MATERIAL SAFETY DATA SHEET (MSDS)

Transcription

1 THYMOLPHTHALEIN INDICATOR SOLUTION MSDS CAS No: MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture : EC no : CAS No : Product code : 6309B Formula : C28H30O4 Synonyms : 5,5 -Diisopropyl-2,2 -dimethylphenolphthalein 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : Industrial;For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number : (9:00am - 6:00 pm) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Annex II of Regulation (EC) No. 453/2010 (REACH Annex II) Flammable liquids, Category 3 H226 Full text of classification categories and H statements : see section 16 Adverse physicochemical, human health and environmental effects 28/12/2017 1/9

2 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS02 : Warning : H226 - Flammable liquid and vapour : P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking P233 - Keep container tightly closed P280 - Wear eye protection, face protection, protective clothing, protective gloves P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P370+P378 - In case of fire: Use alcohol resistant foam, extinguishing powder, sand, foam for extinction P403+P235 - Store in a well-ventilated place. Keep cool 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Ethanol (CAS No) (EC no) (EC index no) Water (CAS No) (EC no) Flam. Liq. 3, H226 Skin Corr. 1A, H Not classified THYMOLPHTHALEIN INDICATOR AR (CAS No) Not classified Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice. 28/12/2017 2/9

3 First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove/Take off immediately all contaminated clothing. Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. : Rinse mouth out with water. Do not induce vomiting/risk of damage to lungs exceeds poisoning risk. If you feel unwell, seek medical advice Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2) Special hazards arising from the substance or mixture Fire hazard : Flammable liquid and vapour Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Use personal protective equipment as required. : Ventilate area Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage : Collect spillage. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. On land, sweep or shovel into suitable containers Precautions for safe handling Precautions for safe handling Hygiene measures : Avoid contact with skin and eyes. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Conditions for safe storage, including any incompatibilities Storage conditions : Keep container tightly closed. Store in a well-ventilated place. Keep cool Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 28/12/2017 3/9

4 8.2. Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection : protective gloves : Chemical goggles or safety glasses : Wear suitable protective clothing : Wear respiratory protection SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point : Clear Colorless. : mild characteristic odor. Flash point : 21 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : 0.79 g/cm³ : Water: Completely Soluble 28/12/2017 4/9

5 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Flammable liquid and vapour Possibility of hazardous reactions Conditions to avoid Direct sunlight. Overheating. Open flame. Heat Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard SECTION 12: Ecological information Toxicity 28/12/2017 5/9

6 12.2. Persistence and degradability Bioaccumulative potential THYMOLPHTHALEIN INDICATOR AR ( ) Log Pow Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) : 1993 UN-No. (IMDG) : 1993 UN-No.(IATA) : 1993 UN-No.(ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) : FLAMMABLE LIQUID, N.O.S. : FLAMMABLE LIQUID, N.O.S. : FLAMMABLE LIQUID, N.O.S. : UN 1993 FLAMMABLE LIQUID, N.O.S., 3, III, (D/E) : UN 1993 FLAMMABLE LIQUID, N.O.S., 3, III : UN 1993 FLAMMABLE LIQUID, N.O.S., 3, III Transport hazard class(es) ADR Transport hazard class(es) (ADR) : 3 Danger labels (ADR) : 3 : 28/12/2017 6/9

7 IMDG Transport hazard class(es) (IMDG) : 3 Danger labels (IMDG) : 3 : IATA Transport hazard class(es) (IATA) : 3 Hazard labels (IATA) : 3 : ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : III : III : III : No : No : No supplementary information available Special precautions for user - Overland transport Classification code (ADR) Special provision (ADR) Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage : F1 : 274, 601, 640E : 5L : E1 : P001, IBC03, LP01, R001 : MP19 : T4 : TP1, TP29 : LGBF : FL Transport category (ADR) : /12/2017 7/9

8 Special provisions for carriage - Packages (ADR) Special provisions for carriage - Operation (ADR) : V12 : S2 Hazard identification number (Kemler No.) : 30 Orange plates : Tunnel restriction code (ADR) EAC code : D/E : 3YE - Transport by sea Special provision (IMDG) : 223, 274, 955 Limited quantities (IMDG) Excepted quantities (IMDG) Packing instructions (IMDG) IBC packing instructions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) : 5 L : E1 : P001, LP01 : IBC03 : T4 : TP1, TP29 : F-E : S-E : A : E1 : Y344 : 10L PCA packing instructions (IATA) : 355 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 366 CAO max net quantity (IATA) Special provision (IATA) ERG code (IATA) - Inland waterway transport Not regulated - Rail transport Not regulated : 220L : A3 : 3L Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions Contains no REACH candidate substance Contains no REACH Annex XIV substances. 28/12/2017 8/9

9 National regulations Germany 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Class for fire hazard : Class I-1 Store unit Classification remarks : 1 liter : F <Flam. Liq. 3>; Emergency management guidelines for the storage of flammable liquids must be followed Chemical safety assessment SECTION 16: Other information Full text of H- and EUH-phrases: Flam. Liq. 3 Flammable liquids, Category 3 Skin Corr. 1A Skin corrosion/irritation, Category 1A H226 Flammable liquid and vapour H314 Causes severe skin burns and eye damage This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 28/12/2017 9/9