Vimark S.r.l. A CALCINA PLUS

Transcription

1 SECTION Hazards Firefighting Exposure Stability Other information. identification. controls/personal and measures. reactivity.... /... >> /... >> / protection. >>... / >> Safety data sheet Page n / The Advice Exposure Incompatible H315 use for controls. of firefighters. this materials. product Causes is not skin subject irritation. to our direct control; therefore, users must, under their own responsibility, comply with the current health SPECIAL Information and H335 safety PROTECTIVE laws not available. and regulations. EQUIPMT May cause The producer respiratory FOR FIRE-FIGHTERS is irritation. relieved from any liability arising from improper uses. SECTION Normal As Provide the appointed fire use fighting of Transport Other adequate staff clothing with information. adequate technical i.e. fire training equipment kit (BS on how must 469), to use always gloves chemical take (BS products. priority 659) over and personal boots protective (HO specification equipment, A29 make and sure A30) that in combination the workplace with is Precautionary self-contained well Hazardous aired through decomposition statements: open circuit effective products. positive local pressure aspiration. compressed Personal air protective breathing equipment apparatus must (BS be 137). CE marked, showing that it complies with applicable SECTION Text standards. UN P102 of number. hazard (H) indications Keep mentioned out of reach in section of children. 2-3 of the sheet: Information Changes to 1. not previous Identification available. review: of the substance/mixture and of the company/undertaking Provide The P261 following an emergency sections were shower Avoid modified: with breathing face and dust eye / fume wash / station. gas / mist / vapours / spray SECTION HAND Not Product P280 Eye applicable. Dam. identifier 1 Wear Serious protective eye damage, gloves category / clothing 1 01 / 02 PROTECTION / 046. / 08 Accidental / 09 / 12 / 14. release measures. and eye / face protection. P302+P352 Skin Irrit. 2 IF Skin ON irritation, SKIN: wash category with 2plenty of water. SECTION In the case 11. of prolonged Toxicological contact with information. the product, protect the hands with penetration-resistant work gloves (see standard 374) Code: Personal P304+P340 STOT SE precautions, 3 IF INHALED: remove person to fresh air and keep comfortable for breathing. Work UN proper glove shipping material name. protective Specific equipment target organ and emergency toxicity A single procedures. exposure, category 3 must be chosen according to the use process and the products that may form. Latex gloves may cause sensitivity If Product P305+P351+P338 H318 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. reactions. Information there are name no contraindications, Causes spray serious powder eye damage. on toxicological effects. with CALCINA water to prevent PLUS the formation of dust. Avoid breathing vapours/mists/gases. H315 Continue Causes skin rinsing. irritation. Wear SKIN In Not the applicable. PROTECTION absence suitable of protective experimental equipment data for (including the product personal itself, health protective hazards equipment are evaluated referred according to under to the Section properties 8 of the of the safety substances data sheet) it to prevent P312 H335 Call May a cause POISON respiratory CTER irritation any or doctor if you feel unwell. Wear contains, Relevant contamination P501category using identified the II uses criteria professional of skin, of the specified eyes substance Dispose long-sleeved and in the or personal mixture applicable of contents overalls and clothing. regulation uses / container and advised These to safety for against classification. in accordance footwear indications with (see apply local/regional/national Directive for 89/686/EEC both processing regulation. and standard staff and those ISO involved 20344). in Wash emergency body procedures. with It is Transport soap therefore and hazard necessary water class(es). after to removing take into protective account clothing. the concentration of the individual hazardous substances indicated in section 3, to evaluate the EYE toxicological Intended Contains: PROTECTION useeffects of exposure to the product. ADESIVO-RASANTE NATURALE A BASE DI CALCE IDRAULICA NATURALE PER 6.2. Wear Not Environmental applicable. a hood visor precautions. or protective visor combined with CICLI airtight DI goggles ISOLAMTO (see standard TERMICO 166). NATURALI LEGD: The 2.3. RESPIRATORY This product must may Other hazards. PROTECTION cause not penetrate serious into ocular the lesions, sewer system cornea or opacity, come into iris lesions, contact with irreversible surface eye water coloration. or ground water. - ADR: European Agreement concerning the carriage of Dangerous goods by Road Use Acute Details Packing a effects: of type group. the P supplier