Freez-It (R) Anti-Stat ES1551E IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING. : Freez-It(R) Anti-Stat

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1 Conforms to Reulation (EC) No. 1907/2006 (REACH), Annex II Europe 1. SAFETY DATA SHEET IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Identification of the substance or mixture Product name Chemical name Synonyms Product type Use of the substance/mixture Company/undertakin identification Manufacturer FreezIt (R) AntiStat ES1551E ES1551E Aerosol. Coolin aents (not for metal processin) Coolin aents ITW Chemtronics 8125 Cobb Center Drive Kennesaw, GA Distributor Tel or toll free Importer address of person responsible for this SDS Emerency telephone number (with hours of operation) 2. HAZARDS IDENTIFICATION Classification ITW Contamination Control BV Saffierlaan 5 VZ2132 Hoofddorp The Netherlands info@itwcc.com Tel FAX askchemtronics@chemtronics.com Chemtrec or collect The product is not classified as danerous accordin to Directive 1999/45/EC and its amendments. Additional hazards Not classified. Dermal contact with rapidly evaporatin liquid could result in freezin of the tissues or frostbite.inestion of liquid can cause burns similar to frostbite. See Section 11 for more detailed information on health effects and symptoms. 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/preparation Inredient name Mixture CAS number dimethyl ether F+; R12 [2] methanol F; R11 T; R23/24/25, R39/23/24/25 [1] [2] See Section 16 for the full text of the Rphrases declared above. [1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit Occupational exposure limits, if available, are listed in Section 8. % EC number Classification There are no additional inredients present which, within the current knowlede of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reportin in this section. 4. FIRST AID MEASURES Firstaid measures Inhalation Inestion Skin contact Move exposed person to fresh air. Keep person warm and at rest. If not breathin, if breathin is irreular or if respiratory arrest occurs, provide artificial respiration or oxyen by trained personnel. Get medical attention if symptoms occur. Wash out mouth with water. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, ive small quantities of water to drink. Do not induce vomitin unless directed to do so by medical personnel. Get medical attention if symptoms occur. If frostbite occurs, et medical attention.flush contaminated skin with plenty of water.remove contaminated clothin and shoes.get medical attention if symptoms occur. 12/15/ /6

2 4. FIRST AID MEASURES Eye contact Protection of firstaiders Notes to physician Immediately flush eyes with plenty of water, occasionally liftin the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. No action shall be taken involvin any personal risk or without suitable trainin. No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if lare quantities have been inested or inhaled. See Section 11 for more detailed information on health effects and symptoms. 5. FIREFIGHTING MEASURES Extinuishin media Suitable Not suitable Special exposure hazards Hazardous thermal decomposition products Special protective equipment for firefihters Use an extinuishin aent suitable for the surroundin fire. None known. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleanin up 7. Small spill Lare spill Handlin Storae HANDLING AND STORAGE Packain materials Recommended Inredient name dimethyl ether In a fire or if heated, a pressure increase will occur and the container may burst. Burstin aerosol containers may be propelled from a fire at hih speed. Promptly isolate the scene by removin all persons from the vicinity of the incident if there is a fire. No action shall be taken involvin any personal risk or without suitable trainin. Move containers from fire area if this can be done without risk. Use water spray to keep fireexposed containers cool. Decomposition products may include the followin materials carbon dioxide carbon monoxide haloenated compounds Firefihters should wear appropriate protective equipment and selfcontained breathin apparatus (SCBA) with a full facepiece operated in positive pressure mode. No action shall be taken involvin any personal risk or without suitable trainin. Evacuate surroundin areas. Keep unnecessary and unprotected personnel from enterin. In the case of aerosols bein ruptured, care should be taken due to the rapid escape of the pressurised contents and propellant. If a lare number of containers are ruptured, treat as a bulk material spillae accordin to the instructions in the cleanup section. Do not touch or walk throuh spilt material. Put on appropriate personal protective equipment (see Section 8). Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if watersoluble. Alternatively, or if waterinsoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillaes into an effluent treatment plant or proceed as follows. Contain and collect spillae with noncombustible, absorbent material e.. sand, earth, vermiculite or diatomaceous earth and place in container for disposal accordin to local reulations (see section 13). Dispose of via a licensed waste disposal contractor. Note see section 1 for emerency contact information and section 13 for waste disposal. Put on appropriate personal protective equipment (see Section 8). Eatin, drinkin and smokin should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eatin, drinkin and smokin. Pressurised container protect from sunliht and do not expose to temperature exceedin 50 C. Do not pierce or burn, even after use. Avoid breathin as. Avoid breathin vapour or mist. Store in accordance with local reulations. Store away from direct sunliht in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Use appropriate containment to avoid environmental contamination. Use oriinal container. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure limit values methanol Occupational exposure limits EU OEL (Europe, 4/2006). Notes Indicative Limit value 1920 m/m³ 8 hour(s). Limit value 1000 ppm 8 hour(s). EU OEL (Europe, 4/2006). Absorbed throuh skin. Notes Indicative Limit value 260 m/m³ 8 hour(s). Limit value 200 ppm 8 hour(s). 12/15/ /6

