MATERIAL SAFETY DATA SHEET (MSDS)

Transcription

1 ZINC SULPHATE 0.1 MOL/L (0.1M) FOR 500ML SOLUTION MSDS CAS-No. MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Mixture Product code Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Industrial For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number (900am pm) SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances SDS EU 2015 According to Regulation (EU) 2015/830 (REACH Annex II) Serious eye damage/eye irritation, Category 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 H319 H411 Full text of H statements see section 16 Adverse physicochemical, human health and environmental effects 05/01/2019 1/10

2 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS07 Warning GHS09 H319 - Causes serious eye irritation. H411 - Toxic to aquatic life with long lasting effects. P273 - Avoid release to the environment. P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Other hazards SECTION 3 Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] WATER AR (CAS-No.) Not classified (EC-No.) ZINC SULPHATE HEPTAHYDRATE AR/ACS (CAS-No.) Acute Tox. 4 (Oral), H302 Eye Dam. 1, H318 Aquatic Chronic 1, H410 Full text of H-statements see section 16 SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Remove person to fresh air and keep comfortable for breathing. Wash skin with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists Get medical advice/attention. Rinse mouth out with water. 05/01/2019 2/10

3 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after eye contact Causes serious eye irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Protection during firefighting Do not attempt to take action without suitable protective equipment. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Avoid contact with skin, eyes and clothing. Use personal protective equipment as required Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Clean contaminated surfaces with an excess of water Reference to other sections SECTION 7 Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Conditions for safe storage, including any incompatibilities Storage conditions Store in a well-ventilated place. Keep container tightly closed Specific end use(s) SECTION 8 Exposure controls/personal protection 8.1. Control parameters 05/01/2019 3/10

4 8.2. Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection Protective gloves Chemical goggles or safety glasses Wear suitable protective clothing Wear respiratory protection. SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Molecular mass Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits g/mol Clear Colorless. No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available 9.2. Other information SECTION 10 Stability and reactivity Reactivity 05/01/2019 4/10

5 10.2. Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Direct sunlight Incompatible materials Hazardous decomposition products SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Not classified Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Not classified Causes serious eye irritation. Not classified Not classified Not classified Reproductive toxicity STOT-single exposure Not classified Not classified STOT-repeated exposure Not classified Aspiration hazard Not classified SECTION 12 Ecological information Toxicity Persistence and degradability ZINC SULPHATE HEPTAHYDRATE AR/ACS ( ) Persistence and degradability May cause long-term adverse effects in the environment Bioaccumulative potential 05/01/2019 5/10

6 12.4. Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13 Disposal considerations Waste treatment methods SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 3082 UN-No. (IMDG) 3082 UN-No. (IATA) 3082 UN-No. (ADN) 3082 UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) Transport document description (ADN) Transport document description (RID) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Environmentally hazardous substance, liquid, n.o.s. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III, (-) UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III, MARINE POLLUTANT UN 3082 Environmentally hazardous substance, liquid, n.o.s., 9, III UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III Transport hazard class(es) ADR Transport hazard class(es) (ADR) 9 Danger labels (ADR) 9 IMDG Transport hazard class(es) (IMDG) /01/2019 6/10

7 Danger labels (IMDG) 9 IATA Transport hazard class(es) (IATA) 9 Hazard labels (IATA) 9 ADN Transport hazard class(es) (ADN) 9 Danger labels (ADN) 9 RID Transport hazard class(es) (RID) 9 Danger labels (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information III III III III III Yes Yes No supplementary information available Special precautions for user - Overland transport Classification code (ADR) M6 Special provisions (ADR) 274, 335, 375, 601 Limited quantities (ADR) 5l Excepted quantities (ADR) E1 05/01/2019 7/10

8 Packing instructions (ADR) Special packing provisions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage P001, IBC03, LP01, R001 PP1 MP19 T4 TP1, TP29 LGBV AT Transport category (ADR) 3 Special provisions for carriage - Packages (ADR) Special provisions for carriage - Loading, unloading and handling (ADR) V12 CV13 Hazard identification number (Kemler No.) 90 Orange plates Tunnel restriction code (ADR) - EAC code - Transport by sea 3Z Special provisions (IMDG) 274, 335, 969 Limited quantities (IMDG) Excepted quantities (IMDG) Packing instructions (IMDG) Special packing provisions (IMDG) IBC packing instructions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) 5 L E1 LP01, P001 PP1 IBC03 T4 TP2, TP29 F-A S-F A E1 Y964 30kgG PCA packing instructions (IATA) 964 PCA max net quantity (IATA) 450L CAO packing instructions (IATA) 964 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) - Inland waterway transport Classification code (ADN) 450L A97, A158, A197 9L M6 Special provisions (ADN) 274, 335, 375, 601 Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) Equipment required (ADN) 5 L E1 T PP Number of blue cones/lights (ADN) /01/2019 8/10

9 - Rail transport Classification code (RID) M6 Special provisions (RID) 274, 335, 375, 601 Excepted quantities (RID) Packing instructions (RID) Special packing provisions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) E1 P001, IBC03, LP01, R001 PP1 MP19 T4 Transport category (RID) 3 Special provisions for carriage Packages (RID) Special provisions for carriage - Loading, unloading and handling (RID) Colis express (express parcels) (RID) TP1, TP29 LGBV W12 CW13, CW31 CE8 Hazard identification number (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany Reference to AwSV 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Water hazard class (WGK) 3, Highly hazardous to water (Classification according to AwSV, Annex 1) Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling None of the components are listed None of the components are listed None of the components are listed None of the components are listed None of the components are listed 05/01/2019 9/10

10 15.2. Chemical safety assessment SECTION 16 Other information Full text of H- and EUH-statements Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 H302 Harmful if swallowed. H318 Causes serious eye damage. H319 Causes serious eye irritation. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 05/01/ /10