SAFETY DATA SHEET 613

Transcription

1 1 SAFETY DATA SHEET 1 IDENTIFICATION OF THE SUBSTANCEPREPARATION AND OF THE COMPANYUNDERTAKING PRODUCT NAME PRODUCT NO , , SUPPLIER BOSTIK LIMITED COMMON ROAD STAFFORD STAFFORDSHIRE ST16 EH (24Hour Emergency) sds.uk@bostik.com 2 HAZARDS IDENTIFICATION Highly flammable. Vapours may cause drowsiness and dizziness. Irritating to eyes and skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. CLASSIFICATION Xi;R68. F;R11. N;R1. R67. COMPOSITIONINFORMATION ON INGREDIENTS Name EC No. CAS-No. Content Classification BUTANONE % F;R11 Xi;R6 R66 R67 CYCLOHEXANE % F;R11 Xn;R6 Xi;R8 R67 N;R0 ETHYL ACETATE % F;R11 Xi;R6 R66 R67 FORMALDEHYDE...% < 1% Carc;R40 T;R2242 C;R4 R4 HEPTANE AND ISOMERS -10% Xn;R6. Xi;R8. F;R11. N;R0. R67. HEXANE, MIXTURE OF ISOMERS 1-% Xn;R6. Xi;R8. F;R11. N;R1. R67. HEXANE-norm METHYLCYCLOHEXANE < 1% % F;R11 Repr;R62 Xn;R6,R4820 Xi;R8 R67 N;R1 F;R11 Xn;R6 Xi;R8 R67 N;R1 N-HEXANE PENTANE < 1% < 1% F;R11 Repr;R62 Xn;R6,R4820 Xi;R8 R67 N;R1 F+;R12 Xn;R6 R66 R67 N;R1 PROPAN-2-OL < 1% F;R11 Xi;R6 R67 ROSIN < 1% R4 XYLENE < 1% R10 Xn;R2021 Xi;R8 The Full Text for all R-Phrases are Displayed in Section 16 4 FIRST-AID MEASURES INHALATION Remove victim immediately from source of exposure. Move the exposed person to fresh air at once. Get medical attention. INGESTION DO NOT induce vomiting. Get medical attention immediately. SKIN CONTACT Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove clothing if soaked through and wash as above. Get medical attention if irritation persists after washing.

2 EYE CONTACT Rinse the eye with water immediately. Continue to rinse for at least 1 minutes and get medical attention. FIRE-FIGHTING MEASURES 2 EXTINGUISHING MEDIA Fire can be extinguished using: Foam, carbon dioxide or dry powder. SPECIAL FIRE FIGHTING PROCEDURES Fight advanced or massive fires from safe distance or protected location. Keep run-off water out of sewers and water sources. Dike for water control. Ventilate closed spaces before entering them. Keep up-wind to avoid fumes. UNUSUAL FIRE & EXPLOSION HAZARDS May travel considerable distance to source of ignition and flash back. Heat may cause the containers to explode. Solvent vapours may form explosive mixtures with air. Vapours are heavier than air and may spread near ground to sources of ignition. SPECIFIC HAZARDS Toxic gasesvapoursfumes of Carbon dioxide (CO2). Carbon monoxide (CO). PROTECTIVE MEASURES IN FIRE Wear self contained breathing apparatus 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Avoid skin and eye contact. Ensure adequate ventilation. Wear personal protective equipment. Wear self contained breathing apparatus. Avoid breathing vapour ENVIRONMENTAL PRECAUTIONS Prevent entry into drains and water courses. SPILL CLEAN UP METHODS Absorb onto sand, earth or abosorbent granules.pick up with non-sparking tools and place into metal containers with sealable lids.mark containers with details of hazards and store in designated area ready for disposal. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. STORAGE PRECAUTIONS Flammablecombustible - Keep away from oxidisers, heat and flames. Ground container and transfer equipment to eliminate static electric sparks. Store at moderate temperatures in dry, well ventilated area. STORAGE CLASS Flammable liquid storage. 8 EXPOSURE CONTROLSPERSONAL PROTECTION Name BUTANONE CYCLOHEXANE Std LT - ppm LT - mgm ST - ppm ST - mgm 200 ppm(sk) 600 mgm(sk) 00 ppm(sk) 899 mgm(sk) 100 ppm 0 mgm 00 ppm 100 mgm ETHYL ACETATE 200 ppm 400 ppm FORMALDEHYDE...% 2 ppm 2. mgm 2 ppm 2. mgm HEXANE-norm N-HEXANE PENTANE 20 ppm 72 mgm 20 ppm 72 mgm 600 ppm 1800 mgm PROPAN-2-OL XYLENE 400 ppm 999 mgm 00 ppm 120 mgm 0 ppm(sk) 220 mgm(sk) 100 ppm(sk) 441 mgm(sk) INGREDIENT COMMENTS = Workplace Exposure Limits PROTECTIVE EQUIPMENT

