MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET Product Identity: CARQUEST, Engine Decarbonizer Page: 1 of 6 Material Safety Data Sheet This MSDS complies with 29 CFR 1910, 1900 (Hazard Communication Standard). IMPORTANT: Read this MSDS before handling and disposing of this product. Pass this information on to employees, customers, and users of this product. SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Identity: CARQUEST Engine Decarbonizer CARQUEST, Inc Hargrove Road Effective: 02/18/05 Raleigh, NC Printed: 10/20/05 USA Tel: (919) hour Emergency Phone, Chemtrec: , or international SECTION 2. INGREDIENT & REGULATORY INFORMATION All components of this product are on the TSCA List. SARA Title III Section 313 Supplier Notification. This product contains the indicated <*> toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning & Community Right-To- Know Act of 1986 & of 40 CFR 372. This information must be included in all MSDS's that are copied and distributed for this material. SARA TITLE III INGREDIENTS CAS# Wt.%(Reg.Section) RQ(lbs.) Light Aromatic Solvent Naphtha * Not appl.(311,312) None *1,2,4-Trimethylbenzene (311,312,313,RCRA) None *Ethylene Glycol Monobutyl Ether (313) None Morpholine Not appl.(311,312) None SARA SECTION 311/312 HAZARDS: Acute Health, Chronic Health, Fire. MATERIAL CAS# TWA + (OSHA) TLV (ACGIH) Light Aromatic Solvent Naphtha * PPM 5 mg/m 3 1,2,4-Trimethylbenzene PPM 25 PPM Ethylene Glycol Monobutyl Ether PPM 25 PPM Morpholine PPM 20 PPM Specific chemical identity withheld as N/A 50 PPM 50 PPM trade secret Product Identity: CARQUEST Engine Decarbonizer D-1

2 Page: 2 of 6 MATERIAL CAS# CEILING STEL(OSHA/ACGIH) N/A Not known Not known MATERIAL CAS# Lowest known lethal dose data Lowest known LD50 (vapors) Ethylene Glycol Monobutyl Ether mg/kg (rabbits) Lowest known LC50 (vapors) Ethylene Glycol Monobutyl Ether mg/kg (mice) Lowest known LD50 (skin) Ethylene Glycol Monobutyl Ether mg/kg (rabbits) Hazards; Health (NFPA): 2 Health(HMIS): 3 Flammability: 2 Reactivity: 0 Balance of ingredients: Non-Hazardous 9 Octadecanoic acid CAS#: SECTION 3. HAZARDOUS IDENTIFICATION Threshold limit value: Not applicable Contains: Petroleum Naphtha, Ethylene Glycol Monobutyl Ether, 1,2,4-Trimethylbenzene Warning! Flammable! Acute Hazards Eye & Skin Contact: Primary irritation to skin, defatting, dermatitis. Absorption through skin increase exposure. Primary irritation to eyes, redness, tearing, blurred vision. Liquid can cause eye burns. Wash thoroughly after handling. Inhalation: Anesthetic. Irritates respiratory tract. Acute overexposure can cause serious nervous system depression. Vapor harmful. Breathing vapor can cause irritation. Acute overexposure can cause damage to kidneys, blood, nerves, liver, and lungs. Swallowing: Harmful or fatal if swallowed. Swallowing can cause abdominal irritation, nausea, vomiting and diarrhea. Subchronic Hazards / Conditions Aggravated Subchronic hazards: Absorption through skin may be harmful. Chronic overexposure can cause damage to kidneys, blood, nerves, liver & lungs. Product Identity: CARQUEST Engine Decarbonizer D-2

