CAS No: MSDS 2,3-DICHLORO-5,6-DICYANO-P- BENZOQUINONE FOR SYNTHESIS MSDS MATERIAL SAFETY DATA SHEET (MSDS)

Transcription

1 2,3-DICHLORO-5,6-DICYANO-P- BENZOQUINONE FOR SYNTHESIS MSDS CAS No MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Substance EC no CAS No Product code 3276D 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture Industrial. For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number (900am pm) SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute toxicity (oral), Category 3 H301 Full text of classification categories and H statements see section 16 Classification according to Directive 67/548/EEC or 1999/45/EC T; R25 R29 Full text of R-phrases see section /05/2016 1/10

2 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) EUH phrases GHS06 Danger H301 - Toxic if swallowed P301+P310 - IF SWALLOWED immediately call a POISON CENTER or doctor/physician EUH029 - Contact with water liberates toxic gas 2.3. Other hazards SECTION 3 Composition/information on ingredients 3.1. Substance Name 2,3-DICHLORO-5,6-DICYANO-p-BENZOQUINONE for synthesis CAS No EC no Full text of R- and H-phrases see section Mixture Not applicable SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Wash with plenty of soap and water. Get medical advice/attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. Rinse mouth. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries Symptoms/injuries after ingestion Not expected to present a significant hazard under anticipated conditions of normal use. Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. 25/05/2016 2/10

3 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Carbon dioxide. Dry powder. Foam. Water spray. Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures Evacuate unnecessary personnel. Use personal protective equipment as required. Ventilate area Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections SECTION 7 Handling and storage Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. On land, sweep or shovel into suitable containers Precautions for safe handling Precautions for safe handling Hygiene measures Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour. Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Conditions for safe storage, including any incompatibilities Storage conditions Store in a well-ventilated place. Keep container tightly closed Specific end use(s) SECTION 8 Exposure controls/personal protection 8.1. Control parameters 25/05/2016 3/10

4 8.2. Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection Protective gloves Chemical goggles or safety glasses Wear suitable protective clothing Wear respiratory protection SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Solid Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Dark yellow. Melting point C Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information 25/05/2016 4/10

5 SECTION 10 Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Highly reactive material. Contact with water liberates toxic gas Conditions to avoid Direct sunlight. Overheating. Open flame. Heat Incompatible materials Hazardous decomposition products SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Oral Toxic if swallowed. Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms Toxic if swallowed. SECTION 12 Ecological information Toxicity 25/05/2016 5/10

6 12.2. Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13 Disposal considerations Waste treatment methods Product/Packaging disposal recommendations Ecology - waste materials Dispose of contents/container to... Hazardous waste due to toxicity. SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 3439 UN-No. (IMDG) 3439 UN-No.(IATA) 3439 UN-No.(ADN) 3439 UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) Transport document description (ADN) Transport document description (RID) NITRILES, SOLID, TOXIC, N.O.S. NITRILES, SOLID, TOXIC, N.O.S. NITRILES, TOXIC, SOLID, N.O.S. NITRILES, SOLID, TOXIC, N.O.S. NITRILES, SOLID, TOXIC, N.O.S. UN 3439 NITRILES, SOLID, TOXIC, N.O.S., 6.1, III, (E) UN 3439 NITRILES, SOLID, TOXIC, N.O.S., 6.1, III UN 3439 NITRILES, TOXIC, SOLID, N.O.S., 6.1, III UN 3439 NITRILES, SOLID, TOXIC, N.O.S., 6.1, III UN 3439 NITRILES, SOLID, TOXIC, N.O.S., 6.1, III Transport hazard class(es) ADR Transport hazard class(es) (ADR) 6.1 Danger labels (ADR) /05/2016 6/10

7 IMDG Transport hazard class(es) (IMDG) 6.1 Danger labels (IMDG) 6.1 IATA Transport hazard class(es) (IATA) 6.1 Hazard labels (IATA) 6.1 ADN Transport hazard class(es) (ADN) 6.1 Danger labels (ADN) 6.1 RID Transport hazard class(es) (RID) 6.1 Danger labels (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information III III III III III No No No supplementary information available 25/05/2016 7/10

8 14.6. Special precautions for user - Overland transport Classification code (ADR) T2 Special provision (ADR) 274 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Special packing provisions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Tank special provisions (ADR) Vehicle for tank carriage 5kg E1 P002, IBC08, LP02, R001 B3 MP10 T1 TP33 SGAH, L4BH TU15, TE19 AT Transport category (ADR) 2 Special provisions for carriage - Bulk (ADR) Special provisions for carriage - Loading, unloading and handling (ADR) Special provisions for carriage - Operation (ADR) VC1, VC2, AP7 CV13, CV28 S9 Hazard identification number (Kemler No.) 60 Orange plates Tunnel restriction code (ADR) EAC code E 2X - Transport by sea Special provision (IMDG) 223, 274 Limited quantities (IMDG) Excepted quantities (IMDG) Packing instructions (IMDG) IBC packing instructions (IMDG) IBC special provisions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) Segregation (IMDG) 5 kg E1 P002, LP02 IBC08 B3 T1 TP33 F-A S-A A SG35 MFAG-No Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) E1 Y645 10kg PCA packing instructions (IATA) 670 PCA max net quantity (IATA) 100kg CAO packing instructions (IATA) /05/2016 8/10

9 CAO max net quantity (IATA) Special provision (IATA) ERG code (IATA) 200kg A3, A5 6L - Inland waterway transport Classification code (ADN) T2 Special provisions (ADN) 274, 802 Limited quantities (ADN) Excepted quantities (ADN) Equipment required (ADN) 5 kg E1 Number of blue cones/lights (ADN) 0 - Rail transport Classification code (RID) PP, EP T2 Special provision (RID) 274 Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Special packing provisions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) Special provisions for RID tanks (RID) 5kg E1 P002, IBC08, LP02, R001 B3 MP10 T1 Transport category (RID) 2 Special provisions for carriage Bulk (RID) Special provisions for carriage Loading and unloading (RID) Colis express (express parcels) (RID) TP33 SGAH, L4BH TU15 VC1, VC2, AP7 CW13, CW28, CW31 CE11 Hazard identification number (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions 2,3-DICHLORO-5,6-DICYANO-p-BENZOQUINONE for synthesis is not on the REACH Candidate List 2,3-DICHLORO-5,6-DICYANO-p-BENZOQUINONE for synthesis is not on the REACH Annex XIV List National regulations Germany 25/05/2016 9/10

10 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Recommendations Danish Regulation Young people below the age of 18 years are not allowed to use the product Chemical safety assessment SECTION 16 Other information Full text of R-, H- and EUH-phrases Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 H301 Toxic if swallowed EUH029 Contact with water liberates toxic gas R25 Toxic if swallowed R29 Contact with water liberates toxic gas T Toxic This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 25/05/ /10