3 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Recommended monitorin procedures Exposure controls Occupational exposure controls Hyiene measures Respiratory protection Hand protection Eye protection Skin protection Environmental exposure controls 9. If this product contains inredients with exposure limits, personal, workplace atmosphere or bioloical monitorin may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical aents and national uidance documents for methods for the determination of hazardous substances. Use only with adequate ventilation. If user operations enerate dust, fumes, as, vapour or mist, use process enclosures, local exhaust ventilation or other enineerin controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Wash hands, forearms and face thorouhly after handlin chemical products, before eatin, smokin and usin the lavatory and at the end of the workin period. Appropriate techniques should be used to remove potentially contaminated clothin. Wash contaminated clothin before reusin. Ensure that eyewash stations and safety showers are close to the workstation location. Use a properly fitted, airpurifyin or airfed respirator complyin with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe workin limits of the selected respirator. Chemicalresistant, impervious loves complyin with an approved standard should be worn at all times when handlin chemical products if a risk assessment indicates this is necessary. Safety eyewear complyin with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protective equipment for the body should be selected based on the task bein performed and the risks involved and should be approved by a specialist before handlin this product. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection leislation. In some cases, fume scrubbers, filters or enineerin modifications to the process equipment will be necessary to reduce emissions to acceptable levels. PHYSICAL AND CHEMICAL PROPERTIES General information Appearance Physical state Colour Boilin point Meltin point Relative density Vapour density Gas. [Compressed as] Colourless. Odour Ethereal. [Sliht] Important health, safety and environmental information Evaporation rate (butyl acetate = 1) Conditions to avoid Hazardous decomposition products 27 C (16.6 F) C (217.3 F) This is based on data for the followin inredient dimethyl ether. Weihted averae 0.75 (Water = 1) 3.18 (Air = 1) 10. STABILITY AND REACTIVITY Stability Materials to avoid >1 compared with butyl acetate The product is stable. 11. TOXICOLOGICAL INFORMATION Potential acute health effects Inhalation Inestion Skin contact Eye contact Acute toxicity Under normal conditions of storae and use, hazardous decomposition products should not be produced. Product/inredient name Result Species Dose Exposure dimethyl ether LC50 Inhalation Rat 309 /m3 4 hours Vapour methanol LD50 Dermal Rabbit m/k LD50 Rat 7529 m/k Intraperitoneal LD50 Rat 2131 m/k Intravenous LD50 Oral Rat 5600 m/k TDLo Rat 3490 m/k 12/15/ /6