3 Page: 3 of 6 Conditions aggravated: Persons with severe skin, liver, heart, lung or kidney problems should avoid use. Chronic hazards: This product has no carcinogens listed by IARC, NTP, NIOSH, OSHA, or ACGIH, as of this date, greater or equal to 0.1%. This product may contain less than 1 PPM of benzene. Not considered hazardous in such low concentrations. SECTION 4. FIRST AID MEASURES PROCEDURES Eye Contact: Immediately flush with plenty of water for 15 minutes & call a physician. Skin Contact: Immediately remove contaminated clothing. Wash skin thoroughly with soap and water. Wash contaminated clothing before reuse. (Discard contaminated shoes.) Inhalation: After high vapor exposure, remove to fresh air. If breathing is difficult, give, oxygen. If breathing has stopped give artificial respiration. Call a physician immediately! Swallowing: Call a physician immediately! Do not induce vomiting. Never give anything by mouth to an unconscious person. Have patient lie down and keep warm. Vomiting may lead to pneumonititis, which may be fatal. SECTION 5. FIRE FIGHTING MEASURES Lower flammable limit in air (% by vol.): 1.0 Flash point (test method): 112 F/ 44.4 C (TCC) (lowest component) Flammability classification: Class II Extinguishing media: NFPA Class B extinguishers (carbon dioxide or foam) for Class II liquid fires. Special fire fighting procedures: Water spray may be ineffective on fire but can protect fire-fighters and cool closed containers. Use fog nozzles if water is used. Do not enter confined fire-space without full bunker gear. (helmet with face shield, bunker coats, gloves & rubber boots). Use NIOSH approved positive-pressure self-contained breathing apparatus. Unusual explosion and fire procedures: Combustible! Keep container tightly closed. Isolate from oxidizers, heat, & open flame. Closed containers may explode if exposed to extreme heat. Applying to hot surfaces requires special precautions. Empty container very hazardous! Continue all label precautions! D-3

4 Product Identity: CARQUEST Engine Decarbonizer Page: 4 of 6 SECTION 6. ACCIDENTAL RELEASE MEASURES Spill or leak procedures: Stop spill at source. Dike area & contain. Clean up remainder with absorbent materials. Mop up and dispose of. Waste disposal method: Recycle or dispose of observing local, state & federal health, safety & pollution laws. If questions exist, contact the appropriate agencies. Other precautions: None. SECTION 7. HANDLING AND STORAGE Handling: Isolate from oxidizers, heat, and open flame. Use only with adequate ventilation. Avoid breathing of vapor or spray mist. Do not get in eyes, on skin or clothing. Wear OSHA standard goggles or face shield. Consult safety equipment supplier. Wear gloves, apron and footwear impervious to this material. Wash clothing before reuse. Avoid free fall of liquid. Ground containers when transferring. Do not flame cut, braze, or weld. Empty container very hazardous! Continue all label precautions! Storage: Store large amounts in structures made for OSHA Class II liquids. Keep container tightly closed and upright when not in use to prevent leakage. SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Exposure controls: None necessary. Ventilation: Local exhaust: Necessary Mechanical (general): Acceptable Special: None Other: None Personal protection: Wear OSHA standard goggles or face shield. Consult safety equipment supplier. Wear gloves, apron & footwear impervious to this material. Wash clothing before reuse. D-4

5 Product Identity: CARQUEST Engine Decarbonizer Page: 5 of 6 SECTION 9. PHYSICAL DATA Appearance: Light yellow/ green color Odor: Petroleum solvent odor Boiling Range: C/ F Specific gravity (water = 1): 0.93 Pounds/gallon (lbs./gal): 7.75 Ph: 8 to 9 VOC's (vapor pressure>0.44 lbs./in 2 ) (lbs./gal): Total volatile organic compounds (TVOC) (gr/lt): Vapor pressure (mm of HG)@20 C: 1.6 Vapor density (air = 1): 4.1 %Volatile by vol.: Flash point: 112 F(44.4 C) (lowest component) SECTION 10. REACTIVITY DATA Stability: Stable Conditions to avoid: Isolate from oxidizers, heat, and open flame. Material to avoid: Isolate from strong oxidizers such as permanganates, chromates and peroxides. Hazardous decomposition products: Carbon monoxide, carbon dioxide from burning. Hazardous polymerization: Will not occur. SECTION 11. Not available SECTION 12. Not available SECTION 13. DISPOSAL CONSIDERATIONS This product is considered a hazardous waste. May be incinerated or burned in a RCRA licensed facility. D-5