3 ENGINEERING MEASURES Explosion-proof general and local exhaust ventilation. RESPIRATORY EQUIPMENT Respiratory protection must be used if air contamination exceeds acceptable level. Wear mask supplied with: Gas cartridge suitable for organic substances. HAND PROTECTION Protective gloves must be used if there is a risk of direct contact or splash. Use protective gloves made of: Nitrile. EYE PROTECTION Wear splash-proof eye goggles to prevent any possibility of eye contact. OTHER PROTECTION Wear appropriate clothing to prevent repeated or prolonged skin contact. HYGIENE MEASURES Wash promptly if skin becomes contaminated. Wash at the end of each work shift and before eating, smoking and using the toilet. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE COLOUR ODOUR SOLUBILITY Liquid Yellowish of solvents Insoluble in water RELATIVE DENSITY 0.84 FLASH POINT ( C) minus C to minus 20C 10 STABILITY AND REACTIVITY STABILITY Avoid: Heat, sparks, flames. 11 TOXICOLOGICAL INFORMATION INHALATION Drowsiness, dizziness, disorientation, vertigo. SKIN CONTACT Prolonged contact may cause dryness of the skin. EYE CONTACT Irritating to eyes. 12 ECOLOGICAL INFORMATION ECOTOXICITY Dangerous for the environment: May cause long-term adverse effects in the aquatic environment. Contamination of the terrestrial and aquatic environments should be avoided 1 DISPOSAL CONSIDERATIONS GENERAL INFORMATION Waste is classified as hazardous waste. DISPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements. 14 TRANSPORT INFORMATION

4 4 UK ROAD CLASS PROPER SHIPPING NAME ADHESIVES UN NO. ROAD ADR CLASS NO. 11 UK ROAD PACK GR. ADR CLASS ADR PACK GROUP HAZARD No. (ADR) 0 ADR LABEL NO. HAZCHEM CODE CEFIC TEC(R) NO. 0GF1-, 0GF1-sp RID CLASS NO. RID PACK GROUP UN NO. SEA 11 IMDG CLASS EMS F-E, S-D IMDG PACK GR. MARINE POLLUTANT UN NO. AIR 11 AIR CLASS AIR PACK GR. 1 REGULATORY INFORMATION Class : Flammable liquids. Y No. LABELLING RISK PHRASES Irritant Highly Flammable Dangerous for the environment R11 Highly flammable. R68 Irritating to eyes and skin. R1 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness. SAFETY PHRASES S2 S9 S16 Keep out of the reach of children Keep container in a well-ventilated place. Keep away from sources of ignition - No smoking. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S296 Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. S679 Wear suitable protective clothing, gloves and eyeface protection. S46 S1 S61 S64 P14 If swallowed, seek medical advice immediately and show this container or label. Use only in well-ventilated areas. Avoid release to the environment. Refer to special instructionssafety data sheets. If swallowed, rinse mouth with water (only if the person is conscious). Contains ROSIN. May produce an allergic reaction. STATUTORY INSTRUMENTS Chemicals (Hazard Information and Packaging) Regulations. Control of Substances Hazardous to Health. APPROVED CODE OF PRACTICE Classification and Labelling of Substances and Preparations Dangerous for Supply.

5 GUIDANCE NOTES Workplace Exposure Limits EH40. CHIP for everyone HSG(108). Introduction to Local Exhaust Ventilation HS(G)7. 16 OTHER INFORMATION GENERAL INFORMATION This product should be used as directed by Bostik Ltd. For further information consult the product data sheet or contact Technical Services. INFORMATION SOURCES This safety data sheet was compiled using current safety information supplied by distributor of raw materials. REVISION COMMENTS This safety data sheet supersedes all previous issues and users are cautioned to ensure that it is current. Destroy all previous data sheets and if in doubt contact Bostik Limited. ISSUED BY Approved LJ REVISION DATE March 2008 REV. NO.REPL. SDS GENERATED DATE August 2006 RISK PHRASES IN FULL R10 R11 R12 R2021 R2242 R4 R6 R7 R8 R40 R4 R4820 R0 R1 R62 R6 R66 R67 Flammable. Highly flammable. Extremely flammable. Harmful by inhalation and in contact with skin. Toxic by inhalation, in contact with skin and if swallowed. Causes burns. Irritating to eyes. Irritating to respiratory system. Irritating to skin. Limited evidence of a carcinogenic effect. May cause sensitisation by skin contact. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Possible risk of impaired fertility. Harmful: may cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness.