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1 HYDROCHLORIC ACID 1N (1M) SOLUTION GMP MANUFACTURED MSDS CAS-No MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Mixture CAS-No Product code G0058 Formula HCl 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Industrial For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number (900am pm) SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances SDS EU 2015 According to Regulation (EU) 2015/830 (REACH Annex II) Skin corrosion/irritation, Category 2 Serious eye damage/eye irritation, Category 2 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H315 H319 H335 Full text of H statements see section /09/2017 1/10
2 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS05 Danger H315 - Causes skin irritation. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. P261 - Avoid breathing gas, dust, fume, vapours, spray. P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Other hazards SECTION 3 Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Water (CAS-No.) (EC-No.) Not classified Hydrochloric acid (CAS-No.) (EC-No.) (EC Index-No.) X Skin Corr. 1B, H314 STOT SE 3, H335 Full text of H-statements see section 16 SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. Get medical advice/attention. 26/09/2017 2/10
3 First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Gently wash with plenty of soap and water. Wash contaminated clothing before reuse. Get medical advice/attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention. Rinse mouth out with water. Get medical advice/attention. Do not induce vomiting Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation May cause respiratory irritation. Symptoms/effects after skin contact Causes skin irritation. Symptoms/effects after eye contact Causes serious eye irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Water spray. Foam. Dry powder. Carbon dioxide. Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures Evacuate unnecessary personnel. Use personal protective equipment as required. Ventilate area Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections SECTION 7 Handling and storage Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible Precautions for safe handling Precautions for safe handling Hygiene measures Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Conditions for safe storage, including any incompatibilities Storage conditions Keep container tightly closed. Store in a well-ventilated place. Keep cool Specific end use(s) 26/09/2017 3/10
4 SECTION 8 Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection Protective gloves Chemical goggles or safety glasses Wear suitable protective clothing [In case of inadequate ventilation] wear respiratory protection. SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Molecular mass Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties 36.5 g/mol Clear Colorless. 26/09/2017 4/10
5 Oxidising properties Explosive limits 9.2. Other information SECTION 10 Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Hazardous decomposition products SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Causes skin irritation. Causes serious eye irritation. Reproductive toxicity STOT-single exposure May cause respiratory irritation. STOT-repeated exposure Aspiration hazard SECTION 12 Ecological information Toxicity 26/09/2017 5/10
6 12.2. Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13 Disposal considerations Waste treatment methods SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 1789 UN-No. (IMDG) 1789 UN-No. (IATA) 1789 UN-No. (ADN) 1789 UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) Transport document description (ADN) Transport document description (RID) HYDROCHLORIC ACID HYDROCHLORIC ACID Hydrochloric acid HYDROCHLORIC ACID HYDROCHLORIC ACID UN 1789 HYDROCHLORIC ACID, 8, III, (E) UN 1789 HYDROCHLORIC ACID, 8, III UN 1789 Hydrochloric acid, 8, III UN 1789 HYDROCHLORIC ACID, 8, III UN 1789 HYDROCHLORIC ACID, 8, III Transport hazard class(es) ADR Transport hazard class(es) (ADR) 8 Danger labels (ADR) /09/2017 6/10
7 IMDG Transport hazard class(es) (IMDG) 8 Danger labels (IMDG) 8 IATA Transport hazard class(es) (IATA) 8 Hazard labels (IATA) 8 ADN Transport hazard class(es) (ADN) 8 Danger labels (ADN) 8 RID Transport hazard class(es) (RID) 8 Danger labels (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information III III III III III No No No supplementary information available 26/09/2017 7/10
8 14.6. Special precautions for user - Overland transport Classification code (ADR) C1 Special provisions (ADR) 520 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage 5l E1 P001, IBC03, LP01, R001 MP19 T4 TP1 L4BN AT Transport category (ADR) 3 Special provisions for carriage - Packages (ADR) V12 Hazard identification number (Kemler No.) 80 Orange plates Tunnel restriction code (ADR) EAC code E 2R - Transport by sea Special provisions (IMDG) 223 Packing instructions (IMDG) IBC packing instructions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) Properties and observations (IMDG) - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) P001, LP01 IBC03 T4 TP1 F-A S-B C Colourless liquid.an aqueous solution of the gas hydrogen chloride. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. E1 Y841 1L PCA packing instructions (IATA) 852 PCA max net quantity (IATA) 5L CAO packing instructions (IATA) 856 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) - Inland waterway transport Classification code (ADN) 60L A3 8L C1 Special provisions (ADN) 520 Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) 5 L E1 T 26/09/2017 8/10
9 Equipment required (ADN) Number of blue cones/lights (ADN) 0 - Rail transport Classification code (RID) PP, EP C1 Special provisions (RID) 520 Excepted quantities (RID) Packing instructions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) E1 P001, IBC03, LP01, R001 MP19 T4 TP1 Transport category (RID) 3 Special provisions for carriage Packages (RID) Colis express (express parcels) (RID) L4BN W12 CE8 Hazard identification number (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany Reference to AwSV 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV, Annex 1) Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling None of the components are listed None of the components are listed None of the components are listed None of the components are listed None of the components are listed 26/09/2017 9/10
10 Denmark Recommendations Danish Regulation Young people below the age of 18 years are not allowed to use the product Chemical safety assessment SECTION 16 Other information Full text of H- and EUH-statements Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Corr. 1B Skin corrosion/irritation, Category 1B Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 26/09/ /10
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