6 Product Identity: CARQUEST Engine Decarbonizer Page: 6 of 6 SECTION 14. TRANSPORTATION INFORMATION *Note the information below are just guidelines. It is the responsibility of the shipper to ensure that all the proper procedures are followed. When shipped by ground (U.S.A.), not regulated ref. CFR When shipped by ground (U.S.A.), in drums: not regulated When Shipped by air: (NOT APPLICABLE TO DRUMS) D.O.T. CFR 49 proper shipping name: Consumer commodity Hazardous Class: 9 UN Number: ID 8000 Packing Group: N/A Packing Instruction: 910 Transportation Details: Permitted in Passenger and Cargo Aircraft (in appropriate quantities), Non-Radioactive DRUMS: D.O.T. CFR 49 proper shipping name: Petroleum distillates, n.o.s. Hazardous Class: 3 UN Number: 1268 Packing Group: III Packing Instruction: 310 Transportation Details: Cargo Aircraft Only, Non-Radioactive SECTION 15. REGULATORY INFORMATION California proposition 65: This product contains no known chemical known to the State of California to cause cancer or reproductive toxicity. SECTION 16 Not available Notice The supplier disclaims all expressed or implied warranties of merchantability or fitness for a specific use, with respect to the product or the information herein, except for conformation to contracted specifications. All information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to accurate, we make no representations as to its accuracy or sufficiency. Conditions of use are beyond our control, and therefore users are responsible for verifying the data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use, handling, and disposal of the product. Users also assume all risks in regards to the publication or use of, or reliance upon, information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or process. D-6

7 MATERIAL SAFETY DATA SHEET Product Identity: CARQUEST / CarbonTune Fuel Conditioner for gasoline (petrol) / Step #3 Part #: 73 Page: 1 of 6 Material Safety Data Sheet Approved by U.S. Dept., essentially similar to form OSHA 174. IMPORTANT: Read this MSDS before handling and disposing of this product. Pass this information on to employees, customers, and users of this product. SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Identity: Fuel Conditioner for gasoline (petrol) Part #: CARQUEST 4721 Hargrove Effective: 02/18/05 Raleigh, NC Printed: 10/20/05 USA Tel: (919) hour Emergency Phone, Chemtrec: , or international SECTION 2. INGREDIENT & REGULATORY INFORMATION All components of this product are on the TSCA List. SARA Title III Section 313 Supplier Notification. This product contains the indicated <*> toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning & Community Right-To- Know Act of 1986 & of 40 CFR 372. This information must be included in all MSDS's that are copied and distributed for this material. Cas Registry No. %v % w Chemical Names EXPOSURE LIMITS IN AIR (units in ppm) Listed as a Carcinogen In NTP IARC Or OHSA 1910 OSHA ACGIH TWA STEL VENDOR <5 Hexanol (1-Hexanol) N/E N/E N/E N/E NO <5 * Xylene which contains: Ethyl Benzene NO * Ethyl Glycol Monobutyl Skin N/E 25/50 Ether Air N/E 100 NO <5 Oxygenated Hydrocarbon N/E N/E N/E N/E NO <5 Petroleum Oil N/E N/E N/E N/E NO Mist 5mg/M 5mg/M 5mg/M N/E * Hydrocarbon Petroleum Distillate or Naphtha which Contains Naphthalene N/E 10 N/E NO 2002 MotorVac Technologies, Inc. D-1

