SAFETY DATA SHEET. according to Regulation (EC) No. 453/2010

Transcription

1 SAFETY DATA SHEET according to Regulation (EC) No. 453/2010 Page: 1/5 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Chemical type Trade name Product code : Mixture : : 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Description/Application Uses advised against No uses adviced against Details of the supplier of the safety data sheet CHRISTEYNS s.r.o. Vítovská 453/ Odry T Emergency telephone number National Poisons Information Service worldwide: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin Corr. 1A : Liquid detergent without phosphorus. For professional use only. H314 Causes severe skin burns and eye damage Adverse physicochemical, human health and environmental effects Mixture was classified as corrosive for skin and eyes Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : CLP Signal word Danger Hazardous ingredients : Formic acid; Acetic acid; Sulphamic acid. Hazard statements (CLP) : H314 Causes severe skin burns and eye damage. Precautionary statements (CLP) : P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash the hands thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P363 Wash contaminated clothing before reuse. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations Other hazards Substance meets the criteria for PBT according to regulation (EG) n. 1907/2006, annex XIII : Not applicable

2 Page: 2/5 P : no B : no T : no Substance meets the criteria for vpbt according to regualtion (EG) n. 1907/2006, annex XIII : vp : not vb : not SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Formic acid (CAS-no) (Einecs nr) (EG annex nr) Acetic acid 98% (CAS-no) (Einecs nr) (EG annex nr) (REACH-no) Sulphamic acid (CAS-no) (Einecs nr) (ES annex nr) Full text of H- and EUH-phrases: see section 16. SECTION 4: First aid measures 4.1. Description of first aid measures General advice Inhalation Skin contact Eye contact Ingestion 4.2. Most important symptoms and effects, both acute and delayed Acute effects skin Acute effects eyes Acute effects oral route Skin Corr. 1A, H Flam. Liq 3, H226 Skin Corr. 1A, H314 < 5 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Aquatic Chronic 3, H412 : In case of doubt or persistent symptoms, consult always a physician. For symptom description, see item 11. : Take victim to fresh air, in a quiet place and if necessary take medical advice. : Take off immediately all contaminated clothing. Rinse immediately and plentifully with plenty of water and seek medical advice. : Wash with plenty of water (during 20 minutes minimum) with eyes wide open, also under the eyelids. Keeping contact lenses and immediately take medical advice. : Rinse mouth, do not vomit, keep quiet, and go immediately to hospital or to a doctor. Show this label or safety data sheet for this product. : Corrosive effect to skin. : Corrosive effect to eyes. : Burns of the upper digestive and respiratory tracts Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Concerning personal protective equipment to use, see item For emergency responders 6.2. Environmental precautions Stop leak without risks if possible Methods and material for containment and cleaning up Absorb spilled material with sand or earth. Sweep up, shovel or vacuum Reference to other sections : In fire case not far from, any kind of extinguisher can be used: foam, sand, carbon dioxyde (CO2), water.

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Page: 3/5 Do not eat, drink and do not smoke in areas where product is used. Do not use compressed air to fill, handle or work up. No special handling advice required Conditions for safe storage, including any incompatibilities Only store product in original container. Keep out of frost Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Hand protection : Chemical resistant PVC gloves (to European standard EN 374 or equivalent). Eye protection : Safety glasses with side-shields (EN 166). Protective equipment : Wear suitable protective clothing (EN 14605). Respiratory protection SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Physical state/form Colour : /. Odour Odour threshold : Not necessary with sufficient ventilation. : Liquid : Liquid. : None. ph : 2,3 ± 0,5 (100%) Melting point/range : < 0 C Solidification point Boiling point/boiling range : / Flash point Relative evaporation rate (butylacetate=1) Flammability (solid, gas) Explosive limits Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Autoignition temperature Decomposition temperature Viscosity : Not applicable. : 1,11 g/cm 3 (20 C) : Water: Soluble 9.2. Other information No additional information available SECTION 10: Stability and reactivity Reactivity Chemical stability The product is stable at normal handling and storage conditions Possibility of hazardous reactions Conditions to avoid Incompatible materials Never mix with other materials Hazardous decomposition products Hazardous decomposition products may be released during prolonged heating like smokes, carbon monoxide and dioxide.

4 SECTION 11: Toxicological information Information on toxicological effects Corrosivity : Causes burns. Page: 4/5 SECTION 12: Ecological information Toxicity Persistence and degradability The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste / unused products SECTION 14: Transport information In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA UN number UN-No. : 3265 : Collect all waste in suitable and labelled containers and dispose according to local legislation UN proper shipping name Proper shipping name Transport document description : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (formic acid, acetic acid) : UN 3265, CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (formic acid, acetic acid), 8, III, 3(E) Transport hazard class(es) Class (UN) : 8 Hazard labels (UN) : Packing group Packing group (UN) Environmental hazards Other information : III : No supplementary information available Special precautions for user Overland transport Hazard identification number (Kemler No.) : 80 Classification code : C3 Tunnel code : E Limited quantities (ADR) : 5 L Excepted quantities (ADR) : E Transport by sea Air transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable.

5 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations INGREDIENT DECLARATION ACCORDING TO 648/2004/EEG <5% Non-ionic surfactants National regulations No chemical safety report for the product available. Page: 5/ Chemical safety assessment SECTION 16: Other information It is recommended to pass the information of this safety data sheet in an appropriate form to the users. Such information is actually the best of our knowledge and believes accurate as reliable. This information relates to the specific material designated and may not be valid in combination with other products. This safety data sheet is in compliance with 1907/2006/EEC. It is user's liabilities to take all necessary measures to meet local required laws and regulations. The producer is not responsable for any damage and loss due to the use of information mentioned in this safety data sheet. HISTORY PREVIOUS REVISION DATE : REVIEW CHAPTER(S) N : 2,3,16 Full text of H-, P- and EUH-phrases: Aquatic Chronic 3 Harmful to aquatic life with long lasting effects Category Eye Irrit. 2 Serious eye damage/eye irritation Category 2 Flam. Liq. 3 Flammable liquids Category 3 Skin Corr. 1A Skin corrosion/irritation Category 1A Skin Irrit. 2 Skin corrosion/irritation Category 2 H226 Flammable liquid and vapour H314 Causes severe skin burns and eye damage H315 Causes skin irritation H319 Causes serious eye irritation H412 Harmful to aquatic life with long lasting effects P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash the hands thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 Immediately call a POISON CENTER or doctor/physician. P363 Wash contaminated clothing before reuse P405 Store locked up P501 Dispose of contents/container in accordance with local/regional/national/international regulations.