1. Designation of the Material/Preparation and of the Company Variotherm FlexPutz

Transcription

1 Page 1/5 Variotherm FlexPutz Safety Data Sheet according to Article 31 and Annex II of Directive No. 1907/2006 of the European Parliament and the Council from 18/12/2006 Created on: 05/08/ Designation of the Material/Preparation and of the Company Variotherm FlexPutz 1.1. Designation of the material or preparation: 1.2. Use of the material or preparation: 1.3. Designation of the company: Factory-mixed, easily workable finishing plaster Variotherm Heizsysteme GmbH Günselsdorfer Strasse 3a, 2544 Leobersdorf, Austria Ph. 0043/2256/ Fax 0043/2256/ Emergency phone number: Poisoning Information Headquarters (VIZ) Vienna:+ 43/1/ Potential Hazards 2.1. The material/preparation is classified as hazardous in the sense of the Guidelines 67/548/EWG and 1999/45/EG 2.2. Classification: 2.3. R paragraphs: R 37/38: Irritates the breathing organs and the skin R41: Danger of serious eye damage R43: Sensitivity through skin contact is possible 3. Composition/Information on the Components Composition: 3.1. Preparation of low-chromate cement as per EU-RL 2003/53/EG, aggregates and additives 3.2. Hazardous ingredients: Name EINECS No.: Content Classificati on Portland cement % - 20% Calcium hydroxide % - 20% The phrasing of the listed R paragraphs is to be taken from point 16 (x i ) (x i ) Symbol R paragraphs R37/38, R41, R 43 R 37/38 R41

2 Safety Data Sheet: Variotherm FlexPutz Page 2 of 5 4. First-aid Measures 4.1. General information: Render assistance quickly 4.2. Inhalation: Ensure fresh air. Consult a doctor if symptoms persist Skin contact: In the case of skin contact wash immediately with copious amounts of water. Remove soiled clothing. Consult a doctor if symptoms persist Eye contact: In the case of eye contact rinse the eyes thoroughly (for approx. 10 minutes) with copious amounts of water (or special saline solution for eyes, eyewash). Do not rub the eyes dry because mechanical abrasion can cause additional corneal damage. Always immediately consult an eye specialist Swallowing: If conscious rinse the mouth and drink copious amounts of water in small gulps. Do not induce vomiting. Immediately consult a doctor Notes for the doctor: No long-term effects are known. 5. Fire Fighting Measures 5.1. Suitable extinguishing agents: 5.2. Extinguishing agents that are unsuitable for safety reasons: 5.3. Decomposition products: None 5.4. Special extinguishing The preparation does not burn. instructions: The preparation is not inflammable when delivered or when mixed. The extinguishing agents and fire fighting measures are to be matched to the local fire. 6. Measures in the Case of Unintentional Release 6.1. Personal precautionary measures: 6.2. Environmental protection measures: Avoid contact with eyes and skin. Individual protective measures (see point 8). An air extraction system for buildings is recommended in order to keep the dust concentration as low as possible. Keep the preparation dry. Cover the preparation to avoid dust formation. Do not allow the preparation to enter the sewage system, surface water or groundwater (increases the ph value) Cleaning procedure: Clean with a dry mechanical system (e.g. vacuum cleaner), allow a mixed preparation to harden and dispose in an appropriate manner (according to point 13). 7. Handling and Storage 7.1. Handling: Avoid formation of dust and contact with water. Use personal safety equipment as per point 8 to avoid contact with the eyes and skin and prevent dust Storage: Store in a dry place. Avoid contact with moisture. Store in original packaging. Observe the manufacturer's storage instructions.

