SAFETY DATA SHEET Mould spray

Transcription

1 1. Identification of the substance/preparation and of the company/undertaking Identification of the substance or preparation Product name Product use Immediately destroys mould, algae, fungus and moss found in areas o high humidity both inside and outside the home. Company/undertaking identification Manufacturer HG International b.v. Telephone No. +31 (0) Address Damsluisweg 70 Fax +31 (0) EJ Almere Internet Country Netherlands Importer Address HG UK Unit 11 Grange Way Business Park Whitehall Road Industrial Estate Uk Colchester Essex CO2 8HF Telephone No. Fax Country Emergency telephone number Netherlands Composition/information on ingredients Substance/preparation Preparation CAS number EC Number % Classification Europe sodium hypochlorite C; R34 R31 Mixture of lauryl ether carboxylic acid and sodium octyl / polymer / 1-5 Xi; R38, 41 sulfate Sodium hydroxide C; R35 See section 16 for the full text of the R Phrases declared above * Occupational Exposure Limit(s), if available, are listed in Section 8 3. Hazards identification The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments. Classification Xi; R36/38 Human health hazards Irritating to eyes and skin. See section 11 for more detailed information on health effects and symptoms. Page 1/6

2 4. First aid measures First aid measures Inhalation If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Obtain medical attention. Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Skin Contact In case of contact, immediately flush skin copiously with water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Obtain medical attention immediately. Eye contact In case of contact, immediately flush eyes with a copious amount of water for at least 15 minutes. Obtain medical attention immediately. See section 11 for more detailed information on health effects and symptoms. 5. Fire-fighting measures Extinguishing media Special exposure hazards Special protective equipment for fire-fighters Use an extinguishing agent suitable for surrounding fires. No specific hazard. Fire fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. 6. Accidental release measures Personal Precautions Environmental precautions and clean-up methods Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment (Section 8). Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. If emergency personnel are unavailable, contain spilled material. For small spills add absorbent (soil may be used in the absence of other suitable materials) scoop up material and place in a sealed, liquid-proof container for disposal. For large spills dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. Note see section 8 for personal protective equipment and section 13 for waste disposal. 7. Handling and storage Handling Storage Packaging materials Recommended Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep container tightly closed. Keep container in a cool, well-ventilated area. Use original container. 8. Exposure controls/personal protection United Kingdom (UK) Sodium hydroxide Exposure controls Occupational exposure controls Occupational exposure limits EH40-OES (United Kingdom (UK), 2002). Notes STEL 2 mg/m 3 15 minute(s). Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapours below their respective occupational exposure limits. Page 2/6

3 9. Respiratory protection Hand protection Eye protection Skin protection This safety data sheet is prepared in accordance with EU Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves or gauntlets complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Physical and chemical properties General information Appearance Physical state Liquid. Colour Yellow. (Light.) Odour Chlorine Important health, safety and environmental information ph 13 to 13.5 [Basic.] Melting point May start to solidify at 10 to 12 C (50 to 53.6 F) based on data for Mixture of lauryl ether carboxylic acid and sodium octyl sulfate. Weighted average 0.12 C (32.2 F) Boiling point The lowest known value is 100 C (212 F) (aqua). Flash point Not applicable. Flammability (solid, gas) Not applicable. Explosive properties Oxidising properties Not applicable Relative density Solubility Evaporation rate (butyl acetate = 1) Other information 10. Stability Conditions to Avoid g/cm 3 Stability and reactivity Toxicological information Easily soluble in hot water. Soluble in cold water (aqua) compared to Butyl acetate. Stable under recommended storage and handling conditions (see section 7). Contact with acids liberates toxic gas. Potential acute health effects Inhalation Ingestion Skin Contact Eye contact Acute toxicity Irritating to skin. Irritating to eyes. Test Result Route Species Page 3/6

4 sodium hypochlorite LD mg/kg Oral Mouse Mixture of lauryl ether carboxylic LD mg/kg Oral Rat acid and sodium octyl sulfate Sodium hydroxide LD50 LDLo 1350 mg/kg 500 mg/kg Dermal Oral Rabbit Rabbit Carcinogenicity Mutagenicity Reproductive toxicity Over-exposure signs/symptoms Inhalation Ingestion Skin Target organs Contains material which causes damage to the following organs lungs, upper respiratory tract, skin, eye, lens or cornea. 12. Other adverse effects Ecological information Ecotoxicity data sodium hypochlorite Mobility Other adverse effects Species Period Result Daphnia magna (EC50) Daphnia magna (EC50) Daphnia magna (EC50) Oncorhynchus mykiss (LC50) Oncorhynchus mykiss (LC50) Oncorhynchus mykiss (LC50) 48 hour(s) 48 hour(s) 48 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 0.04 mg/l 0.17 mg/l 1.57 mg/l mg/l 0.09 mg/l 0.2 mg/l Sodium hydroxide Fish (LC50) 96 hour(s) 72 mg/l 13. Disposal considerations Methods of disposal Waste classification European waste catalogue (EWC) Hazardous waste 14. The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Not applicable. Transport information International transport regulations The classification of the product may meet the criteria for a hazardous waste Page 4/6

5 Regulatory information UN number Proper shipping name Class Packing group Label Additional Information ADR/RID Class Not regulated. - - ADN Class Not regulated. - - IMDG Class Not regulated. - - IATA-DGR Class Not regulated Regulatory information EU Regulations Hazard symbol(s) 16. Risk phrases Safety Phrases Contains Product use Additional warning phrases EC Statistical classification (Tariff Code) Irritant Other information R36/38- Irritating to eyes and skin. S2- Keep out of the reach of children. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37- Wear suitable gloves. S46- If swallowed, seek medical advice immediately and show this container or label. S50- Do not mix with acids. S64- If swallowed, rinse mouth with water (only if the person is conscious). sodium hypochlorite Classification and labelling have been performed according to EU directives 67/548/EEC, 1999/45/EC, including amendments and the intended use. - Consumer applications. Caution! Do not use in combination with other products, hazadours gasses (chlorine) could be released Full text of R phrases referred to in sections 2 and 3 - Europe Full text of classifications referred to in sections 2 and 3 - Europe History Date of printing Date of previous issue Version Verified by T. Rutgers. R34- Causes burns. R35- Causes severe burns. R36/38- Irritating to eyes and skin. R38- Irritating to skin. R41- Risk of serious damage to eyes. R31- Contact with acids liberates toxic gas. C - Corrosive Xi - Irritant No Previous Validation Page 5/6

6 Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Version 5.02 Page 6/6