MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET Section 1 (PRODUCT/MANUFACTURER) Identity (Tradename): ReflectASeal-2CLR Part B Product Type: Polyurea TRANSPORTATION EMERGENCY CALL CHEMTREC: (800) INTERNATIONAL: (703) Section 2 (COMPOSITION/INFO ON INGREDIENTS) Hazardous Components Weight % Components CAS-No % Aspartic Ester CAS# is a trade secret 5-10% Monoaspartate 1-5% Aliphatic Carboxylic Ester Section 3 (HAZARDS IDENTIFICATION) Emergency Overview CAUTION! Color: Light yellow, Amber Form: Liquid Odor: Slight. Irritating gases/fumes may be given off during burning or thermal decomposition. Use cold water spray to cool fire-exposed containers to minimize the risk of rupture. May cause respiratory tract irritation. May cause allergic skin reaction. May cause skin irritation. Potential Health Effects Primary Routes of Entry Skin Contact, Eye Contact, Ingestion, Inhalation Medical Conditions Aggravated by Exposure Skin disorders, Respiratory disorders, Eye disorders, Skin Allergies HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE Inhalation Acute Inhalation Inhalation is unlikely due to the low vapor pressure. If misted or handled at elevated temperatures, high concentrations may cause respiratory tract irritation. For Component: Aspartic Ester Inhalation is unlikely due to the low vapor pressure. If misted or handled at elevated temperatures, high concentrations may cause respiratory tract irritation. Skin Acute Skin May cause irritation with symptoms of reddening and itching. May cause allergic skin reaction with symptoms of reddening, itching, swelling, and rash. May cause sensitization of susceptible persons. For component: Aspartic Ester May cause irritation with symptoms of reddening and itching. May cause allergic skin reaction with symptoms of reddening, itching, swelling, and rash. Chronic Skin Prolonged contact can cause reddening, swelling, rash, and in some cases, skin sensitization.

2 Eye Acute Eye Not expected to be irritating. For Component: Aspartic Ester Not expected to be irritating. Ingestion Acute Ingestion Ingestion is not a typical route of industrial exposure. Not expected to be harmful if swallowed. For Component: Aspartic Ester Not expected to be harmful if swallowed. For Component: Aliphatic Carboxylic Ester May be harmful if swallowed General Effects of Exposure Chronic Effects of Exposure No applicable information was found concerning any adverse chronic health effects from overexposure to this product. Repeated or prolonged overexposure may cause effects as noted under acute health effects. Carcinogenicity No Carcinogenic substances as defined by IARC, NTP and/or OSHA. Section 4 (FIRST AID MEASURES) Eye Contact In case of contact, flush eyes with plenty of lukewarm water. Get medical attention if irritation develops. Skin Contact In case of skin contact, wash affected areas with soap and water. Immediately remove contaminated clothing and shoes. Get medical attention if irritation develops and persists. Thoroughly clean shoes before reuse. Wash clothing before reuse. Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if irritation develops. Ingestion If ingested, do not induce vomiting unless directed to do so by medical personnel. Do not give anything by mouth to an unconscious person. Section 5 (FIRE FIGHTING MEASURES) Suitable Extinguishing Media All extinguishing media are suitable. Special Fire Fighting Procedures Firefighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Use cold water spray to cool fire-exposed containers to minimize risk of rupture. Toxic and irritating gases/fumes may be given off during burning or thermal decomposition. Section 6 (ACCIDENTAL RELEASE MEASURES) Spill and Leak Procedures Cleanup personnel must use appropriate personal protective equipment. Cover spill with inert material (e.g. dry sand or earth) and collect for proper disposal. Prevent from entering open drains and waterways. Ventilate area to remove vapors or dust. Evacuate and keep unnecessary people out of spill area. Section 7 (HANDLING AND STORAGE) Storage Temperature: Minimum: 0 C (32º F) Maximum: 50C (122º F) Storage Period: 6 months in unopened containers

