration of gas/particulates in the breathing zone, approaches or exceeds the "Exposure Standard" (or ES), respiratory protection is required. Degree of protection varies with both face-piece and lass of filter; the nature of protection varies with Type of filter. Material BUTL NAT+NEOPR+NITRILE NATURAL RUBBER NATURAL+NEOPRENE NEOPRENE NEOPRENE/NATURAL NITRILE NITRILE+PV PE/EVAL/PE PVA PV VITON PI Required Minimum Protection Factor Half-Face Respirator up to 10 x ES AB-AUS P2 - up to 50 x ES - Full-Face Respirator AB-AUS / lass 1 P2 Powered Air Respirator AB-PAPR-AUS / lass 1 P2 up to 100 x ES - AB-2 P2 AB-PAPR-2 P2 ^ ^ - Full-face A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(hn), B3 = Acid gas or hydrogen cyanide(hn), E = Sulfur dioxide(so2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 deg) - * PI - hemwatch Performance Index A: Best Selection B: Satisfactory; may degrade after 4 hours continuous immersion : Poor to Dangerous hoice for other than short term immersion NOTE: As a series of factors will influence the actual performance of the glove, a final selection must be based on detailed observation. - * Where the glove is to be used on a short term, casual or infrequent basis, factors such as "feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise be unsuitable following long-term or frequent use. A qualified practitioner should be consulted. SETION 9 PHSIAL AND HEMIAL PROPERTIES Information on basic physical and chemical properties Appearance White creamy emulsion; mixes with water. Physical state Liquid Relative density (Water = 1) Odour Odour threshold ph (as supplied) * Melting point / freezing point ( ) Initial boiling point and boiling range ( ) Partition coefficient n-octanol / water Auto-ignition temperature ( ) Decomposition temperature Viscosity (cst) Molecular weight (g/mol) Flash point ( ) Taste Evaporation rate Explosive properties

5 Page 5 of 7 Upper Explosive Limit (%) Flammability Oxidising properties Surface Tension (dyn/cm or mn/m) Lower Explosive Limit (%) Volatile omponent (%vol) Vapour pressure (kpa) Gas group Solubility in water (g/l) Miscible ph as a solution (1%) Vapour density (Air = 1) VO g/l SETION 10 STABILIT AND REATIVIT Reactivity See section 7 hemical stability Possibility of hazardous reactions Unstable in the presence of incompatible materials. Product is considered stable. Hazardous polymerisation will not occur. See section 7 onditions to avoid See section 7 Incompatible materials See section 7 Hazardous decomposition products See section 5 SETION 11 TOXIOLOGIAL INFORMATION Information on toxicological effects Inhaled Ingestion Skin ontact Eye hronic Not normally a hazard due to non-volatile nature of product onsidered an unlikely route of entry in commercial/industrial environments Ingestion may result in nausea, abdominal irritation, pain and vomiting No adverse effects anticipated from normal use. The liquid may produce eye discomfort causing smarting, pain and redness. No adverse effects anticipated from normal use. As with any chemical product, contact with unprotected bare skin; inhalation of vapour, mist or dust in work place atmosphere; or ingestion in any form, should be avoided by observing good occupational work practice. Amcos Wavol 10VOL reme Peroxide TOXIIT IRRITATION hydrogen peroxide TOXIIT dermal (rat) LD50: mg/kg [1] Inhalation (rat) L50: 2 mg/l/4hr [2] Oral (rat) LD50: 75 mg/kg [1] IRRITATION 1. Value obtained from Europe EHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTES - Register of Toxic Effect of chemical Substances No significant acute toxicological data identified in literature search. HDROGEN PEROXIDE Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS. Exposure to hydrogen peroxide via the skin or oral route can produce toxic effects. Animal studies have shown evidence of damage to the kidney, gut, thymus and liver. Stomach and intestinal lesions including benign and malignant cancers have been observed in mice. It may produce genetic and developmental defects but no reproductive toxicity was reported in mice. The substance is classified by IAR as Group 3: NOT classifiable as to its carcinogenicity to humans. Evidence of carcinogenicity may be inadequate or limited in animal testing. Acute Toxicity Skin Irritation/orrosion Serious Eye Damage/Irritation Respiratory or Skin sensitisation Mutagenicity arcinogenicity Reproductivity STOT - Single Exposure STOT - Repeated Exposure Aspiration Hazard Data available but does not fill the criteria for classification Data required to make classification available Data to make classification

