Material Safety Data Sheet as per regulation (EC) 1907/2006

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/ undertaking 1.1 Product identifier Commercial Product Name PVC Adhesive 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses 1.3 Details of the supplier of the safety data sheet Company designation Adhesive for bonding pipes, gutters, profiles, moulded parts and panels made from PVC. fischerwerke GmbH & Co. KG Weinhalde D Waldachtal Telephone: +49(0) FAX: +49(0) Marketer Great Britain: Mrs Mirka Valovicova, fischer Fixing (UK) Ltd, Hithercroft Road, Wallingford, Oxfordshire, OX10 9AT, Tel , Fax Emergency telephone number Emergency telephone number SECTION 2: Hazards identification +49(0) (24h) 2.1 Classification of the substance or mixture Classification according to Directive 67/548/EEC / 1999/45/ EEC 2.2 Label elements Hazard symbols F; R11 Xi; R36/37 R66 R67 F: Highly flammable Xi: Irritant R-phrase(s) S-phrase(s) R11: Highly flammable. R36/37: Irritating to eyes and respiratory system. R66: Repeated may cause skin dryness or cracking. R67: Vapours may cause drowsiness and dizziness. S16: Keep away from sources of ignition - No smoking. S2: Keep out of the reach of children. S25: Avoid contact with eyes. 1 / 8

2 S3/7: Keep container tightly closed in a cool place. S51: Use only in well-ventilated areas. SECTION 3: Composition/information on ingredients Hazardous ingredients Ingredient butanone CAS No.: EC-No.: Index-No.: REACH No.: xxxx cyclohexanone CAS No.: EC-No.: Index-No.: REACH No.: xxxx tetrahydrofuran CAS No.: EC-No.: Index-No.: REACH No.: xxxx acetone CAS No.: EC-No.: Index-No.: REACH No.: xxxx Classification (EEC) No 67/548 Classification (EC) 1272/2008 F; R11 Xi; R36 R66 R67 Flam. Liq. 2; H225 Eye Irrit. 2; H319 STOT SE 3; H336 R10 Xn; R20 Flam. Liq. 3; H226 Acute Tox. 4 *; H332 F; R11-19 Xi; R36/37 Flam. Liq. 2; H225 Eye Irrit. 2; H319 STOT SE 3; H335 F; R11 Xi; R36 R66 R67 Flam. Liq. 2; H225 Eye Irrit. 2; H319 STOT SE 3; H336 Concentration < 30.0 % by weight < 20.0 % by weight < 15.0 % by weight < 10.0 % by weight SECTION 4: First aid measures 4.1 Description of first aid measures General advice If symptoms persist, call a physician. Remove/Take off immediately all contaminated clothing. If inhaled In case of skin contact In case of eye contact If swallowed IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF ON SKIN: Gently wash with plenty of soap and water. In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If swallowed, seek medical advice immediately and show this container or label. Clean mouth with water and drink afterwards plenty of water. Drink 1 or 2 glasses of water. Do NOT induce vomiting. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Carbon dioxide (CO2) Dry powder Foam Water spray jet 2 / 8

3 Extinguishing media which must not be used for safety reasons High volume water jet 5.2 Special hazards arising from the substance or mixture Special hazards arising from the substance or preparation itself, its combustion products, or released gases Heating or fire can release toxic gas. 5.3 Advice for firefighters Special protective equipment for firefighting Additional information on firefighting In the event of fire, wear self-contained breathing apparatus. In the event of fire and/or explosion do not breathe fumes. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Keep containers and surroundings cool with water spray. Container may rupture on heating. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions 6.2 Environmental precautions Environmental precautions Ensure adequate ventilation, especially in confined areas. Keep people away from and upwind of spill/leak. 6.3 Methods and material for containment and cleaning up Methods for cleaning up The product should not be allowed to enter drains, water courses or the soil. Prevent spreading over a wide area (e.g. by containment or oil barriers). Use mechanical handling equipment. Treat recovered material as described in the section "Disposal considerations". 6.5 Additional information Other information Dispose of in accordance with local regulations. SECTION 7: Handling and storage 7.1 Precautions for safe handling Advice on safe handling None under normal processing. Advice on protection against fire and explosion No special precautions required. 7.2 Conditions for safe storage, including any incompatibilities Storage space and container requirements Keep containers tightly closed in a cool, well-ventilated place. Store in accordance with local regulations. 3 / 8

