Brake Fluid Super Dot 4

Transcription

1 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Commercial Product Name : 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Brake fluid 1.3 Details of the supplier of the safety data sheet Company : Ford Motor Company Ltd., Parts Distribution Centre Royal Oak Way South UK-NN 11 5NT Daventry, Northants United Kingdom Ford-Werke GmbH Edsel-Ford-Str D Köln Deutschland +49 (0) address : Prodsafe.ford@sap.com 1.4 Emergency telephone number (mo. - fr. 09:00-16:00) 2. Hazards identification 2.1 Classification of the substance or mixture Classification (67/548/EEC, 1999/45/EC) Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC. 2.2 Label elements Special labelling of certain mixtures : Safety data sheet available on request for professional users. 2.3 Other hazards 3. Composition/information on ingredients 3.1 Mixtures Hazardous components Chemical Name CAS-No. Classification Classification Concentration 1 / 11

2 EC-No. (67/548/EEC) (1272/2008/EC) [%] Registration number 2,2'-oxybisethanol Xn; R22 Acute Tox. 4; H302 >= 7 - < di-isopropanolamine Xi; R36 Eye Irrit. 2; H319 >= 3 - < For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section First aid measures 4.1 Description of first aid measures General advice If inhaled In case of skin contact In case of eye contact If swallowed : If you feel unwell, seek medical advice (show the label where possible). Never give anything by mouth to an unconscious person. Take off contaminated clothing and shoes immediately. : If breathed in, move person into fresh air. Call a physician immediately. : Immediately flush skin with large amounts of water. : If easy to do, remove contact lens, if worn. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. : If swallowed, DO NOT induce vomiting. Call a physician immediately. If a person vomits when lying on his back, place him in the recovery position. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed 5. Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water spray jet, Alcohol-resistant foam, Dry powder, Carbon dioxide (CO2) : High volume water jet 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting : Do not use a solid water stream as it may scatter and spread fire. Hazardous decomposition products may be formed under fire condi- 2 / 11

3 tions (see section 10). Exposure to decomposition products may be a hazard to health. 5.3 Advice for firefighters Special protective equipment for firefighters Further information : Wear self contained breathing apparatus for fire fighting if necessary. Use personal protective equipment. : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopened containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Refer to protective measures listed in sections 7 and 8. Ensure adequate ventilation, especially in confined areas. Avoid inhalation of vapour or mist. 6.2 Environmental precautions Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3 Methods and materials for containment and cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Clean contaminated surface thoroughly. 6.4 Reference to other sections see chapter: 7, 8, 11, 12 and Handling and storage 7.1 Precautions for safe handling Advice on safe handling Advice on protection against fire and explosion : For personal protection see section 8. Do not breathe vapours or spray mist. Avoid contact with skin and eyes. : Normal measures for preventive fire protection. Dust explosion class : not applicable 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Keep containers tightly closed in a dry, cool and well-ventilated place. Advice on common storage : Keep away from combustible materials. 3 / 11

4 Keep away from food, drink and animal feedingstuffs. Other data : No decomposition if stored and applied as directed. 7.3 Specific end uses 8. Exposure controls/personal protection 8.1 Control parameters Components CAS-No. Control parameters Basis Update 2,2'-oxybisethanol TWA: 101 mg/m3, 23 ppm 2, GB EH Other information on limit values: see chapter Exposure controls Engineering measures Provide adequate ventilation. Personal protective equipment Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator with filter type A Hand protection Material Glove thickness Break through time Remarks : Nitrile rubber : 0,4 mm : >= 480 min : Glove recommendation: Camatril Velours 730 (Kächele-Cama GmbH, source of supply see or comparable product. Hand protection in case of splash contact Material : Nitrile rubber Glove thickness : 0,4 mm Break through time : >= 480 min Glove recommendation: Camatril Velours 730 (Kächele-Cama GmbH, source of supply see or comparable product. The protective gloves to be used must comply with the specification of EU directive 89/686/EC and the 4 / 11

