EU/EN MSDS number Revision Date Oct Revision Number 0.01

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Celcon The following SDS applies to products described by combinations of the following trade name, product grade and color code listed below. Product Grade(s): UV90Z Color Code: See Section 16 for list of Color Codes. REACH Registration Number This product is a mixture and therefore not directly subject of the registration requirements under REACH Relevant identified uses of the substance or mixture and uses advised against Identified uses Plastic processing industry Details of the supplier of the safety data sheet TICONA GmbH Am Unisys-Park Sulzbach Germany SDS Contact ( of responsible person) HazCom@Celanese.com 1.4. Emergency telephone number CHEMTREC: (Collect calls accepted) +49 (0) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation 1272/2008/EC (CLP) Not a hazardous substance or preparation according to Regulation 1272/2008 (CLP) Classification and labelling according to Directive 67/548/EWG or 1999/45/EC Not a hazardous substance or preparation according to EC-directives 67/548/EEC or 1999/45/EC 2.2. Label elements Not required 2.3 Other Hazards None 1 of 7

2 SECTION 3: Composition/information on ingredients Chemical characterization Polyacetal Copolymer / POM; CAS-RN of the basic polymer: Substances not applicable 3.2. Mixtures Details provided in the tables below Components CAS-No EC-No. Identification Percent % Number Formaldehyde < 0.1 Components 67/548/EEC 1272/2008/EC (CLP) Hazard Statements Formaldehyde Carc. Cat.3; R40 Acute oral toxicity - Category 3 Acute dermal toxicity - Category 3 H301 H311 T; R23/24/25 Acute inhalation toxicity - Category 3 H314 C; R34 Xi; R43 Skin corrosion / irritation - Category 1B Skin sensitization - Category 1 Carcinogenicity - Category 2 H317 H331 H351 Remarks For the full text of the R-phrases mentioned in this Section, see Section 16 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Skin Eyes Ingestion Move to fresh air in case of accidental inhalation of vapors. Get medical attention immediately if symptoms occur. Cool skin rapidly with cold water after contact with molten polymer. Immediate medical attention is required. Do not peel solidified product off the skin. Immediately flush eye(s) with plenty of water. Call a physician if irritation persists. If swallowed, do not induce vomiting - seek medical advice Most important symptoms and effects, both acute and delayed Main symptoms None known 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water, Foam, Dry powder, Dry chemical, Solid extinguishing agent 2 of 7

3 MSDS number Revision Date 5.2. Special hazards arising from the substance or mixture Hazardous combustion products Carbon dioxide (CO2) Formaldehyde vapours Carbon monoxide 5.3. Advice for firefighters Special protective equipment for fire-fighters Wear self-contained breathing apparatus and protective suit. Other Information Potential dust explosion hazard. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Remove all sources of ignition. Avoid dust formation Environmental precautions No special environmental precautions required Methods and material for containment and cleaning up Use mechanical handling equipment. Dispose of in accordance with local regulations Reference to other sections Consult trained personnel Consider the information for "Personal Protection" in chapter 8 of this Safety Data Sheet SECTION 7: Handling and storage 7.1. Precautions for safe handling Hygiene measures Clean skin thoroughly after work; apply skin cream When using, do not eat, drink or smoke Advice on safe handling Provide for appropriate exhaust ventilation and dust collection at machinery. Incompatible products strong acids, oxidizing agents, Polyvinyl chloride 7.2. Conditions for safe storage, including any incompatibilities Material storage Maximum storage temperature 40 C. Keep in a dry place. To maintain product quality, do not store in heat or direct sunlight. Incompatible products strong acids, oxidizing agents, Polyvinyl chloride German storage class 11: Combustible solids 7.3. Specific end use(s) None known 3 of 7