contact filtering of the with facemask safety skin data may (see sheet cause: standard irritation, 149) erythema, or equivalent edema, device, dryness whose and class chapped (1, skin. 2 or 3) Ingestion and effective may cause need, health must be disorders, - CAS NUMBER: Chemical Abstract Service Number defined 6.3. Methods and material for containment and cleaning up. On according including stomach the basis the of outcome pain and available of sting, data, risk the assessment. nausea and sickness. - CE50: Effective concentration (required product to does induce not a 50% contain effect) any PBT or vpvb in percentage greater than 0,1%. Use VIRONMTAL Acute Not Name applicable. spark-proof effects: inhalation mechanical EXPOSURE of equipment this CONTROLS. product to may collect irritate Vimark the the leaked S.r.l. lower product and upper and respiratory place it tract in containers and cause for cough recovery and respiratory disposal. disorders; If there at higher - CE NUMBER: Identifier in ESIS (European archive of existing substances) are no contraindications, The concentrations Full address emissions it generated use can jets also of by water cause manufacturing to pulmonary eliminate product processes, edema. Via residues. Spartafino Ingestion including 2may those cause generated health problems, by ventilation including equipment, stomach should pain and be checked sting, nausea to ensure and - CLP: EC Regulation 1272/ Make sure the leakage site is well aired. Check incompatibility for container material in section 7. Contaminated material should be disposed SECTION compliance sickness. District Environmental and Country 3. with Composition/information hazards. environmental standards Peveragno (CN) - DNEL: Derived No Effect Level on ingredients. of in compliance with the provisions set forth in point 13. Italia - EmS: Emergency Schedule 3.1. Not Substances. applicable. Tel GHS: Globally Harmonized System of classification and labeling of chemicals 6.4. SECTION NATURAL Reference 9. HYDRAULIC to Physical other sections. LIME and chemical properties. Fax IATA DGR: International Air Transport Association Dangerous Goods Regulation Information Any LD50 Special information (Oral). address precautions not of relevant. the personal for competent user. protection person > 2000 and mg/kg disposal RAT - IC50: Immobilization Concentration 50% is given in sections 8 and responsible Information for on the basic Safety physical Data and Sheet chemical properties. laboratorio@vimark.com - IMDG: International Maritime Code for dangerous goods Appearance 3.2. Not powder - Mixtures. IMO: applicable. International Maritime Organization SECTION Colour Product distribution Handling Ecological by and information. storage. beige Marco Massolino - INDEX NUMBER: Identifier in Annex VI of CLP Odour characteristic Contains: 7.1. Odour Use - Precautions LC50: Transport this Lethal threshold. product in bulk for Concentration according safe handling. 50% to Annex to good II of MARPOL73/78 working practices. and the Avoid IBC littering. Code. Inform the competent authorities, should the product reach waterways or 1.4. Before ph. contaminate - Emergency LD50: Lethal telephone handling soil dose or vegetation. 50% number the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the Identification. Information Conc. %. Classification 1272/2008 (CLP). environment. - OEL: Occupational not relevant. NATURAL Do not Exposure HYDRAULIC eat, drink Level Melting point / freezing point. or smoke during LIME Not use. available. Remove any contaminated clothes and personal protective equipment before entering places - For PBT: urgent in Persistent inquiries which people bioaccumulative refer to eat. and toxic as REACH CTRI Regulation ANTIVELI Initial boiling point CAS. PEC: Eye Dam. 1 H318, Skin Irrit. 2 H315, STOT SE 3 H335 Boiling Toxicity. Predicted environmental Concentration range. EC SECTION - PEL: Predicted 15. Regulatory exposure level information Milano (IT) Opedale Niguarda Ca' Granda 7.2. Flash Conditions point. for safe storage, including any incompatibilities. INDEX. Store Evaporation NATURAL - PNEC: Predicted only HYDRAULIC no effect rate in the original LIME concentration Torino (IT) Az. Ospedaliera Molinette container. Store the containers Reg. no sealed, in a well ventilated place, away from direct sunlight. Keep containers away from Flammability LC50 - REACH: any - for EC incompatible Fish. Regulation 1907/ Roma (IT) Policlino A. Gemelli Safety, health (solid, and gas) environmental materials, see regulations/legislation section 10 for details. Not 50,6 specific available. mg/l/96h for the (Calcium substance dihydroxyde) or mixture. Lower EC50 - RID: - Regulation inflammability for Crustacea. concerning the international transport +39 limit. Note: Upper limit is not included into the range. Not 49,1 of 055 available. mg/l/48h dangerous (Calcium goods Firenze by (IT) dihydroxyde) train Az. Ospedaliera Careggi 7.3. Upper EC50 - TLV: Specific - Threshold inflammability for end Algae use(s). / Limit Aquatic Value Napoli (IT) Az. Ospedaliera A. Cardarelli Seveso category. limit. Plants. Not 184,57 available. mg/l/72h (Calcium dihydroxyde) The full wording of hazard (H) phrases is given in section 16 of the sheet. Information Lower Chronic - TLV CEILING: explosive NOEC not available. for Concentration limit. Crustacea. that should not be exceeded Not 32 mg/l during available. (Calcium any dihydroxyde) time of occupational exposure. Restrictions Upper Chronic - TWA STEL: explosive NOEC relating Short-term for limit. Algae to the / exposure product Aquatic or Plants. limit Not 48 mg/l available. (Calcium dihydroxyde) SECTION contained substances pursuant to Annex XVII to EC Regulation 1907/ TWA: Time-weighted 2. Hazards average identification. exposure limit Vapour pressure. SECTION 4. First aid measures SECTION Vapour Classification VOC: Persistence Volatile density 8. and Exposure of organic the degradability. substance Compounds controls/personal or mixture. Not protection. available Substances Relative Information - vpvb: Very Description density. in not Persistent of Candidate first available. aid measures. List and (Art. very 59 Bioaccumulative REACH). as for REACH Regulation 1,150 Kg/l 8.1. Control EYES: Solubility - The WGK: product Water parameters. Remove is hazard classified classes contact lenses, as (German). hazardous if present. pursuant Wash Not to immediately available. the provisions with plenty set forth of water in EC for Regulation least /2008 minutes, (CLP) opening (and the subsequent eyelids fully. amendments If problem Substances persists, Partition and Bioaccumulative supplements). coefficient: seek subject medical potential. to n-octanol/water authorisarion advice. The product (Annex thus XIV requires REACH). Not a available. safety datasheet that complies with the provisions of EC Regulation 1907/2006 and Regulatory References: SKIN: Auto-ignition Information subsequent Remove not amendments. temperature. available. contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash Substances GERAL contaminated Decomposition Any additional BIBLIOGRAPHY subject clothing information temperature. to exportation before concerning reporting using it again. the pursuant risks for to health (EC) Reg. and/or 649/2012: the environment are given in sections 11 and 12 of this sheet FRA France JORF n 0109 du 10 mai 2012 page 8773 texte n 102 INHALATION: Viscosity 1. Regulation (EU) 1907/2006 (REACH) of the European Parliament Mobility in soil. Remove to open air. In the event of breathing difficulties, get medical advice/attention immediately. 2. INGESTION: Explosive Information Hazard Regulation classification (EU) 1272/2008 properties not Get available. medical and indication: (CLP) of the European Parliament advice/attention. Induce Not vomiting available. only if indicated by the doctor. Never give anything by mouth to an unconscious Substances 3. Regulation person, Oxidising Serious subject unless properties eye (EU) authorised damage, to 790/2009 the Rotterdam category (I Atp. by a doctor. 1Convention: CLP) of the European Not NATURAL Parliament available. H318 HYDRAULIC LIME Causes serious eye damage. Threshold Limit Value Regulation Other Results Skin information. irritation, (EU) of PBT and category 2015/830 vpvb assessment. 2 of the European Parliament H315 Causes skin irritation. 5. Regulation Type 4.2. Most important symptoms Country and effects, TWA/8h both acute and delayed. STEL/15min Information Specific not target (EU) available. organ 286/2011 toxicity (II Atp. - single CLP) exposure, of the European category Parliament 3 H335 May cause respiratory irritation. Substances 6. Regulation subject (EU) to 618/2012 the Stockholm (III Atp. mg/m3 Convention: CLP) of ppm the European Parliament mg/m3 ppm For On the symptoms basis of and available effects data, caused the by product the contained does not substances, contain any see PBT chap. or vpvb 11. in percentage greater than 0,1% Label Regulation VLEP elements. (EU) 487/2013 FRA (IV Atp. 1CLP) of the European Parliament RESP. Health 8. Regulation - Derived (EU) no-effect 944/2013 level (V Atp. - DNEL CLP) / DMEL of the European Parliament SECTION Indication Other adverse 10. of any Stability effects. immediate and medical reactivity. Healthcare controls. attention and special treatment needed. 