FLEADO004A-Rudduck's Flea Shampoo 5L

Transcription

1 Prowash Australia hemwatch Hazard Alert ode: 0 hemwatch: Material Safety Data Sheet according to NOHS and ADG requirements Initial Date: S.Local.AUS.EN SETION 1 IDENTIFIATION OF THE SUBSTANE / MIXTURE AND OF THE OMPAN / UNDERTAKING Product Identifier Product name Synonyms APVMA ode: Other means of identification Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Animal shampoo used in the treatment of fleas and lice. Details of the manufacturer/importer Registered company name Prowash Australia Address Flight Drive Tullamarine 3043 VI Australia Telephone Fax Website Emergency telephone number Association / Organisation Emergency telephone numbers Other emergency telephone numbers (BH) SETION 2 HAZARDS IDENTIFIATION lassification of the substance or mixture NON-HAZARDOUS SUBSTANE. NON-DANGEROUS GOODS. According to NOHS riteria, and ADG ode. HEMWATH HAZARD RATINGS Flammability 0 Toxicity 0 Body ontact 0 Reactivity 0 hronic 0 Min Max 0 = Minimum 1 = Low 2 = Moderate 3 = High 4 = Extreme Poisons Schedule Risk Phrases [1] R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Legend: 1. lassified by hemwatch; 2. lassification drawn from HSIS ; 3. lassification drawn from E Directive 1272/ Annex VI Relevant risk statements are found in section 2 Indication(s) of danger SAFET ADVIE S02 S35 S56 Keep out of reach of children. This material and its container must be disposed of in a safe way. Dispose of this material and its container at hazardous or special waste collection point. Other hazards umulative effects may result following exposure*. SETION 3 OMPOSITION / INFORMATION ON INGREDIENTS ontinued...

2 Page 2 of 6 Substances See section below for composition of Mixtures Mixtures AS No %[weight] Name piperonyl butoxide surfactants, unregulated <10 Ingredients determined not to be hazardous balance water The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. SETION 4 FIRST AID MEASURES Description of first aid measures Eye ontact Skin ontact Inhalation Ingestion If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin or hair contact occurs: Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SETION 5 FIREFIGHTING MEASURES Extinguishing media There is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area. Special hazards arising from the substrate or mixture Fire Incompatibility None known. Advice for firefighters Fire Fighting Fire/Explosion Hazard Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water courses. Use fire fighting procedures suitable for surrounding area. Non combustible. Not considered a significant fire risk, however containers may burn. Decomposes on heating and produces:, carbon monoxide (O), carbon dioxide (O2), sulfur oxides (SOx), nitrogen oxides (NOx) SETION 6 AIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Minor Spills Major Spills lean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. ontrol personal contact with the substance, by using protective equipment. ontain and absorb spill with sand, earth, inert material or vermiculite. Moderate hazard. lear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Personal Protective Equipment advice is contained in Section 8 of the MSDS. SETION 7 HANDLING AND STORAGE Precautions for safe handling ontinued...

3 Page 3 of 6 Safe handling Other information Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers. onditions for safe storage, including any incompatibilities Suitable container Storage incompatibility Polyethylene or polypropylene container. Packing as recommended by manufacturer. heck all containers are clearly labelled and free from leaks. None known X Must not be stored together 0 May be stored together with specific preventions + May be stored together PAKAGE MATERIAL INOMPATIBILITIES SETION 8 EXPOSURE ONTROLS / PERSONAL PROTETION ontrol parameters OUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA EMERGEN LIMITS Ingredient Material name TEEL-1 TEEL-2 TEEL-3 piperonyl butoxide Piperonyl butoxide 1.2 mg/m3 13 mg/m mg/m3 Ingredient Original IDLH Revised IDLH piperonyl butoxide surfactants, unregulated Ingredients determined not to be hazardous water Exposure controls Appropriate engineering controls Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Personal protection Eye and face protection Skin protection Hands/feet protection Body protection Other protection Safety glasses with side shields hemical goggles. ontact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. See Hand protection below The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed when making a final choice. Suitability and durability of glove type is dependent on usage. See Other protection below Overalls. P.V.. apron. Barrier cream. ontinued...