5 resultant standard EN374. The above given information is based on laboratory test in line with EN374. The recommendation is only valid for the supplied product and the stated application. Special working conditions, like heat or mechanical strain, which deviate from the test conditions, can reduce the protective effect provided by the recommended glove. Eye protection : Safety glasses Skin and body protection : Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. General industrial hygiene practice. Avoid breathing vapors, mist or gas. Avoid contact with skin, eyes and clothing. When using do not eat, drink or smoke. Wash hands before breaks and at the end of workday. Wash contaminated clothing before re-use. Environmental exposure controls General advice : Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : liquid Colour : yellow Odour : characteristic Odour Threshold : Flash point : > 130 C Method: ISO 2719, closed cup Ignition temperature : > 200 C Lower explosion limit Upper explosion limit Explosive properties : 1,5 %(V) : : Flammability (solid, gas) : Oxidizing properties : not applicable Autoignition temperature : not auto-flammable Burning number : Molecular Weight : ph : 8 Concentration: ca. 500,00 g/l 5 / 11

6 Pour point : < -70 C Method: DIN Boiling point/boiling range : > 260 C Vapour pressure : < 1 hpa at 20 C Density : 1,075 g/cm3 at 20 C Bulk density Water solubility Partition coefficient: n- octanol/water Solubility in other solvents Viscosity, dynamic : not applicable : completely soluble : not applicable : : 17,2 mpa.s Viscosity, kinematic : 16 mm2/s at 20 C Flow time Impact Sensitivity Relative vapour density Surface tension Evaporation rate Minimum ignition energy Acid number Refraction index Miscibility in water Solvent separation test 9.2 Other information None known. : : : : : : : : : : 10. Stability and reactivity 10.1 Reactivity 10.2 Chemical stability The product is chemically stable Possibility of hazardous reactions Stability : Product is hygroscopic., No decomposition if stored and applied as directed Conditions to avoid 10.5 Incompatible materials Materials to avoid : Combustible material 6 / 11

7 10.6 Hazardous decomposition products Hazardous decomposition products : Carbon monoxide, nitrogen oxides (NOx) Thermal decomposition : ca. 360 C 11. Toxicological information 11.1 Information on toxicological effects Acute toxicity Acute oral toxicity: 2,2'-oxybisethanol di-isopropanolamine : LD50 rat: mg/kg : LD50 rat: mg/kg Acute inhalation toxicity: Acute dermal toxicity: 2,2'-oxybisethanol : LD50 rabbit: mg/kg Acute toxicity (other routes of administration): Skin corrosion/irritation di-isopropanolamine : Mild skin irritation Serious eye damage/eye irritation di-isopropanolamine : Blindness Respiratory or skin sensitization Sensitisation: Germ cell mutagenicity Genotoxicity in vitro: Carcinogenicity Reproductive toxicity 7 / 11

8 Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard Aspiration toxicity Neurological effects Toxicology Assessment Toxicology, Metabolism, Distribution Acute effects Further information 2,2'-oxybisethanol : Inhalation of high vapour concentrations can cause CNS-depression and narcosis. Liver and kidney injuries may occur. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. 12. Ecological information 12.1 Toxicity Toxicity to daphnia and other aquatic invertebrates 2,2'-oxybisethanol : EC50 (Daphnia magna (Water flea)): > mg/l Exposure time: 24 h Toxicity to bacteria 2,2'-oxybisethanol : EC0 (Pseudomonas putida): mg/l Exposure time: 16 h 12.2 Persistence and degradability 8 / 11

9 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects Additional ecological information : The product should not be allowed to enter drains, water courses or the soil. 13. Disposal considerations 13.1 Waste treatment methods Advice on disposal and packaging : Disposal: In accordance with local and national regulations. Do not dispose of waste into sewer. Do not dispose of together with household waste. Waste codes should be assigned by the user based on the application for which the product was used. 14. Transport information ADR Not dangerous goods RID Not dangerous goods IATA Not dangerous goods IMDG Not dangerous goods Special precautions for user see chapter: 6, 7 and Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 9 / 11

10 VOC : not applicable Directive 96/82/EC : Update: 2003 Directive 96/82/EC does not apply 15.2 Chemical Safety Assessment 16. Other information Full text of R-phrases referred to under sections 2 and 3 R22 Harmful if swallowed. R36 Irritating to eyes. Full text of H-Statements referred to under sections 2 and 3. H302 Harmful if swallowed. H319 Causes serious eye irritation. Other information 2 Where no specific short-term exposure limit is listed, a figure three times the long-term exposure should be used The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 10 / 11

11 Attachment to the Material Safety Data Sheet Involved parts CU7J M6C57 A1A 250 ml Part of kit: CU7J M6C57 B1A 500 ml Part of kit: CU7J M6C57 C1A 1 l Part of kit: CU7J M6C57 D1A 5 l Part of kit: - 11 / 11