4 SECTION 8: Exposure controls/personal protection 8.1. Control parameters EC Exposure Limit Values The OEL (occupational exposure limit) of Formaldehyde (the German TRGS 900: 0,62mg/m³, 0,5ml/m³) is cancelled with the amendment of the TRGS 900 in January This figures are only for information. The development of a new OEL is in process Exposure controls Engineering measures General: May not be adequate as the sole means to control employee exposure. Local Exhaust: Recommended when appropriate to control employee exposure to dust or process vapors. Personal protective equipment General advice Hygiene measures Respiratory protection Eye protection Skin protection Hand protection Suitable material Type Break through time Do not breathe dust. Avoid contact with skin and eyes. Clean skin thoroughly after work; apply skin cream When using, do not eat, drink or smoke Wear dust mask when handling large quantities. safety glasses with side-shields Avoid contact with skin Chemicals resistant gloves Suitable material Butoject (Company KCL) or comparable article; or refer to glove manufacturer's recommendation 480 min Environmental exposure controls Do not discharge into the drains/surface waters/groundwater Environmental Precautions Should not be released into the environment SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Form pellets Odor slight, specific Flash point >93 C Ignition temperature 320 C Method ASTM D of 7

5 SECTION 9: Physical and chemical properties Density C approx Bulk density approx C Vapor pressure not determined Water solubility insoluble 9.2. Other information The product was not tested for properties not listed on the MSDS.. SECTION 10: Stability and reactivity Reactivity Stable under normal conditions Chemical Stability Thermal decomposition can take place above 240 C Possibility of hazardous reactions Polyvinyl chloride. Incompatible with strong acids and oxidizing agents Conditions to avoid Flame. Avoid temperatures above 238 C / 460 F Incompatible Materials strong acids, oxidizing agents, Polyvinyl chloride Hazardous decomposition products No hazardous decomposition products are known SECTION 11: Toxicological information Information on toxicological effects Toxicological data are not available. When handled appropriately, even after long years of experience with this product, no adverse health effects are known. SECTION 12: Ecological information Product is insoluble in water. According to experience, the material has no harmful effect on the environment. SECTION 13: Disposal considerations Waste treatment methods Product information Uncleaned empty packaging In accordance with current regulations may be taken to waste disposal site or incineration plant, after consultation with site operator and/or with the responsible authority. Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for reuse. European Waste Catalogue150102: Packages from plastics 5 of 7

6 MSDS number Revision Date SECTION 14: Transport information ADR/RID ADN Not regulated Not regulated ICAO/IATA IMDG Not restricted Not regulated SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Water Hazard Class (WGK): not water endangering WGK Reg. No. 766 WGK Source KBwS classification 15.2 Chemical Safety Assessment Chemical Safety Assessment (CSA) is not required Authorization - Reach Regulation, Title VII This substance is not subject to authorization requirements Restrictions - Reach Regulation, Titel VIII This substance meets not the criteria SECTION 16: Other information Formaldehyde R34 - Causes burns R37 - Irritating to respiratory system R40 - Limited evidence of a carcinogenic effect R43 - May cause sensitization by skin contact R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed Color Code(s): CG34874 For further information, see: For more information, other material safety data sheets or technical data sheets please consult the Celanese homepage ( Other Information: Observe national and local legal requirements Except as otherwise noted, all of the trademarks referenced herein are owned by Ticona or its affiliates. Changes against the previous version are marked by *** Training advice Make sure that employees are aware of the hazards / risks as detailed on this Safety Data Sheet. When wearing a breathing apparatus, the need for appropriate training needs to be considered. 6 of 7

7 Sources of key data used to compile the datasheet Information contained in this safety data sheet is based on Celanese owned data and public sources deemed valid or acceptable.. Further information This information is based on our present state of knowledge. It shall describe our products regarding safety requirements and shall not be construed as a guarantee or statement of condition and/or quality. Abbreviation and Acronym: NOEC = No Observed Effect Concentration ADR = Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID = Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG = International Maritime Code for Dangerous Goods IATA = International Air Transport Association ICAO = International Civil Aviation Organization GHS = Globally Harmonized System of Classification and Labelling of Chemicals EINECS = European Inventory of Existing Commercial Chemical Substances CAS = Chemical Abstracts Service (division of the American Chemical Society) CLP = Classification, Labelling and Packaging PBT = Persistent, Bioaccumulative and Toxic vpvb = very Persistent and very Bioaccumulative R-Phrases = Risk Phrases S-Phrases = Safety Phrases Annex: Exposure Scenario(s) Development of Exposure Scenario is not required 7 of 7