4 Page 4 of 6 Thermal hazards Recommended material(s) GLOVE SELETION INDEX Glove selection is based on a modified presentation of the: "Forsberg lothing Performance Index". The effect(s) of the following substance(s) are taken into account in the computergenerated selection: Respiratory protection Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent) Where the concentration of gas/particulates in the breathing zone, approaches or exceeds the "Exposure Standard" (or ES), respiratory protection is required. Degree of protection varies with both face-piece and lass of filter; the nature of protection varies with Type of filter. Material BUTL NATURAL RUBBER NEOPRENE PVA VITON PI Required Minimum Protection Factor Half-Face Respirator up to 10 x ES A-AUS P2 - up to 50 x ES - Full-Face Respirator A-AUS / lass 1 P2 Powered Air Respirator A-PAPR-AUS / lass 1 P2 up to 100 x ES - A-2 P2 A-PAPR-2 P2 ^ - * PI - hemwatch Performance Index A: Best Selection B: Satisfactory; may degrade after 4 hours continuous immersion : Poor to Dangerous hoice for other than short term immersion NOTE: As a series of factors will influence the actual performance of the glove, a final selection must be based on detailed observation. - * Where the glove is to be used on a short term, casual or infrequent basis, factors such as "feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise be unsuitable following long-term or frequent use. A qualified practitioner should be consulted. ^ - Full-face A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(hn), B3 = Acid gas or hydrogen cyanide(hn), E = Sulfur dioxide(so2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 deg) SETION 9 PHSIAL AND HEMIAL PROPERTIES Information on basic physical and chemical properties Appearance Honey-coloured liquid with a pleasant rose fragrance; mixes with water. Physical state Liquid Relative density (Water = 1) ~1.0 Odour Odour threshold ph (as supplied) 7.0 Melting point / freezing point ( ) Initial boiling point and boiling range ( ) Partition coefficient n-octanol / water Auto-ignition temperature ( ) Decomposition temperature ~0 Viscosity (cst) ~100 Molecular weight (g/mol) Flash point ( ) Taste Evaporation rate Explosive properties Upper Explosive Limit (%) Flammability Oxidising properties Surface Tension (dyn/cm or mn/m) Lower Explosive Limit (%) Volatile omponent (%vol) Vapour pressure (kpa) 20 Gas group Solubility in water (g/l) Miscible ph as a solution (1%) Vapour density (Air = 1) VO g/l SETION 10 STABILIT AND REATIVIT Reactivity See section 7 hemical stability Possibility of hazardous reactions Unstable in the presence of incompatible materials. Product is considered stable. Hazardous polymerisation will not occur. See section 7 onditions to avoid See section 7 Incompatible materials See section 7 Hazardous decomposition products See section 5 SETION 11 TOXIOLOGIAL INFORMATION Information on toxicological effects ontinued...

5 Page 5 of 6 Inhaled Ingestion Skin ontact Eye hronic The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by E Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting. The material has NOT been classified by E Directives or other classification systems as "harmful by ingestion". This is because of the lack of corroborating animal or human evidence. The material is not thought to produce adverse health effects or skin irritation following contact (as classified by E Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting. Open cuts, abraded or irritated skin should not be exposed to this material Although the liquid is not thought to be an irritant (as classified by E Directives), direct contact with the eye may produce transient discomfort characterised by tearing or conjunctival redness (as with windburn). Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure. As with any chemical product, contact with unprotected bare skin; inhalation of vapour, mist or dust in work place atmosphere; or ingestion in any form, should be avoided by observing good occupational work practice. FLEADO004A-Rudduck's Flea Shampoo 5L TOXIIT IRRITATION piperonyl butoxide TOXIIT dermal (rat) LD50: >7950 mg/kg [2] Inhalation (rat) L50: >5.9 mg/l4 h [1] Oral (rat) LD50: 5630 mg/kg [1] IRRITATION water TOXIIT Oral (rat) LD50: >90000 mg/kg [2] IRRITATION Legend: 1. Value obtained from Europe EHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's msds. Unless otherwise specified data extracted from RTES - Register of Toxic Effect of chemical Substances PIPERONL BUTOXIDE The substance is classified by IAR as Group 3: NOT classifiable as to its carcinogenicity to humans. Evidence of carcinogenicity may be inadequate or limited in animal testing. Dermal (rabbit) LD50: >1880 mg/kg [Handbook of Toxicology] *Published value - probably not peer-reviewed ADI: 0.03 mg/kg WATER No significant acute toxicological data identified in literature search. Acute Toxicity Skin Irritation/orrosion Serious Eye Damage/Irritation Respiratory or Skin sensitisation Mutagenicity arcinogenicity Reproductivity STOT - Single Exposure STOT - Repeated Exposure Aspiration Hazard Legend: Data required to make classification available Data available but does not fill the criteria for classification Data to make classification MR STATUS SETION 12 EOLOGIAL INFORMATION Toxicity Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. DO NOT discharge into sewer or waterways. Persistence and degradability Ingredient Persistence: Water/Soil Persistence: Air piperonyl butoxide HIGH HIGH water LOW LOW Bioaccumulative potential Ingredient Bioaccumulation piperonyl butoxide HIGH (LogKOW = 4.75) water LOW (LogKOW = -1.38) Mobility in soil Ingredient Mobility piperonyl butoxide LOW (KO = 69.74) ontinued...

6 Page 6 of 6 water LOW (KO = 14.3) SETION 13 DISPOSAL ONSIDERATIONS Waste treatment methods Product / Packaging disposal Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. A Hierarchy of ontrols seems to be common - the user should investigate: Reduction Reuse Recycling Disposal (if all else fails) This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. SETION 14 TRANSPORT INFORMATION Labels Required Marine Pollutant HAZHEM NO Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Air transport (IAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Sea transport (IMDG-ode / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS SETION 15 REGULATOR INFORMATION Safety, health and environmental regulations / legislation specific for the substance or mixture piperonyl butoxide( ) is found on the following regulatory lists water( ) is found on the following regulatory lists "Australia Inventory of hemical Substances (AIS)","International Agency for Research on ancer (IAR) - Agents lassified by the IAR Monographs","Australia Hazardous Substances Information System - onsolidated Lists" "Australia Inventory of hemical Substances (AIS)" National Inventory Australia - AIS anada - DSL hina - IES Europe - EINE / ELINS / NLP Japan - ENS Korea - KEI New Zealand - NZIo Philippines - PIS USA - TSA Legend: Status N (water) = All ingredients are on the inventory N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets) SETION 16 OTHER INFORMATION Other information lassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the hemwatch lassification committee using available literature references. A list of reference resources used to assist the committee may be found at: The (M)SDS is a Hazard ommunication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the opyright Act, no part may be reproduced by any process without written permission from HEMWATH. TEL (+61 3) end of SDS