SAFETY DATA SHEET. according to Regulation (EC) No. 1907/2006. Part number: Version : 1.0 GB / EN

Transcription

1 Print Date: Revision Date : Page 1 of Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Commercial Product Name : Frostox HT Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Radiator anti-freeze 1.3 Details of the supplier of the safety data sheet Company : HAERTOL Chemie GmbH Havelstr Magdeburg Telephone : Telefax : Contact person : Herr Egon Dühring address : info@haertol.de 1.4 Emergency telephone number Hazards identification 2.1 Classification of the substance or mixture Classification (67/548/EEC, 1999/45/EC) Harmful R22: Harmful if swallowed. 2.2 Label elements Labelling according to EC Directives: 1999/45/EC Hazard symbols : Harmful R-phrase(s) : R22 Harmful if swallowed. S-phrase(s) : S60 This material and its container must be disposed of as hazardous waste. Hazardous components which must be listed on the label: 2.3 Other hazards 1/12

2 Print Date: Revision Date : Page 2 of Composition/information on ingredients 3.2 Mixtures Hazardous components Chemical Name CAS-No. EC-No. Classification (67/548/EEC) Classification (1272/2008/EC) Registration number Xn; R22 Acute Tox. 4; H STOT RE 2; H For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16. Concentration [%] >= 90 - < First aid measures 4.1 Description of first aid measures General advice If inhaled In case of skin contact In case of eye contact If swallowed : In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Take off all contaminated clothing immediately. Never give anything by mouth to an unconscious person. : Remove to fresh air. Keep patient warm and at rest. If symptoms persist, call a physician. : Wash off immediately with soap and plenty of water. : Remove contact lenses. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. : If swallowed, seek medical advice immediately and show this container or label. If a person vomits when lying on his back, place him in the recovery position. Do NOT induce vomiting. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed 2/12

3 Print Date: Revision Date : Page 3 of Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting : Build-up of dangerous/toxic fumes possible in cases of fire/high temperature. Exposure to decomposition products may be a hazard to health. 5.3 Advice for firefighters Special protective equipment for firefighters Further information : In the event of fire, wear self-contained breathing apparatus. : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Ventilate the area. Remove all sources of ignition. Avoid inhalation of vapour or mist. Avoid contact with skin and eyes. 6.2 Environmental precautions Should not be released into the environment. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). 6.4 Reference to other sections see chapter: 7, 8, 11, 12 and Handling and storage 7.1 Precautions for safe handling 3/12

4 Print Date: Revision Date : Page 4 of 12 Advice on safe handling Advice on protection against fire and explosion : Avoid contact with skin and eyes. Do not breathe vapours or spray mist. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. : Normal measures for preventive fire protection. Keep away from sources of ignition - No smoking. Dust explosion class : not applicable 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Advice on common storage : Keep away from food, drink and animal feedingstuffs. Incompatible with oxidizing agents. Storage temperature : > -25 C 7.3 Specific end use(s) 8. Exposure controls/personal protection 8.1 Control parameters Components CAS-No. Control parameters Basis Update TWA (Vapour): 52 mg/m3, 20 ppm Sk, TWA (Particulates): 10 mg/m3, Sk, STEL (Vapour): 104 mg/m3, 40 ppm Sk, GB EH Components CAS-No. Control parameters Basis Update TWA: 52 mg/m3, 20 ppm skin, STEL: 104 mg/m3, 40 ppm skin, 2000/39/EC Other information on limit values: see chapter Exposure controls Engineering measures Provide sufficient air exchange and/or exhaust in work rooms. 4/12

5 Print Date: Revision Date : Page 5 of 12 Personal protective equipment Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Respirator with filter type A Hand protection Material Glove thickness Breakthrough time: Remarks Eye protection : butyl-rubber : 0,6-0,8 mm : > 480 min : Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. : Safety glasses Skin and body protection : Lightweight protective clothing Hygiene measures : When using do not eat, drink or smoke. Avoid contact with skin, eyes and clothing. Wash hands before breaks and at the end of workday. Wash contaminated clothing before re-use. Handle in accordance with good industrial hygiene and safety practice. General industrial hygiene practice. Environmental exposure controls General advice : Should not be released into the environment. If the product contaminates rivers and lakes or drains inform respective authorities. 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : liquid Colour : violet Odour : Odour Threshold : Flash point : > 110 C Ignition temperature Thermal decomposition Lower explosion limit : : No decomposition if stored and applied as directed. : 5/12