3 Handling/Storage Precautions Avoid contact with skin or clothing. Avoid contact with eyes. Use only with adequate ventilation/personal protection. Wash thoroughly after handling. Keep container closed when not in use. Do not breathe vapors or spray mist. Store in a dry place away from excessive heat. Material is hygroscopic and may absorb small amounts of atmospheric moisture. Further Info on Storage Conditions Avoid contact with moisture/water. Material can be stored safely at ambient temperatures. Section 8 (EXPOSURE CONTROLS/PERSONAL PROTECTION) Country specific exposure limits have not been established or are not applicable. Industrial Hygiene/Ventilation Measures General dilution and local exhaust as necessary to control airborne vapors, mists, dusts and thermal decomposition products below appropriate airborne concentration standards/guidelines. Curing ovens must be ventilated to prevent the build up of explosive atmospheres and to prevent off gases from entering the work place. Respiratory Protection In spray applications, an organic vapor/particulate respirator or air supplied unit is necessary. The use of a positive pressure supplied air respirator is recommended if the airborne concentration is unknown or if spraying is performed in a confined space or area with limited ventilation. Hand Protection Permeation resistant clothing and foot protection. Gloves, long sleeved shirts and pants. Eye Protection Chemical safety goggles or safety glassed with side-shields. Skin and body protection Permeation resistant clothing and foot protection. Gloves, long sleeved shirts and pants. Additional Protective Measures Employees should wash their hands and face before eating, drinking, or using tobacco products. Educate and train employees in the safe use and handling of this product. Emergency showers and eye was stations should be available. Section 9 (PHYSICAL AND CHEMICAL PROPERTIES) Form: Liquid Color: Light yellow, Amber Odor: Slight ph: Freezing Point: Boiling Point/Range: Approximately 185 C (365º 1,013 mbar Flash Point: Approximately 145 C (293º F) Lower Explosion Limit: Upper Explosion Limit: Approximately 8 20 C (68º F) Approximately C (122º F) Approximately C (131º F) Density C (68º F) Solubility in Water: Insoluble Autoignition Temperature: Approximately 365 C (689º F) Viscosity Dynamic: Approximately 1, C (77º F) Bulk Density: C (77º F) Pour Point: Approximately -15 C (5º F) Section 10 (STABILITY AND REACTIVITY) Hazardous Reactions Hazardous polymerization does not occur. Stability: Stable Materials to avoid: Oxidizing Agents Conditions to avoid: Avoid Extreme Heat Hazardous decomposition products

4 By fire and thermal decomposition: Carbon oxides, nitrogen oxides (NOx), Amines, other aliphatic fragments which have not been determined, Ammonia Gas may be liberated at high temperatures. Section 11 (TOXICOLOGICAL INFORMATION) Toxicity note Toxicity Data is based on a similar product Acute Oral Toxicity Acute Inhalation Toxicity LC50: >4,224 mg/l, 4 h (Rat) Acute Dermal Toxicity Skin Irritation Rabbit, Non-irritating Eye Irritation Rabbit, Moderately irritating Sensitization (Magnusson/Kligmann (Maximization Test)) Mutagenicity Genetic Toxicity in Vitro: Ames test: negative Based on a similar product Toxicity Data for Aspartic Ester Toxicity Note Toxicity data is based on a similar product Acute Oral Toxicity Acute Inhalation Toxicity LC50: >4224 mg/m3, aerosol, 4 hrs (Rat) Acute dermal Toxicity Skin Irritation Rabbit, Irritating to skin. Eye Irritation Rabbit, No eye irritation Sensitization Dermal: sensitizer (Guinea pig, Magnusson/Kligmann (Maximization Test)) Mutagenicity Genetic Toxicity in Vitro: Ames: negative (metabolic activation: with/without) Toxicity Data for Aliphatic Carboxylic Ester Acute Oral Toxicity LD50: 1,780 mg/kg (Rat) Section 12 (ECOLOGICAL INFORMATION) Biodegradation 13% exposure time: 28 d, not readily biodegradable. According to the results of tests of biodegradability this product is not readily biodegradable. Acute and Prolonged Toxicity to Fish LC50: 66mg/L (Zebra fish (Brachydanio rerio), 96 h) Acute Toxicity to Aquatic Invertebrates