6 Page 6 of 7 SETION 12 EOLOGIAL INFORMATION Toxicity Ingredient Endpoint Test Duration (hr) Species Value Source hydrogen peroxide L50 96 Fish 0.020mg/L 3 hydrogen peroxide E50 48 rustacea 2.32mg/L 4 hydrogen peroxide E50 72 Algae or other aquatic plants 0.71mg/L 4 hydrogen peroxide E50 3 Algae or other aquatic plants 0.27mg/L 4 hydrogen peroxide NOE 192 Fish 0.028mg/L 4 Extracted from 1. IULID Toxicity Data 2. Europe EHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. EETO Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data DO NOT discharge into sewer or waterways. Persistence and degradability Ingredient Persistence: Water/Soil Persistence: Air hydrogen peroxide LOW LOW Bioaccumulative potential Ingredient Bioaccumulation hydrogen peroxide LOW (LogKOW = ) Mobility in soil Ingredient Mobility hydrogen peroxide LOW (KO = 14.3) SETION 13 DISPOSAL ONSIDERATIONS Waste treatment methods Product / Packaging disposal Recycle wherever possible or consult manufacturer for recycling options. onsult State Land Waste Management Authority for disposal. Bury residue in an authorised landfill. Recycle containers if possible, or dispose of in an authorised landfill. SETION 14 TRANSPORT INFORMATION Labels Required Marine Pollutant HAZHEM NO Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Air transport (IAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Sea transport (IMDG-ode / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Transport in bulk according to Annex II of MARPOL and the IB code SETION 15 REGULATOR INFORMATION Safety, health and environmental regulations / legislation specific for the substance or mixture HDROGEN PEROXIDE( ) IS FOUND ON THE FOLLOWING REGULATOR LISTS Australia Exposure Standards Australia Hazardous Substances Information System - onsolidated Lists Australia Inventory of hemical Substances (AIS) International Agency for Research on ancer (IAR) - Agents lassified by the IAR Monographs International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited List Passenger and argo Aircraft National Inventory Australia - AIS anada - DSL anada - NDSL hina - IES Europe - EINE / ELINS / NLP Status N (hydrogen peroxide)

7 Page 7 of 7 Japan - ENS Korea - KEI New Zealand - NZIo Philippines - PIS USA - TSA = All ingredients are on the inventory N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets) SETION 16 OTHER INFORMATION Other information lassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the hemwatch lassification committee using available literature references. A list of reference resources used to assist the committee may be found at: The SDS is a Hazard ommunication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered. Definitions and abbreviations P-TWA: Permissible oncentration-time Weighted Average P-STEL: Permissible oncentration-short Term Exposure Limit IAR: International Agency for Research on ancer AGIH: American onference of Governmental Industrial Hygienists STEL: Short Term Exposure Limit TEEL: Temporary Emergency Exposure Limit IDLH: Immediately Dangerous to Life or Health oncentrations OSF: Odour Safety Factor NOAEL :No Observed Adverse Effect Level LOAEL: Lowest Observed Adverse Effect Level TLV: Threshold Limit Value LOD: Limit Of Detection OTV: Odour Threshold Value BF: Biooncentration Factors BEI: Biological Exposure Index This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the opyright Act, no part may be reproduced by any process without written permission from HEMWATH. TEL (+61 3) end of SDS