4 Keep only in original container. Hints on storage assembly Store in accordance with the particular national regulations. German storage class 3 (TRGS 510) SECTION 8: Exposure controls/personal protection 8.1 Control parameters butanone, ethyl methyl ketone Great Britain Sk BMGV R11,36, 66, EH40/200 Workplace limits (October 2007) Europe 19 Issuing date / DIRECTIVE 2009/161/EU CYCLOHEXANONE Great Britain Sk BMGV R10, EH40/200 Workplace limits (October 2007) Europe Long-term mg/ m3 Long-term Short-term mg/ m3 Short-term Note Issuing date Skin 2000/ DIRECTIVE 2009/161/EU TETRAHYDROFURAN Great Britain Sk R11, 19,36/ EH40/200 Workplace limits (October 2007) 19 4 / 8

5 Europe Long-term mg/ m3 Long-term Short-term mg/ m3 Short-term Note Issuing date Skin 2000/ DIRECTIVE 2009/161/EU acetone, propan-2-one, propanone Great Britain R11 36, 66, EH40/200 Workplace limits (October 2007) Europe Issuing date / DIRECTIVE 2009/161/EU 8.2 Exposure controls Respiratory protection Hand protection No personal respiratory protective equipment normally required. Suitable material: Unsuitable material: Material thickness: Break through time: : Eye protection Skin and body protection Note: General protective and hygiene measures butyl-rubber, Nitrile rubber, Chloroprene PVC disposable gloves >= 0,5 mm >120 min Replace when worn. Request information on glove permeation properties from the glove supplier. Be aware that in daily use the durability of a chemical resistant protective glove can be notably shorter than the break through time measured according to EN 374, due to the numerous outside influences (e.g. temperature). Tightly fitting safety goggles Wear suitable protective equipment. Choose body protection according to the amount and concentration of the dangerous substance at the work place. Smoking, eating and drinking should be prohibited in the application area. Avoid contact with skin, eyes and clothing. Take off all contaminated clothing immediately. Wash hands before breaks and at the end of workday. Keep away from food, drink and animal feedingstuffs. Use protective skin cream before handling the product. 5 / 8

6 Information on environmental protection regulations No special environmental precautions required. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Form viscous liquid Colour Odour transparent solvent characteristic Boiling point [ C] > 35 C Flash point [ C] < 21 C Explosion limits [Vol-% ] Lower limit: 0,6 % Upper limit: 15 % Risk of explosion. Density [g/cm³] Not explosive 0,90-0,99 g/cm3 Temperature: 20 C Water solubility [g/l] insoluble Autoignition temperature [ C] > 240 C Autoinflammability not auto-flammable SECTION 10: Stability and reactivity 10.3 Possibility of hazardous reactions Hazardous reactions No dangerous reaction known under conditions of normal use Conditions to avoid Conditions to avoid No decomposition if used as directed Hazardous decomposition products Hazardous decomposition products SECTION 11: Toxicological information 11.1 Information on toxicological effects No decomposition if used as directed Additional information Other information (chapter 11.) There is no data available for this product. 6 / 8

7 SECTION 12: Ecological information 12.1 Toxicity 12.6 Other adverse effects Further information on ecology No information on ecology is available. SECTION 13: Disposal considerations 13.1 Waste treatment methods Disposal considerations Disposal together with normal waste is not allowed. Special disposal required according to local regulations. The product should not be allowed to enter drains, water courses or the soil. Empty remaining contents. Uncleaned empty packaging Dispose of as unused product. SECTION 14: Transport information Land transport ADR/RID *Marine transport IMDG Air transport ICAO/IATA UN-No Class Packaging group III III III Description of the goods ADHESIVES ADHESIVES Adhesives Proper shipping name ADHESIVES Adhesives Labels Flammable Liquid Risk No. 33 Category 3 Classification Code F1 SP G Tunnel restriction code D/E EmS Stowage category Leerzeile SECTION 15: Regulatory information containing flammable liquid, viscous substance - transport under IMDG- Code F-E;S-D A containing flammable liquid 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Cassification in compliance with the Industrial Safety Regulation 15.2 Chemical safety assessment Safety assessment highly flammable Not relevant. Chemical safety assessments for substances in this mixture were not carried out. 7 / 8

8 SECTION 16: Other information Relevant R-phrases Relevant H-phrases Wording of the hazard classes R10: Flammable. R11: Highly flammable. R19: May form explosive peroxides. R20: Harmful by inhalation. R36: Irritating to eyes. R36/37: Irritating to eyes and respiratory system. R66: Repeated may cause skin dryness or cracking. R67: Vapours may cause drowsiness and dizziness. H225: Highly flammable liquid and vapour. H226: Flammable liquid and vapour. H319: Causes serious eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation. H336: May cause drowsiness or dizziness. Flam. Liq.: Flammable liquid Eye Irrit.: Serious eye irritation STOT SE: Specific target organ toxicity - single Acute Tox.: Acute toxicity This information is provided in accordance with the current status of our knowledge and experience. The Safety Data Sheet describes products with a view to relevant safety requirements. This information does not constitute a warranty of properties, features or qualities. 8 / 8