CYANOGEN BROMIDE FOR SYNTHESIS MSDS. CAS No: MSDS MATERIAL SAFETY DATA SHEET (MSDS)

Transcription

1 CYANOGEN BROMIDE FOR SYNTHESIS MSDS CAS No: MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance Trade name : EC no : CAS No : Product code : Formula : CNBr Synonyms : Bromine cyanide 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : Laboratory chemicals, Manufacture of substances Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number : (9:00am - 6:00 pm) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute toxicity (oral), Category 1 Acute toxicity (dermal), Category 1 Acute toxicity (inhal.), Category 2 Skin corrosion/irritation, Category 1B Hazardous to the aquatic environment Chronic Hazard, Category 1 H300 H310 H330 H314 H410 Full text of classification categories and H statements : see section 16 Version: 1 25/05/2016 1/10

2 Classification according to Directive 67/548/EEC or 1999/45/EC T+; R26/27/28 C; R34 N; R50/53 Full text of R-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) : Danger GHS05 GHS06 GHS09 : H300+H310+H330 - Fatal if swallowed, in contact with skin or if inhaled H314 - Causes severe skin burns and eye damage H410 - Very toxic to aquatic life with long lasting effects : P260 - Do not breathe vapours, spray, dust, fume, gas, mist P264 - Wash... thoroughly after handling P273 - Avoid release to the environment P280 - Wear protective gloves, protective clothing, eye protection, face protection P284 - [In case of inadequate ventilation] wear respiratory protection P302+P352 - IF ON SKIN: Wash with plenty of water/ 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Name : CYANOGEN BROMIDE FOR SYNTHESIS CAS No : EC no : Full text of R- and H-phrases: see section Mixture Not applicable Version: 1 25/05/2016 2/10

3 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries Symptoms/injuries after skin contact Symptoms/injuries after ingestion : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. : Immediately call a POISON CENTER or doctor/physician. Gently wash with plenty of soap and water. Remove/Take off immediately all contaminated clothing. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. : Rinse mouth. Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. : Causes severe skin burns and eye damage. : Fatal in contact with skin. : Fatal if swallowed Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray. : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Use personal protective equipment as required. : Ventilate area Environmental precautions Very toxic to aquatic life with long lasting effects Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. On land, sweep or shovel into suitable containers Precautions for safe handling Precautions for safe handling : Do not get in eyes, on skin, or on clothing. Avoid contact with skin and eyes. Do not breathe vapours. Version: 1 25/05/2016 3/10

4 Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep container tightly closed Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection : Protective gloves : Chemical goggles or face shield : Wear suitable protective clothing : Wear respiratory protection SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) : Colorless to white. : penetrating odor. Melting point : C Freezing point Boiling point : C Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure : 133 hpa at 20 C Relative vapour density at 20 C : 3.62 Relative density Version: 1 25/05/2016 4/10

5 Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : g/cm³ : Water: Soluble in water 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Overheating. Open flame. Sparks. Heat Incompatible materials Hazardous decomposition products Thermal decomposition generates : Corrosive vapours. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Oral: Fatal if swallowed. Dermal: Fatal in contact with skin. Inhalation: Fatal if inhaled. Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity : Causes severe skin burns and eye damage. : Serious eye damage, category 1, implicit Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Version: 1 25/05/2016 5/10

6 Aspiration hazard Potential adverse human health effects and symptoms : Fatal if swallowed. Fatal in contact with skin. SECTION 12: Ecological information Toxicity Ecology - water : Very toxic to aquatic life with long lasting effects Persistence and degradability ( ) Persistence and degradability May cause long-term adverse effects in the environment Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations Ecology - waste materials : Dispose of contents/container to... : Hazardous waste due to toxicity. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) : 1889 UN-No. (IMDG) : 1889 UN-No.(IATA) : 1889 UN-No.(ADN) : 1889 UN-No. (RID) : UN proper shipping name Proper Shipping Name (ADR) : CYANOGEN BROMIDE Version: 1 25/05/2016 6/10

7 Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) Transport document description (ADN) Transport document description (RID) : CYANOGEN BROMIDE : CYANOGEN BROMIDE : CYANOGEN BROMIDE : CYANOGEN BROMIDE : UN 1889 CYANOGEN BROMIDE, 6.1 (8), I, (C/E), ENVIRONMENTALLY HAZARDOUS : UN 1889 CYANOGEN BROMIDE, 6.1 (8), I, MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS : UN 1889 CYANOGEN BROMIDE, 6.1, I, ENVIRONMENTALLY HAZARDOUS : UN 1889 CYANOGEN BROMIDE, 6.1 (8), I, ENVIRONMENTALLY HAZARDOUS : UN 1889 CYANOGEN BROMIDE, 6.1 (8), I, ENVIRONMENTALLY HAZARDOUS Transport hazard class(es) ADR Transport hazard class(es) (ADR) : 6.1 (8) Danger labels (ADR) : 6.1, 8 : IMDG Transport hazard class(es) (IMDG) : 6.1 (8) Danger labels (IMDG) : 6.1, 8 : IATA Transport hazard class(es) (IATA) : 6.1 (8) Hazard labels (IATA) : 6.1, 8 : ADN Transport hazard class(es) (ADN) : 6.1 (8) Danger labels (ADN) : 6.1, 8 : RID Transport hazard class(es) (RID) : 6.1 (8) Danger labels (RID) : 6.1, 8 Version: 1 25/05/2016 7/10

8 : Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : I : I : I : I : I : Yes : Yes : No supplementary information available Special precautions for user - Overland transport Classification code (ADR) : TC2 Limited quantities (ADR) : 0 Excepted quantities (ADR) Packing instructions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Tank special provisions (ADR) Vehicle for tank carriage : E0 : P002 : MP18 : T6 : TP33 : S10AH, L10CH : TU14, TU15, TE19, TE21 : AT Transport category (ADR) : 1 Special provisions for carriage - Loading, unloading and handling (ADR) Special provisions for carriage - Operation (ADR) : CV1, CV13, CV28 : S9, S14 Hazard identification number (Kemler No.) : 668 Orange plates : Tunnel restriction code (ADR) EAC code APP code : C/E : 2XE : B - Transport by sea Limited quantities (IMDG) : 0 Excepted quantities (IMDG) : E0 Packing instructions (IMDG) : P002 Packing provisions (IMDG) : PP31 Tank instructions (IMDG) : T6 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Version: 1 25/05/2016 8/10

9 Stowage category (IMDG) Stowage and handling (IMDG) Segregation (IMDG) : D : SW2 : SG35 MFAG-No : Air transport PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) PCA packing instructions (IATA) PCA max net quantity (IATA) CAO packing instructions (IATA) CAO max net quantity (IATA) Special provision (IATA) ERG code (IATA) : A2 : 6C - Inland waterway transport Classification code (ADN) : TC2 Special provisions (ADN) : 802 Limited quantities (ADN) : 0 Excepted quantities (ADN) Equipment required (ADN) : E0 Number of blue cones/lights (ADN) : 2 - Rail transport Classification code (RID) : PP, EP : TC2 Limited quantities (RID) : 0 Excepted quantities (RID) Packing instructions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) Special provisions for RID tanks (RID) : E0 : P002 : MP18 : T6 Transport category (RID) : 1 Special provisions for carriage Loading and unloading (RID) : TP33 Hazard identification number (RID) : 668 : S10AH, L10CH : TU14, TU15, TU38, TE21, TE22 : CW13, CW28, CW Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions is not on the REACH Candidate List is not on the REACH Annex XIV List Version: 1 25/05/2016 9/10

10 National regulations Germany AwSV/VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to VwVwS, Annex 2; WGK No 947) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product Chemical safety assessment SECTION 16: Other information Full text of R-, H- and EUH-phrases: Acute Tox. 1 (Dermal) Acute toxicity (dermal), Category 1 Acute Tox. 1 (Oral) Acute toxicity (oral), Category 1 Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Skin Corr. 1B Skin corrosion/irritation, Category 1B H300 Fatal if swallowed H310 Fatal in contact with skin H314 Causes severe skin burns and eye damage H330 Fatal if inhaled H410 Very toxic to aquatic life with long lasting effects R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed R34 Causes burns R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment C Corrosive N Dangerous for the environment T+ Very toxic This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product Version: 1 25/05/ /10