9. Information Hazard Regulation labelling (EU) not available. pursuant 605/2014 to Effects EC (VI Atp. Regulation CLP) consumers. of 1272/2008 the European (CLP) Parliament and subsequent amendments Effects and on workers supplements Workers Reactivity. Route exposed of exposure to this Acute chemical local agent Acutemust not undergo Chronic health Chronic checks, provided Acute local that available Acuterisk-assessment Chronic data prove Chronic that the risks There related - Hazard Merck are to pictograms: the no Index. particular workers' - 10th health risks Edition of and reaction safety with systemic are modest other substances and local that the in normal 98/24/EC systemic conditions directive of is use. respected. systemic local systemic - Handling Inhalation. Chemical Safety SECTION 5. Firefighting measures INRS Chemical - Fiche stability. safety Toxicologique assessment. (toxicological sheet) mg/m3 mg/m3 mg/m3 mg/m3 SECTION 13. Disposal considerations The - Extinguishing Patty product - Industrial is media. stable Hygiene in normal and Toxicology conditions of use and storage SUITABLE Legend: A - N.I. Waste chemical Sax treatment - EXTINGUISHING Dangerous safety methods. assessment properties EQUIPMT has of been Industrial performed Materials-7, for the 1989 following Edition contained substances Choose (C) Reuse, NATURAL - ECHA Possibility = CEILING website the when HYDRAULIC of most hazardous possible. ; appropriate INHAL LIME reactions. Product = Inhalable extinguishing residues Fraction equipment should ; RESP be for considered the = Respirable specific special case. Fraction hazardous ; THORA waste. = Thoracic The hazard Fraction. level of waste containing this product UNSUITABLE VND The should powders = be hazard evaluated are EXTINGUISHING identified potentially according but explosive no to DNEL/PNEC EQUIPMT applicable when mixed regulations. available with air. ; NEA = no exposure expected ; NPI = no hazard identified. None Disposal in particular. must be performed through an authorised waste management firm, in compliance with national and local regulations During CONTAMINATED Note Signal for Conditions words: the users: to risk avoid. assessment PACKAGING Danger process, it is essential to take into consideration the ACGIH occupational exposure levels for inert particulate 5.2. otherwise Avoid Contaminated The information Special environmental hazards classified packaging contained arising dust (PNOC from build-up. must in the respirable substance be the recovered present or fraction: mixture. or sheet disposed 3 are mg/m3; based of in PNOC compliance on our inhalable own with knowledge national fraction: waste on 10 the mg/m3). management date For of values the regulations. last above version. these Users limits, must use verify a P type the HAZARDS filter, suitability Hazard whose statements: and CAUSED class thoroughness (1, BY 2 EXPOSURE 3) of must provided be IN chosen information THE EVT according according OF to FIRE the to outcome each specific of risk assessment. use of the product. This The H318 document must not be product is neither flammable Causes regarded nor serious as a combustible. eye guarantee damage. on any specific product property.

2 SECTION 2. Hazards identification.... / >> Page n. 2 / 8 H315 H335 Precautionary statements: P102 P261 P280 P302+P352 P304+P340 P305+P351+P338 P312 P501 Contains: Causes skin irritation. May cause respiratory irritation. Keep out of reach of children. Avoid breathing dust / fume / gas / mist / vapours / spray. Wear protective gloves / clothing and eye / face protection. IF ON SKIN: wash with plenty of water. IF INHALED: remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CTER or doctor if you feel unwell. Dispose of contents / container to in accordance with local/regional/national regulation Other hazards. On the basis of available data, the product does not contain any PBT or vpvb in percentage greater than 0,1%. SECTION 3. Composition/information on ingredients Substances. Information not relevant Mixtures. Contains: Identification. Conc. %. Classification 1272/2008 (CLP). CAS Eye Dam. 1 H318, Skin Irrit. 2 H315, STOT SE 3 H335 EC INDEX. Reg. no Note: Upper limit is not included into the range. The full wording of hazard (H) phrases is given in section 16 of the sheet. SECTION 4. First aid measures Description of first aid measures. EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem persists, seek medical advice. SKIN: Remove contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash contaminated clothing before using it again. INHALATION: Remove to open air. In the event of breathing difficulties, get medical advice/attention immediately. INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person, unless authorised by a doctor Most important symptoms and effects, both acute and delayed. For symptoms and effects caused by the contained substances, see chap Indication of any immediate medical attention and special treatment needed. SECTION 5. Firefighting measures Extinguishing media. SUITABLE EXTINGUISHING EQUIPMT Choose the most appropriate extinguishing equipment for the specific case. UNSUITABLE EXTINGUISHING EQUIPMT None in particular Special hazards arising from the substance or mixture. HAZARDS CAUSED BY EXPOSURE IN THE EVT OF FIRE The product is neither flammable nor combustible.