5 EC50: 88.6 mg/l (Water flea (Daphnia Magana), 48h) Toxicity to Aquatic Plants EC50: 3,110 mg/i (Scenedesmus subspicatus) Toxicity to Terrestrial Plants 113 mg/l, (72H) Additional Ecotoxicological Remarks Ecotoxicological data is based on a similar product. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Ecological Data for Aliphatic Carboxylic Ester Acute and Prolonged Toxicity to Fish 38 g/l (Fathead minnow (Pimephales promelas), 96h) Section 13 (DISPOSAL CONSIDERATIONS) Waste Disposal Method Waste disposal should be in accordance with existing federal, state and local environmental control laws. Empty Container Precautions Recondition or dispose of empty container in accordance with governmental regulations. Do not reuse empty container without proper governmental regulations. Do not reuse empty container without proper cleaning. Empty containers retain product residue (dust, liquid, vapor and/or gases) and can be dangerous. Do not heat or cut container with electric or gas torch. Section 14 (TRANSPORTATION INFORMATION) Land transport (DOT) Non-Regulated Sea transport (IMDG) Non-regulated Air Transport (ICAO/IATA) Non-Regulated Section 15 (REGULATORY INFORMATION) United States Federal Regulations OSHA Hazcom Standard Rating: Hazardous US. Toxic Substances Control Act: Listed on the TSCA Inventory. US. EPA CERCLA Hazardous Substances (40 CFR 302): Components None SARA Section 311/312 Hazard Categories: Acute Health Hazard USA EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 302 Extremely Hazardous Substances (40 CFR 355, Appendix A): Components None USA EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313 Toxic Chemicals (40 CFR ) Supplier Notification Required: Components None USA EPA Resource Conservation and Recovery Act (RCRA) Composite List of Hazardous Wastes and Appendix VIII Hazardous Constituents (40 CFR 261): If discarded in its purchased form, this product would not be a hazardous waste either by listing or by characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. (40 CFR ) State Right-To-Know Information The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the MSDS

6 may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state. Massachusetts, New Jersey or Pennsylvania Right to Know Substance Lists: Weight % Components CAS-No % Aspartic Ester CAS# is a trade secret 5-10% Monoaspartate 1-5% Aliphatic Carboxylic Ester California Prop. 65: To the best of our knowledge, this product does not contain any of the listed chemicals, which the state of California has found to cause cancer, birth defects or other reproductive harm. Section 16 (OTHER INFORMATION) NFPA 704M Rating Health 2 Flammability 1 Reactivity 0 Other 0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme HMIS Rating Health 2 Flammability 1 Physical Hazard 0 0=Minimal 1=Slight 2=Moderate 3=Serious 4=Severe *=Chronic Health Hazard EFP Material Science LLC s method of hazard communication is comprised of Product Labels and Material Safety Data Sheets. HMIS and NFPA ratings are provided by Bayer material science LLC as a customer service. Contact Person: Product Safety Department Telephone: MSDS number: Version Date: 03/2008 Report Version: 1.5 For Additions Information: Contact: MSDS Coordinator- ReflectASeal, LLC During business hours, Center NOTICE ReflectASeal, LLC expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose with respect to the product or information provided herein, and shall under not circumstances be liable for incidental or consequential damages. Do not use ingredient information and/or ingredient percentages in this MSDS as a product specification. For product specification information refer to a Product Specification Sheet and/or a Certificate of Analysis. These can be obtained from your local ReflectASeal, LLC sales office. All information appearing herein is based upon data obtained from the manufacturer and/or recognized technical sources. While the information is believed to be accurate, ReflectASeal, LLC makes no representations as to its accuracy or sufficiency. Conditions of use are beyond ReflectASeal, LLC control. Therefore, users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes, and they assume all risks of their use, handling, and disposal of the product or from the publication or use of, or reliance upon, information contained herein. This information relates only to the product designated herein and does not relate to its use in combination with any other material or in any other process.