8 Product Identity: CARQUEST / CarbonTune Fuel Conditioner for gasoline (petrol) / Step #3 Part #: 73 Page: 2 of 6 SECTION 3. HAZARDOUS IDENTIFICATION Threshold limit value: See Section II EFFECTS OF OVEREXPOSURE: Eye & Skin Contact: Primary irritation to skin, defatting, dermatitis. Absorption through skin increases exposure. Primary irritation to eyes, redness, tearing, blurred vision. Liquid can cause eye burns. Wash thoroughly after handling. Inhalation: Anesthetic. Irritates respiratory tract. Acute overexposure can cause headache, nausea, dizziness, weakness and fatigue. Breathing vapor can cause irritation. Acute overexposure can result in unconsciousness and even respiratory arrest. Swallowing: Vomiting may result. Pulmonary aspiration hazard if vomiting occurs. Chronic hazards: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. SECTION 4. FIRST AID MEASURES PROCEDURES Eye Contact: Immediately flush with plenty of water for 15 minutes & call a physician. Skin Contact: Immediately remove contaminated clothing. Wash skin thoroughly with soap and water. Wash contaminated clothing before reuse. (Discard contaminated shoes.) Inhalation: After high vapor exposure, remove to fresh air. If breathing is difficult, give, oxygen. If breathing has stopped give artificial respiration. Call a physician immediately! Swallowing: Call a physician immediately! Do not induce vomiting. Never give anything by mouth to an unconscious person. Have patient lie down and keep warm. Vomiting may lead to pneumonititis, which may be fatal. D MotorVac Technologies, Inc.

9 Product Identity: CARQUEST / CarbonTune Fuel Conditioner for gasoline (petrol) / Step #3 Part #: 73 Page: 3 of 6 SECTION 5. FIRE FIGHTING MEASURES Flammable limits: LEL 0.5 UEL Flash point (test method): 137 F/ 58.3 C (TCC) (lowest component) Extinguishing media: CO₂ dry chemical, foam or other National Fire Protection Association (NFPA) approved method for treating a Class B fire. Special fire fighting procedures: Water spray may be ineffective on fire but can protect fire-fighters and cool closed containers. Use fog nozzles if water is used. Do not enter confined fire-space without full bunker gear. (helmet with face shield, bunker coats, gloves & rubber boots). Use NIOSH approved positive-pressure self-contained breathing apparatus. Unusual explosion and fire procedures: Combustible! Keep container tightly closed. Isolate from oxidizers, heat, & open flame. Closed containers may explode if exposed to extreme heat. Applying to hot surfaces requires special precautions. Empty container very hazardous! Continue all label precautions! SECTION 6. ACCIDENTAL RELEASE MEASURES Spill or leak procedures: Remove all sources of ignition (flames, hot surfaces and electrical, static or frictional sparks). Do not smoked. Prevent breathing vapors. Ventilate area. Stop spill at source. Dike & contain area with inert absorbent materials. Store in closed container until properly disposed. Waste disposal method: Recycle or dispose of observing local, state & federal health, safety & pollution laws. If questions exist, contact the appropriate agencies. Do not incinerate closed containers. CERCLA (Superfund) Reportable quantity (in lbs): One pound or refer to Section 311 Clean Water Act RCRA hazardous Waste No. (40 CFR ): D-001 Note: Numbers apply to thinner blend only. Volatile Organic Compound (VOC): XX Theoretical lb/gal XX Analytical lb/gal 2002 MotorVac Technologies, Inc. D-3