3 SECTION 5. Firefighting measures.... / >> Page n. 3 / Advice for firefighters. SPECIAL PROTECTIVE EQUIPMT FOR FIRE-FIGHTERS Normal fire fighting clothing i.e. fire kit (BS 469), gloves (BS 659) and boots (HO specification A29 and A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS 137). SECTION 6. Accidental release measures Personal precautions, protective equipment and emergency procedures. If there are no contraindications, spray powder with water to prevent the formation of dust. Avoid breathing vapours/mists/gases. Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency procedures Environmental precautions. The product must not penetrate into the sewer system or come into contact with surface water or ground water Methods and material for containment and cleaning up. Use spark-proof mechanical equipment to collect the leaked product and place it in containers for recovery or disposal. If there are no contraindications, use jets of water to eliminate product residues. Make sure the leakage site is well aired. Check incompatibility for container material in section 7. Contaminated material should be disposed of in compliance with the provisions set forth in point Reference to other sections. Any information on personal protection and disposal is given in sections 8 and 13. SECTION 7. Handling and storage Precautions for safe handling. Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which people eat Conditions for safe storage, including any incompatibilities. Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away from any incompatible materials, see section 10 for details Specific end use(s). SECTION 8. Exposure controls/personal protection Control parameters. Regulatory References: FRA France JORF n 0109 du 10 mai 2012 page 8773 texte n 102 Threshold Limit Value. Type Country TWA/8h STEL/15min mg/m3 ppm mg/m3 ppm VLEP FRA 1 RESP. Health - Derived no-effect level - DNEL / DMEL Effects on consumers. Effects on workers Route of exposure Acute local Acute systemic Chronic local Chronic systemic Acute local Acute systemic Chronic local Chronic systemic Inhalation mg/m3 mg/m3 mg/m3 mg/m3 Legend: (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. VND = hazard identified but no DNEL/PNEC available ; NEA = no exposure expected ; NPI = no hazard identified. During the risk assessment process, it is essential to take into consideration the ACGIH occupational exposure levels for inert particulate otherwise classified (PNOC respirable fraction: 3 mg/m3; PNOC inhalable fraction: 10 mg/m3). For values above these limits, use a P type filter, whose class (1, 2 or 3) must be chosen according to the outcome of risk assessment.

4 SECTION 8. Exposure controls/personal protection.... / >> 8.2. Exposure controls. Page n. 4 / 8 As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration. Personal protective equipment must be CE marked, showing that it complies with applicable standards. Provide an emergency shower with face and eye wash station. HAND PROTECTION In the case of prolonged contact with the product, protect the hands with penetration-resistant work gloves (see standard 374). Work glove material must be chosen according to the use process and the products that may form. Latex gloves may cause sensitivity reactions. SKIN PROTECTION Wear category II professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard ISO 20344). Wash body with soap and water after removing protective clothing. EYE PROTECTION Wear a hood visor or protective visor combined with airtight goggles (see standard 166). RESPIRATORY PROTECTION Use a type P filtering facemask (see standard 149) or equivalent device, whose class (1, 2 or 3) and effective need, must be defined according to the outcome of risk assessment. VIRONMTAL EXPOSURE CONTROLS. The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards. SECTION 9. Physical and chemical properties Information on basic physical and chemical properties. Appearance powder Colour beige Odour characteristic Odour threshold. ph. Melting point / freezing point. Initial boiling point. Boiling range. Flash point. Evaporation rate Flammability (solid, gas) Lower inflammability limit. Upper inflammability limit. Lower explosive limit. Upper explosive limit. Vapour pressure. Vapour density Relative density. 1,150 Kg/l Solubility Partition coefficient: n-octanol/water Auto-ignition temperature. Decomposition temperature. Viscosity Explosive properties Oxidising properties 9.2. Other information. SECTION 10. Stability and reactivity Reactivity. There are no particular risks of reaction with other substances in normal conditions of use Chemical stability. The product is stable in normal conditions of use and storage Possibility of hazardous reactions. The powders are potentially explosive when mixed with air Conditions to avoid. Avoid environmental dust build-up.