6 Print Date: Revision Date : Page 6 of 12 Upper explosion limit : Explosive properties : Flammability : Oxidizing properties : Auto-ignition temperature : Burning number : Molecular weight : ph : 8,1 Concentration: 330,00 g/l Boiling point/boiling range : > 170 C Method: ASTM D Vapour pressure : Density : 1,11-1,14 g/cm3 at 20 C Method: DIN Bulk density Water solubility Partition coefficient: n- octanol/water Solubility in other solvents Viscosity, dynamic Viscosity, kinematic Flow time Impact sensitivity Relative vapour density Surface tension Evaporation rate Minimum ignition energy Acid number Refraction index Miscibility in water : : soluble : : : : : : : : : : : : : completely miscible Solvent separation test : 9.2 Other information Refractive index : 1,425-1, Stability and reactivity 10.1 Reactivity 10.2 Chemical stability The product is chemically stable Possibility of hazardous reactions 6/12

7 Print Date: Revision Date : Page 7 of 12 Stability : Product is hygroscopic Conditions to avoid Keep away from heat and sources of ignition Incompatible materials Materials to avoid : Oxidizing agents 10.6 Hazardous decomposition products Hazardous decomposition products : Build-up of dangerous/toxic fumes possible in cases of fire/high temperature., No decomposition if stored and applied as directed. 11. Toxicological information 11.1 Information on toxicological effects Acute toxicity Acute oral toxicity : Harmful if swallowed. Acute inhalation toxicity: : LC50 rat: > 2,5 mg/l Test atmosphere: dust/mist Exposure time: 6 h Acute dermal toxicity: : LD50 mouse: > mg/kg Acute toxicity (other routes of administration): Skin corrosion/irritation : Species: rabbit No skin irritation Serious eye damage/eye irritation : Species: rabbit No eye irritation Respiratory or skin sensitisation Sensitisation: : Test Method: Maximisation Test Species: guinea pig Result: Did not cause sensitisation on laboratory animals. Germ cell mutagenicity Genotoxicity in vitro: 7/12

8 Print Date: Revision Date : Page 8 of 12 : Type: Mutagenicity (Salmonella typhimurium - reverse mutation assay) Result: negative Genotoxicity in vivo: : Test species: rat Result: negative Carcinogenicity Remarks : Carcinogenicity: Animal testing did not show any carcinogenic effects. Reproductive toxicity Teratogenicity STOT - single exposure STOT - repeated exposure : Exposure routes: Ingestion Target Organs: Kidney Shown to produce significant health effects in animals at concentrations of >10 to 100 mg/kg bw. Aspiration hazard Aspiration toxicity Neurological effects Toxicology Assessment Toxicology, Metabolism, Distribution Acute effects 8/12

9 Print Date: Revision Date : Page 9 of Ecological information 12.1 Toxicity Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): g/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae : ErC50 (Pseudokirchneriella subcapitata): mg/l Exposure time: 96 h Toxicity to fish (Chronic toxicity) : NOEC: mg/l Exposure time: 7 d Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC: mg/l Exposure time: 7 d Species: Ceriodaphnia Dubia (water flea) 12.2 Persistence and degradability Biodegradability : Result: Readily biodegradable Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects Adsorbed organic bound halogens (AOX) Additional ecological information : Remarks: not included : The product should not be allowed to enter drains, water courses or the soil. 9/12

10 Print Date: Revision Date : Page 10 of Disposal considerations 13.1 Waste treatment methods Advice on disposal and packaging : Disposal: In accordance with local and national regulations. Waste codes should be assigned by the user based on the application for which the product was used. The following Waste Codes are only suggestions: Disposal of uncleaned packaging : Waste key (uncleaned packaging): , packaging containing residues of or contaminated by dangerous substances 14. Transport information 14.1 UN number ADR RID IMDG IATA 14.2 Proper shipping name ADR RID IMDG IATA 14.3 Transport hazard class(es) ADR RID IMDG IATA 14.4 Packing group 10/12

11 Print Date: Revision Date : Page 11 of 12 ADR RID IMDG IATA 14.5 Environmental hazards ADR RID IMDG IATA 14.6 Special precautions for user see chapter: 6, 7 and Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture VOC : not applicable Directive 96/82/EC : Update: 2003 Directive 96/82/EC does not apply Further information : Reserved for industrial and professional use. National legislation Other regulations : Take note of Dir 94/33/EC on the protection of young people at work Chemical Safety Assessment 16. Other information Full text of R-phrases referred to under sections 2 and 3 R22 Harmful if swallowed. Full text of H-Statements referred to under sections 2 and 3. 11/12

12 Print Date: Revision Date : Page 12 of 12 H302 H373 Harmful if swallowed. May cause damage to organs through prolonged or repeated exposure if swallowed. Other information Sk skin Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. Identifies the possibility of significant uptake through the skin The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Prepared by : SAP Business Compliance Services GmbH Birlenbacher Str Siegen Germany Telephone: +49-(0) /12