CITRIC ACID MONOHYDRATE AR/ACS MSDS. CAS-No.: MSDS MATERIAL SAFETY DATA SHEET (MSDS)

Transcription

1 MSDS CAS-No.: MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance : CAS-No. : Product code : Chemical structure : 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec : Industrial For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number : (9:00am - 6:00 pm) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Serious eye damage/eye irritation, Category 2 H319 Full text of H statements : see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Xi; R36 Full text of R-phrases: see section /05/2016 1/8

2 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS07 : Warning : H319 - Causes serious eye irritation. : P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Name : CAS-No. : Full text of R- and H-statements: see section Mixtures Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Assure fresh air breathing. Allow the victim to rest. : Wash with plenty of water/. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. : Rinse mouth. Do not induce vomiting Most important symptoms and effects, both acute and delayed Symptoms/effects after eye contact : Causes serious eye irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. 20/05/2016 2/8

3 SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray. : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Use personal protective equipment as required. : Ventilate area Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. On land, sweep or shovel into suitable containers Precautions for safe handling Precautions for safe handling Hygiene measures : Avoid contact with skin and eyes. Do not breathe vapours. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep container tightly closed Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 20/05/2016 3/8

4 8.2. Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection : Protective gloves : Chemical goggles or safety glasses : Wear suitable protective clothing : [In case of inadequate ventilation] wear respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Molecular mass Colour Odour Odour threshold : g/mol : White crystalline. : odourless. ph : 1.8 at 50 g/l at 20 C Relative evaporation rate (butylacetate=1) Melting point : 153 C Freezing point Boiling point : 175 C Flash point : C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure : mm Hg at 25 C Relative vapour density at 20 C : 7.26 Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : g/cm³ : Water: 59.2 % (20 C) 9.2. Other information 20/05/2016 4/8

5 SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Air contact. Direct sunlight. Moisture Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity ph: 1.8 at 50 g/l at 20 C : Causes serious eye irritation. ph: 1.8 at 50 g/l at 20 C Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard SECTION 12: Ecological information Toxicity 20/05/2016 5/8

6 12.2. Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID 20/05/2016 6/8

7 Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions is not on the REACH Candidate List is not on the REACH Annex XIV List National regulations Germany Reference to AwSV 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV; ID No. 8248) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) 20/05/2016 7/8

8 Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Chemical safety assessment SECTION 16: Other information Full text of R-, H- and EUH-statements: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation. R36 Irritating to eyes Xi Irritant This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 20/05/2016 8/8