5 SECTION 10. Stability and reactivity.... / >> Incompatible materials. Page n. 5 / Hazardous decomposition products. SECTION 11. Toxicological information Information on toxicological effects. In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it contains, using the criteria specified in the applicable regulation for classification. It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the toxicological effects of exposure to the product. This product may cause serious ocular lesions, cornea opacity, iris lesions, irreversible eye coloration. Acute effects: contact with skin may cause: irritation, erythema, edema, dryness and chapped skin. Ingestion may cause health disorders, including stomach pain and sting, nausea and sickness. Acute effects: inhalation of this product may irritate the lower and upper respiratory tract and cause cough and respiratory disorders; at higher concentrations it can also cause pulmonary edema. Ingestion may cause health problems, including stomach pain and sting, nausea and sickness. LD50 (Oral). > 2000 mg/kg RAT SECTION 12. Ecological information. Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation Toxicity. LC50 - for Fish. EC50 - for Crustacea. EC50 - for Algae / Aquatic Plants. Chronic NOEC for Crustacea. Chronic NOEC for Algae / Aquatic Plants. 50,6 mg/l/96h (Calcium dihydroxyde) 49,1 mg/l/48h (Calcium dihydroxyde) 184,57 mg/l/72h (Calcium dihydroxyde) 32 mg/l (Calcium dihydroxyde) 48 mg/l (Calcium dihydroxyde) Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment. On the basis of available data, the product does not contain any PBT or vpvb in percentage greater than 0,1% Other adverse effects. SECTION 13. Disposal considerations Waste treatment methods. Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

6 Page n. 6 / 8 SECTION 14. Transport information UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code. Information not relevant. SECTION 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture. Seveso category. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006. Substances in Candidate List (Art. 59 REACH). Substances subject to authorisarion (Annex XIV REACH). Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: Substances subject to the Rotterdam Convention: Substances subject to the Stockholm Convention: Healthcare controls. Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks related to the workers' health and safety are modest and that the 98/24/EC directive is respected Chemical safety assessment. A chemical safety assessment has been performed for the following contained substances.

7 Page n. 7 / 8 SECTION 16. Other information. Text of hazard (H) indications mentioned in section 2-3 of the sheet: Eye Dam. 1 Serious eye damage, category 1 Skin Irrit. 2 Skin irritation, category 2 STOT SE 3 Specific target organ toxicity - single exposure, category 3 H318 Causes serious eye damage. H315 Causes skin irritation. H335 May cause respiratory irritation. LEGD: - ADR: European Agreement concerning the carriage of Dangerous goods by Road - CAS NUMBER: Chemical Abstract Service Number - CE50: Effective concentration (required to induce a 50% effect) - CE NUMBER: Identifier in ESIS (European archive of existing substances) - CLP: EC Regulation 1272/ DNEL: Derived No Effect Level - EmS: Emergency Schedule - GHS: Globally Harmonized System of classification and labeling of chemicals - IATA DGR: International Air Transport Association Dangerous Goods Regulation - IC50: Immobilization Concentration 50% - IMDG: International Maritime Code for dangerous goods - IMO: International Maritime Organization - INDEX NUMBER: Identifier in Annex VI of CLP - LC50: Lethal Concentration 50% - LD50: Lethal dose 50% - OEL: Occupational Exposure Level - PBT: Persistent bioaccumulative and toxic as REACH Regulation - PEC: Predicted environmental Concentration - PEL: Predicted exposure level - PNEC: Predicted no effect concentration - REACH: EC Regulation 1907/ RID: Regulation concerning the international transport of dangerous goods by train - TLV: Threshold Limit Value - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. - TWA STEL: Short-term exposure limit - TWA: Time-weighted average exposure limit - VOC: Volatile organic Compounds - vpvb: Very Persistent and very Bioaccumulative as for REACH Regulation - WGK: Water hazard classes (German). GERAL BIBLIOGRAPHY 1. Regulation (EU) 1907/2006 (REACH) of the European Parliament 2. Regulation (EU) 1272/2008 (CLP) of the European Parliament 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament 4. Regulation (EU) 2015/830 of the European Parliament 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament - The Merck Index. - 10th Edition - Handling Chemical Safety - INRS - Fiche Toxicologique (toxicological sheet) - Patty - Industrial Hygiene and Toxicology - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition - ECHA website Note for users: The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product. This document must not be regarded as a guarantee on any specific product property.

8 SECTION 16. Other information.... / >> Page n. 8 / 8 The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Provide appointed staff with adequate training on how to use chemical products. Changes to previous review: The following sections were modified: 01 / 02 / 04 / 08 / 09 / 12 / 14.