4 11. TOXICOLOGICAL INFORMATION Potential chronic health effects Intraperitoneal TDLo Rat 3000 m/k Intraperitoneal TDLo Oral Rat 8 /k TDLo Oral Rat 3 /k TDLo Oral Rat 3500 m/k LC50 Inhalation Gas. Rat ppm 4 hours Chronic effects Carcinoenicity Mutaenicity Teratoenicity Developmental effects Fertility effects Overexposure sins/symptoms Inhalation Inestion Skin Eyes Taret orans Adverse symptoms may include the followin respiratory tract irritation couhin 12. ECOLOGICAL INFORMATION Environmental effects Aquatic ecotoxicity Adverse symptoms may include the followin irritation redness Contains material which causes damae to the followin orans the nervous system. Contains material which may cause damae to the followin orans astrointestinal tract, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. Product/inredient name Test Result Species methanol to m/l obtusa Neonate <24 hours to u/l to u/l to u/l > u/l m/l 3289 to 4395 m/l 19 to 20 ml/l Fresh water mana LARVAE <24 hours Fish Rainbow trout,donaldson trout Oncorhynchus mykiss Juvenile Weanlin) Fish Blueill Lepomis macrochirus Juvenile Weanlin) 3.07 mana 6 to 24 hours Fish Blueill Lepomis macrochirus mana Neonate <24 hours Fish Rainbow trout,donaldson trout Oncorhynchus mykiss 0.8 Exposure Fish Bleak 12/15/ /6

5 12. ECOLOGICAL INFORMATION > u/l u/l to u/l to u/l to u/l u/l > u/l Alburnus alburnus 8 cm Fish Bleak Alburnus alburnus 8 to 10 cm Fish Rainbow trout,donaldson trout Oncorhynchus mykiss Juvenile Weanlin) Fish Blueill Lepomis macrochirus Juvenile Weanlin) 3.07 Fish Hooknose Aonus cataphractus Adult Crustaceans Common shrimp, sand shrimp Cranon cranon Adult Fish Fathead minnow Pimephales promelas Juvenile Weanlin) 0.2 to 0.5 Conclusion/Summary Bioderadability Conclusion/Summary Other adverse effects Not available. Not available. 13. DISPOSAL CONSIDERATIONS Methods of disposal Hazardous waste 14. TRANSPORT INFORMATION International transport reulations Reulatory information ADR/RID Class UN number UN1950 The eneration of waste should be avoided or minimised wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection and waste disposal leislation and any reional local authority requirements. Do not puncture or incinerate container. Within the present knowlede of the supplier, this product is not rearded as hazardous waste, as defined by EU Directive 91/689/EEC. Proper shippin name AEROSOLS (1,1,1,2 TETRAFLUOROETHANE) Classes PG* Label 2 Additional information ADN/ADNR Class 1950 AEROSOLS(dimethyl ether) 2 IMDG Class 1950 AEROSOLS (1,1,1,2 TETRAFLUOROETHANE) /15/ /6

6 14. TRANSPORT INFORMATION IATA Class 3159 Aerosols, non 2.2 flammable(1,1,1,2 TETRAFLUOROETHANE) PG* Packin roup 15. REGULATORY INFORMATION EU reulations Classification and labelin have been determined accordin to EU Directives 67/548/EEC and 1999/45/EC (includin amendments) and take into account the intended product use. Risk phrases Product use Europe inventory Other EU reulations Additional warnin phrases 16. OTHER INFORMATION Full text of Rphrases referred to in sections 2 and 3 Europe Full text of classifications referred to in sections 2 and 3 Europe History Date of printin Date of previous issue Version Prepared by Notice to reader This product is not classified accordin to EU leislation. Professional applications, Used by sprayin. Not determined. Pressurised container protect from sunliht and do not expose to temperature exceedin 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of inition No smokin. Keep out of the reach of children. Safety data sheet available for professional user on request. R12 Extremely flammable. R11 Hihly flammable. R23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R39/23/24/25 Toxic daner of very serious irreversible effects throuh inhalation, in contact with skin and if swallowed. F+ Extremely flammable F Hihly flammable T Toxic 12/15/ /15/2011. No previous validation. 6 Not available. Indicates information that has chaned from previously issued version. To the best of our knowlede, the information contained herein is accurate. However, neither the abovenamed supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Althouh certain hazards are described herein, we cannot uarantee that these are the only hazards that exist. 12/15/ /6