SELIWANOFF S REAGENT MSDS. CAS No: MSDS MATERIAL SAFETY DATA SHEET (MSDS)

Transcription

1 MSDS CAS No MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Mixture Product code Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture Laboratory chemicals, Manufacture of substances Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number (900am pm) SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Directive 67/548/EEC or 1999/45/EC Xi; R36/37/38 Full text of R-phrases see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Directive 67/548/EEC or 1999/45/EC Hazard symbols Xi - Irritant 09/04/2015 1/10

2 R-phrases S-phrases R36/37/38 - Irritating to eyes, respiratory system and skin S24 - Avoid contact with skin S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S35 - This material and its container must be disposed of in a safe way S36/37 - Wear suitable protective clothing and gloves S51 - Use only in well-ventilated areas S59 - Refer to manufacturer/supplier for information on recovery/recycling 2.3. Other hazards SECTION 3 Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC Water (CAS No) (EC no) Hydrochloric acid (CAS No) (EC no) (EC index no) X Resorcinol (CAS No) (EC no) (EC index no) Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Not classified C; R34 Xi; R Xn; R22 Xi; R36/38 N; R50 Skin Corr. 1B, H314 STOT SE 3, H335 Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 Skin Irrit. 2, H315 Aquatic Acute 1, H400 Full text of R- and H-phrases see section 16 SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. 09/04/2015 2/10

3 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries Causes severe skin burns and eye damage. Symptoms/injuries after inhalation May cause respiratory irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Protection during firefighting Do not attempt to take action without suitable protective equipment. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures Evacuate unnecessary personnel. Use personal protective equipment as required. Stop release Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Clear up rapidly by scoop or vacuum Reference to other sections SECTION 7 Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures Do not breathe dust/fume/gas/mist/vapours/spray. Wash... thoroughly after handling. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Technical measures Storage conditions 7.3. Specific end use(s) SECTION 8 Exposure controls/personal protection 8.1. Control parameters Comply with applicable regulations. Store in original container. Keep container tightly closed. Store in a dry place. Protect from moisture. 09/04/2015 3/10

4 8.2. Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection protective gloves Chemical goggles or face shield Wear suitable protective clothing Wear respiratory protection SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Clear Colorless. No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits No data available Water Soluble in water No data available No data available No data available No data available No data available No data available 9.2. Other information 09/04/2015 4/10

5 SECTION 10 Stability and reactivity Reactivity Thermal decomposition generates Corrosive vapours Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Direct sunlight. Open flame. Overheating Incompatible materials Hazardous decomposition products Thermal decomposition generates Corrosive vapours. SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Not classified Irritation Corrosivity Sensitisation Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction Irritating to eyes, respiratory system and skin. Not classified Not classified Not classified Not classified Not classified Not classified SECTION 12 Ecological information Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil 09/04/2015 5/10

6 12.5. Results of PBT and vpvb assessment Other adverse effects SECTION 13 Disposal considerations Waste treatment methods Product/Packaging disposal recommendations Dispose of contents/container to... SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 1789 UN-No. (IMDG) 1789 UN-No.(IATA) 1789 UN-No.(ADN) 1789 UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) Transport document description (ADN) Transport document description (RID) HYDROCHLORIC ACID HYDROCHLORIC ACID HYDROCHLORIC ACID HYDROCHLORIC ACID HYDROCHLORIC ACID UN 1789 HYDROCHLORIC ACID, 8, II, (E) UN 1789 HYDROCHLORIC ACID, 8, II UN 1789 HYDROCHLORIC ACID, 8, II UN 1789 HYDROCHLORIC ACID, 8, II UN 1789 HYDROCHLORIC ACID, 8, II Transport hazard class(es) ADR Transport hazard class(es) (ADR) 8 Danger labels (ADR) 8 IMDG Transport hazard class(es) (IMDG) 8 Danger labels (IMDG) /04/2015 6/10

7 IATA Transport hazard class(es) (IATA) 8 Hazard labels (IATA) 8 ADN Transport hazard class(es) (ADN) 8 Danger labels (ADN) 8 RID Transport hazard class(es) (RID) 8 Danger labels (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information II II II II II No No No supplementary information available Special precautions for user - Overland transport Classification code (ADR) C1 Special provision (ADR) 520 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) 1L E2 P001, IBC02 MP15 T8 TP2 09/04/2015 7/10

8 Tank code (ADR) Vehicle for tank carriage L4BN AT Transport category (ADR) 2 Hazard identification number (Kemler No.) 80 Orange plates Tunnel restriction code (ADR) EAC code E 2R - Transport by sea Limited quantities (IMDG) Excepted quantities (IMDG) Packing instructions (IMDG) IBC packing instructions (IMDG) IBC special provisions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) 1 L E2 P001 IBC02 B20 T8 TP2 F-A S-B C MFAG-No Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) E2 Y L PCA packing instructions (IATA) 851 PCA max net quantity (IATA) 1L CAO packing instructions (IATA) 855 CAO max net quantity (IATA) Special provision (IATA) ERG code (IATA) - Inland waterway transport Classification code (ADN) 30L A3 8L C1 Special provisions (ADN) 520 Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) Equipment required (ADN) 1 L E2 T Number of blue cones/lights (ADN) 0 - Rail transport Classification code (RID) PP, EP C1 Special provision (RID) 520 Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) 1L E2 P001, IBC02 MP15 T8 TP2 09/04/2015 8/10

9 Tank codes for RID tanks (RID) Transport category (RID) 2 Colis express (express parcels) (RID) L4BN CE6 Hazard identification number (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions Contains no REACH candidate substance Contains no REACH Annex XIV substances National regulations Germany AwSV/VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Water hazard class (WGK) 3, strongly hazardous to water (Classification according to AwSV, Annex 1) Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Recommendations Danish Regulation Young people below the age of 18 years are not allowed to use the product Chemical safety assessment SECTION 16 Other information Full text of R-, H- and EUH-phrases Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Corr. 1B Skin corrosion/irritation, Category 1B Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H302 Harmful if swallowed H314 Causes severe skin burns and eye damage 09/04/2015 9/10

10 H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation H400 Very toxic to aquatic life R22 Harmful if swallowed R34 Causes burns R36/37/38 Irritating to eyes, respiratory system and skin R36/38 Irritating to eyes and skin R37 Irritating to respiratory system R50 Very toxic to aquatic organisms C Corrosive N Dangerous for the environment Xi Irritant Xn Harmful This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 09/04/ /10