SAFETY DATA SHEET. Serious eye damage/eye irritation

Transcription

1 SAFETY DATA SHEET 1. Identification GHS product identifier Version. 01 Issue date 23-July-2015 Revision date - Supersedes date - CAS. Mixture Recommended use Cleaning products. Recommended Restrictions Use in accordance with supplier's recommendations. Manufacturer ESSILOR International 147, rue de Paris Charenton-le-Pont Cedex France Contact person Global EHS Department Telephone +33 (0) responsibleforsds@essilor.com 1.4. Emergency telephone N ORFILA (33) (0) number 2. Hazards identification GHS classification Physical hazards Health hazards Environmental hazards GHS label elements Signal word Flammable liquids Serious eye damage/eye irritation Aspiration hazard Danger Category 4 Category 2A Category 1 Hazard statement Precautionary statements Prevention Response Storage Disposal Supplemental information 3. Composition/information on ingredients Combustible liquid. May be fatal if swallowed and enters airways. Causes serious eye irritation. Wash thoroughly after handling. Wear protective gloves/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Do NOT induce vomiting. If eye irritation persists: Get medical advice/attention. In case of fire: Use appropriate media to extinguish. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. Components CAS. Percent Distillates (petroleum), hydrotreated light 2-Methoxy-1-methylethyl acetate 1,1,1,3,3-pentafluorbutane 1,1,1,2,2,3,4,5,5,5-decafluoropentane Version #: 01 Revision date: - Issue date: 23-July / 5

2 Composition comments 4. First aid measures First aid procedures Inhalation Skin Eye Ingestion Most important symptoms and effects, both acute and delayed tes to physician General advice 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Protective equipment and precautions for firefighters Protection of fire-fighters All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Move into fresh air and keep at rest. Get medical attention if any discomfort continues. Flush skin thoroughly with water. Get medical attention if any discomfort continues. Flush eyes thoroughly with water for at least 15 minutes. Remove any contact lenses. Get medical attention if any discomfort continues. Rinse mouth thoroughly. Drink a few glasses of water or milk. Only induce vomiting at the instruction of medical personnel. Get medical attention if any discomfort continues. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Irritation of eyes. Symptoms may include redness, oedema, drying, defatting and cracking of the skin. Aspiration may cause pulmonary oedema and pneumonitis. In case of shortness of breath, give oxygen. Keep victim under observation. Provide general supportive measures and treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Water spray, foam, dry powder or carbon dioxide. Do not use water jet as an extinguisher, as this will spread the fire. The product is combustible, and heating may generate vapours which may form explosive vapour/air mixtures. Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. Prevent runoff from fire control or dilution from entering streams, sewers or drinking water supply. 6. Accidental release measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep unnecessary personnel away. Ventilate closed spaces before entering. Avoid inhalation of vapours and contact with skin and eyes. Wear suitable protective clothing. Do not discharge into drains, water courses or onto the ground. Dike the spilled material, where this is possible. Collect and dispose of spillage as indicated in Section 13 of the SDS. Absorb spillage with non-combustible, absorbent material. 7. Handling and storage Handling Storage All handling to take place in well-ventilated area. Avoid inhalation of vapours and contact with skin and eyes. Follow rules for combustible liquids. Keep away from heat, spark, open flames and other sources of ignition. Keep away from sources of ignition - smoking. Wear appropriate personal protective equipment. Wash hands after handling. Wash contaminated clothing before reuse. Observe good industrial hygiene practices. Keep container tightly closed in a dry and well-ventilated place. Store away from incompatible materials. 8. Exposure controls / personal protection Occupational exposure limits Recommended monitoring procedures Engineering controls Personal protective equipment Eye/face protection Skin protection Respiratory protection Hand protection exposure limits noted for ingredient(s). Follow standard monitoring procedures. Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of vapours. Wear approved safety glasses or goggles. rmal work clothing (long sleeved shirts and long pants) is recommended. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Nitrile gloves are recommended. Suitable gloves can be recommended by the glove supplier Version #: 01 Revision date: - Issue date: 23-July / 5

3 9. Physical and chemical properties Appearance Colourless liquid. Physical state Liquid. Colour Colourless. Form Liquid. Odour Hydrocarbon. Odour threshold ph 7 Melting point/freezing point Boiling point C ( F) Flash point 63.0 C (145.4 F) Evaporation rate Flammability (solid, gas) t applicable. Flammability limits in air, lower, % by volume Flammability limits in air, upper, % by volume Vapour pressure Vapour density Relative density Solubility(ies) Solubility (water) < 0.1 % (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity 10. Stability and reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Stable under normal temperature conditions. Hazardous reactions do not occur. Heat, sparks, flames. Oxidising materials. Alkali metals. Alkalies. Caustics. Metals. Carbon dioxide. Carbon monoxide. Various hydrocarbons. Hydrogen fluoride. Fluorophosgene. 11. Toxicological information Routes of exposure Toxicological information Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory sensitizer Skin sensitisation Mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects Eye contact. Skin contact. Inhalation. Ingestion. Occupational exposure to the substance or mixture may cause adverse effects. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Causes serious eye irritation. t classifiable as to carcinogenicity to humans. May be fatal if swallowed and enters airways Version #: 01 Revision date: - Issue date: 23-July / 5

4 Symptoms Other information Irritation of eyes. Symptoms may include redness, oedema, drying, defatting and cracking of the skin. other specific acute or chronic health impact noted. 12. Ecological information Ecotoxicity Environmental effects Persistence and degradability Bioaccumulation Mobility Other adverse effects 13. Disposal considerations Disposal methods Waste from residues / unused products Contaminated packaging 14. Transport information ADR RID IATA IMDG Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. The product is not readily biodegradable. The product is insoluble or slightly soluble in water. Do not discharge into drains, water courses or onto the ground. Empty containers may contain product residues. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Do not discharge into drains, water courses or onto the ground. Dispose of in accordance with local regulations. Empty containers should be taken to an approved waste handling site for recycling or disposal. t applicable. Regulatory information This material safety data sheet was prepared in accordance with "Globally Harmonized System of Classification and Labelling of Chemicals (GHS). International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada n-domestic Substances List (NDSL) China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Europe European List of tified Chemical Substances (ELINCS) Japan Inventory of Existing and New Chemical Substances (ENCS) Korea Existing Chemicals List (ECL) New Zealand New Zealand Inventory Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "" indicates this product complies with the inventory requirements administered by the governing country(s). A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information Disclaimer List of abbreviations The information in the sheet was written based on the best knowledge and experience currently available Version #: 01 Revision date: - Issue date: 23-July / 5

5 LC50: Lethal Concentration, 50%. LD50: Lethal Dose, 50% Version #: 01 Revision date: - Issue date: 23-July / 5