: Benzoic acid Analytical Grade

Transcription

1 Date of issue: 13/08/2015 Revision date: 08/11/2016 Supersedes: 13/08/2015 Version: 2.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance Trade name : EC no : CAS No : REACH registration No : Product code : BNZA-00A Formula : C₇ H₆ O₂ 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category : Laboratory use Uses advised against 1.3. Details of the supplier of the safety data sheet labbox labware s.l. Joan Peiró i Belis, Vilassar de Dalt - ES T F info@labkem.com Emergency telephone number Emergency number : ( Office Hours) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Acute toxicity (oral), Category 4 Skin corrosion/irritation, Category 2 Serious eye damage/eye irritation, Category 2 H302 H315 H319 Specific target organ toxicity Repeated exposure, Category 1 H372 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS07 : Warning : H302 - Harmful if swallowed H319 - Causes serious eye irritation : P280 - Wear protective gloves/protective clothing/eye protection/face protection P337+P313 - If eye irritation persists: Get medical advice/attention 2.3. Other hazards 08/11/2016 EN (English) 1/6

2 SECTION 3: Composition/information on ingredients 3.1. Substances Name Product identifier % Benzoic acid (CAS No) (EC no) (REACH-no) Full text of H-statements: see section Mixtures Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Get medical advice/attention if you feel unwell. : Remove person to fresh air and keep comfortable for breathing. Get medical advice/attention if you feel unwell. When symptoms occur: go into open air and ventilate suspected area. : Gently wash with plenty of soap and water. Wash contaminated clothing before reuse. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. : Rinse eyes with water as a precaution. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention. : Rinse mouth. Do not induce vomiting. Call a physician immediately. Get immediate medical advice/attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after eye contact Symptoms/injuries after ingestion : Causes serious eye irritation. : Swallowing a small quantity of this material will result in serious health hazard Indication of any immediate medical attention and special treatment needed Never give anything by mouth to an unconscious person. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water spray. Sand. Carbon dioxide. Foam. Dry powder. : Strong water jet Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : fume Advice for firefighters Precautionary measures fire Firefighting instructions Protection during firefighting : Stop leak if safe to do so. : Exercise caution when fighting any chemical fire. : Do not attempt to take action without suitable protective equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Stop leak if safe to do so Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters Methods and material for containment and cleaning up For containment : Collect spillage. Methods for cleaning up : Take up liquid spill into absorbent material. Collect spillage. Other information : Dispose of materials or solid residues at an authorized site Reference to other sections 08/11/2016 EN (English) 2/6

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage area : Store in a well-ventilated place. Special rules on packaging : Store in a closed container. Keep only in original container Specific end use(s) Laboratory chemicals. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Personal protective equipment: Avoid all unnecessary exposure. Safety glasses. Protective goggles. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Respiratory protection of the dependent type. Protective clothing. Environmental exposure controls: Avoid release to the environment. Consumer exposure controls: Avoid contact during pregnancy/while nursing. Other information: The present safety data sheet is consistent with the specific conditions relied on to justify the registration of the substance as isolated intermediate. Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Colour Odour Odour threshold : Solid : white. : characteristic. ph : 2,5-3,5 Relative evaporation rate (butylacetate=1) Melting point : 122 C Freezing point Boiling point : 249 Flash point Auto-ignition temperature : 570 Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density : 0,001 hpa : 1,321 g/cm³ Solubility : Water: 2900 mg/l 25ºC Log Pow : 1,88 08/11/2016 EN (English) 3/6

4 Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Extremely high or low temperatures. Direct sunlight Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Oral: Harmful if swallowed. ( ) LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (Dust/Mist - mg/l/4h) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard 1700 mg/kg 5000 mg/kg 12,2 mg/l/4h : Causes skin irritation. ph: 2,5-3,5 : Causes serious eye irritation. ph: 2,5-3,5 : Causes damage to organs through prolonged or repeated exposure. SECTION 12: Ecological information Toxicity ( ) LC50 fish 1 44,6 mg/l 96 H Persistence and degradability ( ) Biodegradation 71 % Bioaccumulative potential ( ) Log Pow 1, Mobility in soil 08/11/2016 EN (English) 4/6

5 12.5. Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user - Overland transport - Transport by sea 08/11/2016 EN (English) 5/6

6 - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions is not on the REACH Candidate List is not on the REACH Annex XIV List National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Denmark Recommendations Danish Regulation : Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex 1 or 2; ID No. 30) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product Chemical safety assessment SECTION 16: Other information Full text of H- and EUH-statements: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 1 Specific target organ toxicity Repeated exposure, Category 1 H302 Harmful if swallowed H315 H319 H372 Causes skin irritation Causes serious eye irritation Causes damage to organs through prolonged or repeated exposure SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 08/11/2016 EN (English) 6/6