ANTIMONY METAL LUMPS EXTRA PURE MSDS. CAS-No.: MSDS MATERIAL SAFETY DATA SHEET (MSDS)

Transcription

1 ANTIMONY METAL LUMPS EXTRA PURE MSDS CAS-No MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Substance CAS-No Product code Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture Laboratory chemicals, Manufacture of substances Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number (900am pm) SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute toxicity (inhal.), Category 4 Acute toxicity (oral), Category 4 Hazardous to the aquatic environment Chronic Hazard, Category 2 H332 H302 H411 Full text of hazard classes and H-statements see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Xn; R20/22 N; R51/53 Full text of R-phrases see section /04/2016 1/10

2 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS07 Warning GHS09 H302+H332 - Harmful if swallowed or if inhaled H411 - Toxic to aquatic life with long lasting effects. P273 - Avoid release to the environment Other hazards SECTION 3 Composition/information on ingredients 3.1. Substances Name ANTIMONY METAL LUMPS Extra Pure CAS-No Full text of R- and H-statements see section Mixtures Not applicable SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation Symptoms/effects after ingestion Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Wash with plenty of water/. Get immediate medical advice/attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. Rinse mouth. Call a POISON CENTER/doctor if you feel unwell. Harmful if inhaled. Harmful if swallowed. 26/04/2016 2/10

3 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Carbon dioxide. Dry powder. Foam. Water spray. Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures Evacuate unnecessary personnel. Use personal protective equipment as required. Ventilate area Environmental precautions Toxic to aquatic life with long lasting effects Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections SECTION 7 Handling and storage Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Minimize generation of dust Precautions for safe handling Precautions for safe handling Hygiene measures Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour. Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Conditions for safe storage, including any incompatibilities Storage conditions 7.3. Specific end use(s) SECTION 8 Exposure controls/personal protection 8.1. Control parameters Store in a well-ventilated place. Keep container tightly closed. Store in a dry place. Protect from moisture. 26/04/2016 3/10

4 8.2. Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection Protective gloves Chemical goggles or safety glasses Wear suitable protective clothing [In case of inadequate ventilation] wear respiratory protection. SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Solid Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Grayish black lumps. Melting point 630 C Freezing point Boiling point 1635 C Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits g/cm³ Water Insoluble in cold water 26/04/2016 4/10

5 9.2. Other information SECTION 10 Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Direct sunlight. Air contact. Moisture Incompatible materials Hazardous decomposition products SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Inhalation Harmful if inhaled. Oral Harmful if swallowed. Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard Potential adverse human health effects and symptoms Harmful if swallowed. SECTION 12 Ecological information Toxicity Ecology - water Toxic to aquatic life with long lasting effects. 26/04/2016 5/10

6 12.2. Persistence and degradability ANTIMONY METAL LUMPS Extra Pure ( ) Persistence and degradability May cause long-term adverse effects in the environment Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13 Disposal considerations Waste treatment methods Product/Packaging disposal recommendations Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 2871 UN-No. (IMDG) 2871 UN-No. (IATA) 2871 UN-No. (ADN) 2871 UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) Transport document description (ADN) Transport document description (RID) ANTIMONY POWDER ANTIMONY POWDER Antimony powder ANTIMONY POWDER ANTIMONY POWDER UN 2871 ANTIMONY POWDER, 6.1, III, (E), ENVIRONMENTALLY HAZARDOUS UN 2871 ANTIMONY POWDER, 6.1, III, MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS UN 2871 Antimony powder, 6.1, III, ENVIRONMENTALLY HAZARDOUS UN 2871 ANTIMONY POWDER, 6.1, III, ENVIRONMENTALLY HAZARDOUS UN 2871 ANTIMONY POWDER, 6.1, III, ENVIRONMENTALLY HAZARDOUS Transport hazard class(es) ADR Transport hazard class(es) (ADR) /04/2016 6/10

7 Danger labels (ADR) 6.1 IMDG Transport hazard class(es) (IMDG) 6.1 Danger labels (IMDG) 6.1 IATA Transport hazard class(es) (IATA) 6.1 Hazard labels (IATA) 6.1 ADN Transport hazard class(es) (ADN) 6.1 Danger labels (ADN) 6.1 RID Transport hazard class(es) (RID) 6.1 Danger labels (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment III III III III III Yes 26/04/2016 7/10

8 Marine pollutant Other information Yes No supplementary information available Special precautions for user - Overland transport Classification code (ADR) Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Special packing provisions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Tank special provisions (ADR) Vehicle for tank carriage T5 5kg E1 P002, IBC08, LP02, R001 B3 MP10 T1 TP33 SGAH, L4BH TU15, TE19 AT Transport category (ADR) 2 Special provisions for carriage - Bulk (ADR) Special provisions for carriage - Loading, unloading and handling (ADR) Special provisions for carriage - Operation (ADR) VC1, VC2, AP7 CV13, CV28 S9 Hazard identification number (Kemler No.) 60 Orange plates Tunnel restriction code (ADR) EAC code E 2X - Transport by sea Packing instructions (IMDG) IBC packing instructions (IMDG) IBC special provisions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) Properties and observations (IMDG) P002, LP02 IBC08 B3 T1 TP33 F-A S-A A MFAG-No Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) Metallic antimony in the form of a fine grey powder. Insoluble in water. Toxic if swallowed, by skin contact or by dust inhalation. E1 Y645 10kg PCA packing instructions (IATA) 670 PCA max net quantity (IATA) 100kg CAO packing instructions (IATA) /04/2016 8/10

9 CAO max net quantity (IATA) ERG code (IATA) 200kg 6L - Inland waterway transport Classification code (ADN) T5 Special provisions (ADN) 802 Limited quantities (ADN) Excepted quantities (ADN) Equipment required (ADN) 5 kg E1 Number of blue cones/lights (ADN) 0 - Rail transport Classification code (RID) Excepted quantities (RID) Packing instructions (RID) Special packing provisions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) Special provisions for RID tanks (RID) PP, EP T5 E1 P002, IBC08, LP02, R001 B3 MP10 T1 Transport category (RID) 2 Special provisions for carriage Bulk (RID) Special provisions for carriage - Loading, unloading and handling (RID) Colis express (express parcels) (RID) TP33 SGAH, L4BH TU15 VC1, VC2, AP7 CW13, CW28, CW31 CE11 Hazard identification number (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions ANTIMONY METAL LUMPS Extra Pure is not on the REACH Candidate List ANTIMONY METAL LUMPS Extra Pure is not on the REACH Annex XIV List National regulations Germany 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) 26/04/2016 9/10

10 Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling The substance is not listed The substance is not listed The substance is not listed The substance is not listed The substance is not listed Denmark Recommendations Danish Regulation Young people below the age of 18 years are not allowed to use the product Chemical safety assessment SECTION 16 Other information Full text of R-, H- and EUH-statements Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 H302 Harmful if swallowed. H332 Harmful if inhaled. H411 Toxic to aquatic life with long lasting effects. R20/22 Harmful by inhalation and if swallowed R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment N Dangerous for the environment Xn Harmful This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 26/04/ /10