1-BROMOHEPTANE FOR SYNTHESIS MSDS. CAS-No.: MSDS MATERIAL SAFETY DATA SHEET (MSDS)

Transcription

1 1-BROMOHEPTANE FOR SYNTHESIS MSDS CAS-No MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Substance EC-No CAS-No Product code Chemical structure 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture Laboratory chemicals, Manufacture of substances Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number (900am pm) SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Flammable liquids, Category 3 H226 Full text of H statements see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] F Full text of R-phrases see section /05/2016 1/10

2 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) Signal word (CLP) Hazard statements (CLP) GHS02 Warning H226 - Flammable liquid and vapour Other hazards SECTION 3 Composition/information on ingredients 3.1. Substances Name 1-BROMOHEPTANE For Synthesis CAS-No EC-No Full text of R- and H-statements see section Mixtures Not applicable SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Wash with plenty of water/. Get immediate medical advice/attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. Rinse mouth. Do not induce vomiting Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Carbon dioxide. Dry powder. Foam. Water spray. 12/05/2016 2/10

3 Unsuitable extinguishing media Do not use a heavy water stream Special hazards arising from the substance or mixture Fire hazard Flammable liquid and vapour Advice for firefighters Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures Remove ignition sources. Use special care to avoid static electric charges For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures Evacuate unnecessary personnel. Use personal protective equipment as required. Ventilate area Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections SECTION 7 Handling and storage On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible Precautions for safe handling Additional hazards when processed Precautions for safe handling Hygiene measures Handle empty containers with care because residual vapours are flammable. Avoid contact with skin and eyes. Do not breathe vapours. Keep away from sources of ignition - No smoking. Use only outdoors or in a well-ventilated area. Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Conditions for safe storage, including any incompatibilities Storage conditions Keep in fireproof place. Keep container tightly closed. Incompatible materials Heat sources Specific end use(s) SECTION 8 Exposure controls/personal protection 8.1. Control parameters 12/05/2016 3/10

4 8.2. Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection Protective gloves Chemical goggles or safety glasses Wear suitable protective clothing [In case of inadequate ventilation] wear respiratory protection. SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Clear colourless. Melting point -58 C Freezing point Boiling point 180 Flash point 60 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density 1.14 g/cm³ at 25 C Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10 Stability and reactivity Reactivity 12/05/2016 4/10

5 10.2. Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Heat. Sparks. Open flame Incompatible materials Strong bases. Oxidizing agent Hazardous decomposition products SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard SECTION 12 Ecological information Toxicity Persistence and degradability Bioaccumulative potential 12/05/2016 5/10

6 12.4. Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13 Disposal considerations Waste treatment methods SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 1993 UN-No. (IMDG) 1993 UN-No. (IATA) 1993 UN-No. (ADN) 1993 UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) Transport document description (ADN) Transport document description (RID) FLAMMABLE LIQUID, N.O.S. FLAMMABLE LIQUID, N.O.S. Flammable liquid, n.o.s. FLAMMABLE LIQUID, N.O.S. FLAMMABLE LIQUID, N.O.S. UN 1993 FLAMMABLE LIQUID, N.O.S., 3, III, (D/E) UN 1993 FLAMMABLE LIQUID, N.O.S., 3, III UN 1993 Flammable liquid, n.o.s., 3, III UN 1993 FLAMMABLE LIQUID, N.O.S., 3, III UN 1993 FLAMMABLE LIQUID, N.O.S., 3, III Transport hazard class(es) ADR Transport hazard class(es) (ADR) 3 Danger labels (ADR) 3 IMDG Transport hazard class(es) (IMDG) 3 Danger labels (IMDG) /05/2016 6/10

7 IATA Transport hazard class(es) (IATA) 3 Hazard labels (IATA) 3 ADN Transport hazard class(es) (ADN) 3 Danger labels (ADN) 3 RID Transport hazard class(es) (RID) 3 Danger labels (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information III III III III III No No No supplementary information available Special precautions for user - Overland transport Classification code (ADR) F1 Special provisions (ADR) 274, 601 Limited quantities (ADR) 5l Excepted quantities (ADR) E1 Packing instructions (ADR) P001, IBC03, LP01, R001 Mixed packing provisions (ADR) MP /05/2016 7/10

8 Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage T4 TP1, TP29 LGBF FL Transport category (ADR) 3 Special provisions for carriage - Packages (ADR) Special provisions for carriage - Operation (ADR) V12 S2 Hazard identification number (Kemler No.) 30 Orange plates Tunnel restriction code (ADR) EAC code D/E 3YE - Transport by sea Special provisions (IMDG) 223, 274, 955 Limited quantities (IMDG) Excepted quantities (IMDG) Packing instructions (IMDG) IBC packing instructions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) 5 L E1 LP01, P001 IBC03 T4 TP1, TP29 F-E S-E A MFAG-No 127;128 - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) E1 Y344 10L PCA packing instructions (IATA) 355 PCA max net quantity (IATA) 60L CAO packing instructions (IATA) 366 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) - Inland waterway transport Classification code (ADN) 220L A3 3L F1 Special provisions (ADN) 274, 601 Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) Equipment required (ADN) Ventilation (ADN) 5 L E1 T Number of blue cones/lights (ADN) 0 PP, EX, A VE01 - Rail transport Classification code (RID) F1 12/05/2016 8/10

9 Special provisions (RID) 274, 601 Excepted quantities (RID) Packing instructions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) E1 P001, IBC03, LP01, R001 MP19 T4 Transport category (RID) 3 Special provisions for carriage Packages (RID) Colis express (express parcels) (RID) TP1, TP29 LGBF W12 CE4 Hazard identification number (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions 1-BROMOHEPTANE For Synthesis is not on the REACH Candidate List 1-BROMOHEPTANE For Synthesis is not on the REACH Annex XIV List National regulations Germany 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling The substance is not listed The substance is not listed The substance is not listed The substance is not listed The substance is not listed Denmark Class for fire hazard Store unit Classification remarks Class III-1 50 liter Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed 12/05/2016 9/10

10 15.2. Chemical safety assessment SECTION 16 Other information Full text of R-, H- and EUH-statements Flam. Liq. 3 Flammable liquids, Category 3 H226 Flammable liquid and vapour. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 12/05/ /10