10 Product Identity: CARQUEST / CarbonTune Fuel Conditioner for gasoline (petrol) / Step #3 Part #: 73 Page: 4 of 6 SECTION 7. HANDLING AND STORAGE Precautions when Handling and/or Storing: Isolate from oxidizers, heat, and open flame. Do not store above 80 F. Use only with adequate ventilation. Avoid breathing of vapor or spray mist. Do not get in eyes, on skin or clothing. Wear OSHA standard goggles or face shield. Consult safety equipment supplier. Wear gloves, apron and footwear impervious to this material. Wash clothing before reuse. Avoid free fall of liquid. Ground containers when transferring. Do not flame cut, braze, or weld. Empty container very hazardous, do not reuse! Continue all label precautions! SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Exposure controls: When used in restricted ventilation areas, wear NIOSH/MSHA approved chemical/mechanical filters designed to remove a combination of particles and vapor. When used in confined areas wear NIOSH/MSHA approved air supply respirators or hoods. Follow respirator manufacture s direction for respirator use. If respirators are used, a program should be established to assure compliance with OSHA standard 29 CFR Ventilation: Local exhaust: Necessary Mechanical (general): Acceptable Special: None Other: None Personal protection: Wear OSHA standard goggles or face shield. Consult safety equipment supplier. Wear gloves, apron & footwear impervious to this material (butyl and F.E.P. Teflon and other solvent impermeable products). Wash clothing before reuse. D MotorVac Technologies, Inc.

11 Product Identity: CARQUEST / CarbonTune Fuel Conditioner for gasoline (petrol) / Step #3 Part #: 73 Page: 5 of 6 SECTION 9. PHYSICAL DATA Appearance: Liquid, Amber color Odor: Aromatic odor Boiling Range: F / C Specific gravity (water = 1): Pounds/gallon (lbs./gal): Vapor pressure (mm of HG)@20 C: N/A Vapor density (air = 1): Greater than air %Volatile by vol.: % Solid by Weight 0.0 Evaporation Rate: Slower than Ether Solubility in Water: 0% ph N/A Is Material: Solid, Gas, Paste, Powder SECTION 10. REACTIVITY DATA Stability: Stable Conditions to avoid: Isolate from oxidizers, heat, ignition source and open flame. Material to avoid: Isolate from strong oxidizers such as permanganates, chromates and peroxides. Hazardous decomposition products: Carbon monoxide, carbon dioxide from burning. Hazardous polymerization: Will not occur. SECTION 11. Not available SECTION 12. Not available SECTION 13. DISPOSAL CONSIDERATIONS This product is considered a hazardous waste. May be incinerated or burned in a RCRA licensed facility MotorVac Technologies, Inc. D-5

12 Product Identity: CARQUEST / CarbonTune Fuel Conditioner for gasoline (petrol) / Step #3 Part #: 73 Page: 6 of 6 SECTION 14. TRANSPORTATION INFORMATION *Note the information below are just guidelines. It is the responsibility of the shipper to ensure that all the proper procedures are followed. When shipped by ground (U.S.A.), not regulated ref. CFR When shipped by ground (U.S.A.), in drums: not regulated When Shipped by air: (NOT APPLICABLE TO DRUMS) D.O.T. CFR 49 proper shipping name: Petroleum distillates, n.o.s. Hazardous Class: 3 UN Number: 1268 Packing Group: III Packing Instruction: Y309 Transportation Details: Permitted in Passenger and Cargo Aircraft (in appropriate quantities), Non-Radioactive DRUMS: D.O.T. CFR 49 proper shipping name: Petroleum distillates, n.o.s. Hazardous Class: 3 UN Number: 1268 Packing Group: III Packing Instruction: 310 Transportation Details: Cargo Aircraft Only, Non-Radioactive SECTION 15. REGULATORY INFORMATION California proposition 65: This product contains no known chemical known to the State of California to cause cancer or reproductive toxicity. SECTION 16 Not available Notice The supplier disclaims all expressed or implied warranties of merchantability or fitness for a specific use, with respect to the product or the information herein, except for conformation to contracted specifications. All information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to accurate, we make no representations as to its accuracy or sufficiency. Conditions of use are beyond our control, and therefore users are responsible for verifying the data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use, handling, and disposal of the product. Users also assume all risks in regards to the publication or use of, or reliance upon, information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or process. D MotorVac Technologies, Inc.