3 Safety Data Sheet: Variotherm FlexPutz Page 3 of 5 8. Limiting of Exposure and Personal Protective Equipment 8.1. Exposure limit values: GKV 2006 (according to the currently valid version of BGBL.II No. 242/2006, Materials List Annex I) 8.2. Additional notes on the design of technical systems: General protection and hygiene measures: Breathing protection: Hand protection: Eye protection: Mean daily value: 5 mg/m 3 inhalable fraction (Portland cement (dust)) Mean daily value: 2 mg/m 3 inhalable fraction Short-term mean value: 4 mg/m 3 inhalable fraction; duration of 5 min (calcium hydroxide (dust)) Avoid formation of dust during handling or provide an appropriate ventilation system or use an enclosed handling system. Avoid contact with eyes and skin. Wear dry clothing. Change soiled clothing. Do not eat, drink or smoke when working. Thoroughly wash hands after work and before breaks. Provide washing facilities at the workplace. Shower after heavy exposure. Wear a particle filter dust mask (e.g. EN 149 FFP1) when exposure limits are exceeded (e.g. when mixing). Wear nitrile-impregnated gloves with a CE certification symbol. Wear full-sealing protective goggles when dust develops or a danger of splashing is present. (Provide eyewash). Skin protection cream Wear closed work clothing with long arms and closed shoes. Skin protection: Body protection: Limiting and monitoring of environmental exposure: Equip the ventilation system with filters. 9. Physical and Chemical Properties 9.1. General information: Appearance: Fine stone particle mixture with mineral additives, Portland cement and calcium hydroxide Colour: White Odour: Odourless 9.2. Important information on health protection and environmental protection and safety ph value ph when mixed and used according to the specifications None General data: Melting point: Boiling point/boiling range: Ignition point:, solid material is not ignitable Explosion danger: None Fire-enhancing properties None Inflammability: Not inflammable Ignition temperature: Density: Water solubility: Low Bulk density: kg/m³ at 20 C No further information on the physical and chemical properties as per RL 91/155/EWG is provided because this is not applicable. 10. Stability and Reactivity Conditions to be avoided: Moisture: The preparation hardens in contact with water. Alkaline reaction with water Materials to be avoided: None known Dangerous decomposition products: No dangerous decomposition products are known. All specifications assume appropriate use of the product.

4 Safety Data Sheet: Variotherm FlexPutz Page 4 of Toxicological Information Irritation effects: Acute toxicity Inhaled: Oral: Dermal: Eye contact: Other specifications 12. Environmental Specifications Ecological toxicity The product has not been tested. The preparation has been classified according to the conventional method (calculation process as per EU Directive 1999/45/EG) and according to the toxic dangers. Irritates the skin and mucous membranes. Causes irritation of the upper breathing tract. Non-toxic. Large amounts can cause irritation of the digestive tract. Irritation of intact skin in combination with moisture. Severe irritation in the case of damaged or injured skin. Causes irritation in the case of eye contact. Possible mechanical abrasion from dust. Multiple and constant exposure can result in sensitivity or severe impairment. Increase in ph value when combined in large quantities with water. The ph value drops rapidly with dilution. (inorganic mineral material) Other ecological information is not available. 13. Notes on Disposal Disposal: EAK (EWC) Collect using a dry system, dispose according to the local and official regulations. Mix unused residual cement with water, while avoiding skin contact, then allow to harden and dispose of as concrete waste. Do not dispose in the household waste. Do not dispose in the water drain or toilet Concrete waste and concrete sludge 14. Transport Specifications Classification The product is not classified according to the currently applicable hazardous goods regulations. ADR (road) No designation required RID (rail) No designation required IMDG / GGVSea (sea No designation required transport) IATA-DGR / ICTAO-TI No designation required (air freight) Special protective measures: Store in a dry place. Avoid dust formation during transport. Use a SILO truck for bulk material. (see point 8.2)

5 Safety Data Sheet: Variotherm FlexPutz Page 5 of Information on the Legal Requirements Identification as per RL 67/548/EWG and RL 1999/45/EG in the applicable versions: Danger symbol and danger designation: Chemical designation of the cause of the hazard: Portland cement Calcium hydroxide R paragraphs: R 37/38: Irritates the breathing organs and the skin R41: Danger of serious eye damage S paragraphs: S2: Must not reach the hands of children. S22: Do not inhale the dust S24/25: Avoid contact with eyes and skin. S26: In the case of contact with the eyes rinse thoroughly with water and seek medical advice. S28: In the case of skin contact wash immediately with copious amounts of water. S36/37/39: Wear appropriate protective clothing, protective gloves and protective goggles/face protection when working with the product. S46: If swallowed immediately seek medical advice and present the product packaging or label. The provisions of the currently applicable versions of the employee protection/consumer protection legislation and associated directives are to be observed. 16. Other Specifications List of relevant R paragraphs: (Points 2 and 3) The following R paragraphs do not represent the classification of the preparation: R37/38: Irritates the breathing organs and the skin; R41: Danger of serious eye damage, R43: Sensitivity through skin contact is possible Modified from the last version: for Portland cement brick R41 instead of R36 Created by: Laboratory