MATERIAL SAFETY DATA SHEET (MSDS)

Transcription

1 MSDS CAS No MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Mixture Product code Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture Industrial. For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number (900am pm) SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance SDS EU 2015 According to Annex II of Regulation (EC) No. 453/2010 (REACH Annex II) Flammable liquids, Category 3 Serious eye damage/eye irritation, Category 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 H226 H319 H411 Full text of classification categories and H statements see section 16 Adverse physicochemical, human health and environmental effects Version 1 12/09/2016 1/10

2 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) Warning GHS02 GHS07 GHS09 H226 - Flammable liquid and vapour H319 - Causes serious eye irritation H411 - Toxic to aquatic life with long lasting effects P273 - Avoid release to the environment P281 - Use personal protective equipment as required P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing 2.3. Other hazards SECTION 3 Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Water (CAS No) (EC no) Not classified Ethanol (CAS No) (EC no) (EC index no) CRYSTAL VIOLET AR C.I.No substance listed as REACH Candidate ([4-[4,4'- bis(dimethylamino) benzhydrylidene]cyclohexa- 2,5-dien-1-ylidene]dimethylammonium chloride (C.I. Basic Violet 3) [with 0.1% of Michler's ketone (EC No ) or Michler's base (EC No )]) Flam. Liq. 3, H226 Skin Corr. 1A, H314 (CAS No) Eye Dam. 1, H318 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 STOT SE 3, H335 Aquatic Chronic 4, H413 AMMONIUM OXALATE AR 99.5% (CAS No) Not classified Full text of H-phrases see section 16 Version 1 12/09/2016 2/10

3 SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Remove victim to fresh air and keep at rest in a position comfortable for breathing. Wash with plenty of soap and water Most important symptoms and effects, both acute and delayed Symptoms/injuries after eye contact Rinse cautiously with water for several minutes. Get medical advice/attention. Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. May cause eye irritation Indication of any immediate medical attention and special treatment needed SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Carbon dioxide. Dry powder. Foam. Water spray. Do not use a heavy water stream Special hazards arising from the substance or mixture Fire hazard Flammable liquid and vapour Advice for firefighters Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Evacuate unnecessary personnel. Use personal protective equipment as required Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Collect spillage. On land, sweep or shovel into suitable containers Reference to other sections SECTION 7 Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures Do not breathe vapours. Avoid contact with skin and eyes. Keep away from sources of ignition - No smoking. Wear personal protective equipment. Do not eat, drink or smoke when using this product Conditions for safe storage, including any incompatibilities Storage conditions Incompatible materials 7.3. Specific end use(s) Store in a well-ventilated place. Keep container tightly closed. Keep in fireproof place. Heat sources. Version 1 12/09/2016 3/10

4 SECTION 8 Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection Protective gloves Chemical goggles or face shield Wear suitable protective clothing Wear respiratory protection SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Violet solution. odourless. Flash point 37 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Water Miscible with water Version 1 12/09/2016 4/10

5 Explosive limits 9.2. Other information SECTION 10 Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Open flame. Heat. Sparks Incompatible materials Oxidizing agent. acids Hazardous decomposition products SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Causes serious eye irritation. Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard SECTION 12 Ecological information Toxicity Version 1 12/09/2016 5/10

6 12.2. Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Component CRYSTAL VIOLET AR C.I.No ( ) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII Other adverse effects SECTION 13 Disposal considerations Waste treatment methods Waste disposal recommendations Dispose of contents/container to.. SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 1993 UN-No. (IMDG) 1993 UN-No.(IATA) 1993 UN-No.(ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) FLAMMABLE LIQUID, N.O.S. FLAMMABLE LIQUID, N.O.S. FLAMMABLE LIQUID, N.O.S. UN 1993 FLAMMABLE LIQUID, N.O.S., 3, III, (D/E), ENVIRONMENTALLY HAZARDOUS UN 1993 FLAMMABLE LIQUID, N.O.S., 3, III, MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS UN 1993 FLAMMABLE LIQUID, N.O.S., 3, III, ENVIRONMENTALLY HAZARDOUS Transport hazard class(es) ADR Transport hazard class(es) (ADR) 3 Version 1 12/09/2016 6/10

7 Danger labels (ADR) 3 IMDG Transport hazard class(es) (IMDG) 3 Danger labels (IMDG) 3 IATA Transport hazard class(es) (IATA) 3 Hazard labels (IATA) 3 ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information III III III Yes Yes No supplementary information available Version 1 12/09/2016 7/10

8 14.6. Special precautions for user - Overland transport Classification code (ADR) Special provision (ADR) Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage F1 274, 601, 640E 5L E1 P001, IBC03, LP01, R001 MP19 T4 TP1, TP29 LGBF FL Transport category (ADR) 3 Special provisions for carriage - Packages (ADR) Special provisions for carriage - Operation (ADR) V12 S2 Hazard identification number (Kemler No.) 30 Orange plates Tunnel restriction code (ADR) EAC code D/E 3YE - Transport by sea MFAG-No 127;128 - Air transport No data available - Inland waterway transport No data available - Rail transport No data available Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions Contains substance on the candidate list in concentration 0.1% or with a lower specific limit [4-[4,4'-bis(dimethylamino) benzhydrylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium chloride (C.I. Basic Violet 3) [with 0.1% of Michler's ketone (EC No ) or Michler's base (EC No )] (CAS ) Contains no REACH Annex XIV substances. Version 1 12/09/2016 8/10

9 National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Water hazard class (WGK) 3, strongly hazardous to water (Classification according to VwVwS, Annex 4) Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Class for fire hazard Store unit Classification remarks Recommendations Danish Regulation Class II-1 5 liter R10 <H226;H319;H411>; Emergency management guidelines for the storage of flammable liquids must be followed Young people below the age of 18 years are not allowed to use the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal Chemical safety assessment SECTION 16 Other information Full text of H- and EUH-phrases Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 Aquatic Chronic 4 Hazardous to the aquatic environment Chronic Hazard, Category 4 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H226 Flammable liquid and vapour H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H319 Causes serious eye irritation H335 May cause respiratory irritation H411 Toxic to aquatic life with long lasting effects H413 May cause long lasting harmful effects to aquatic life This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product Version 1 12/09/2016 9/10

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