: Sodium thiosulfate, conc. to prepare 1 L of solution 0.1 M (0.1 N) VSA

Transcription

1 Sodium thiosulfate, conc. to prepare 1 L of solution 0.1 M (0.1 N) VSA Date of issue: 31/03/2011 Revision date: 05/12/2016 Supersedes: 30/08/2016 Version: 2.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name : Substance : EC no : CAS No : REACH registration No : Product code : SOTH-01C Formula : Na2O3S Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category : Laboratory use Uses advised against 1.3. Details of the supplier of the safety data sheet labbox labware s.l. Joan Peiró i Belis, Vilassar de Dalt - ES T F info@labkem.com Emergency telephone number Emergency number : ( Office Hours) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display No labelling applicable 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Name Product identifier % Sodium thiosulfate, volumetric solutions (CAS No) (EC no) (REACH-no) Full text of H-statements: see section Mixtures Not applicable 99 05/12/2016 EN (English) 1/6

2 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Get medical advice/attention if you feel unwell. : Remove person to fresh air and keep comfortable for breathing. When symptoms occur: go into open air and ventilate suspected area. If you feel unwell, seek medical advice. : Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. : Rinse eyes with water as a precaution. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do not induce vomiting. Call a physician immediately Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Never give anything by mouth to an unconscious person. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water spray. Sand. Carbon dioxide. Foam. Dry powder. : Strong water jet Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : fume Advice for firefighters Precautionary measures fire : Evacuate area. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Evacuate area For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Breathing apparatus. : Ventilate area. Stop leak if safe to do so Environmental precautions Prevent entry to sewers and public waters. Avoid release to the environment Methods and material for containment and cleaning up For containment : Collect spillage. Methods for cleaning up : On land, sweep or shovel into suitable containers. Collect spillage Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Keep only in original container Specific end use(s) Laboratory chemicals. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 05/12/2016 EN (English) 2/6

3 8.2. Exposure controls Hand protection: protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: Wear appropriate mask Other information: The present safety data sheet is consistent with the specific conditions relied on to justify the registration of the substance in accordance with Article 17 or 18 of the REACH regulation. Do not eat, drink or smoke during use. Wash hands with water as a precaution. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Colour Odour Odour threshold : Liquid : Colourless. : odourless. ph : 6-7,5 Relative evaporation rate (butylacetate=1) Melting point : 48 C Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density : 1,73 Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Incompatible materials : 1,22 g/cm³ : Water: 700 g/dm3 (20 C) 05/12/2016 EN (English) 3/6

4 10.6. Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity ( ) LD50 oral rat > 5000 mg/kg Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard ph: 6-7,5 ph: 6-7,5 SECTION 12: Ecological information Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) : Disposal must be done according to official regulations. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) 05/12/2016 EN (English) 4/6

5 14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions is not on the REACH Candidate List is not on the REACH Annex XIV List 05/12/2016 EN (English) 5/6

6 National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling : Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex 1 or 2; ID No. 386) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Chemical safety assessment SECTION 16: Other information SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 05/12/2016 EN (English) 6/6