Supplier: Synthetic base. Eases assembly and disassembly of metal parts by protecting against galling, self-welding, corrosion, and galvanic attack.

Transcription

1 MATERIAL SAFETY DATA SHEET in accordance with 1907/2006/EC 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product Name: 785 Parting Lubricant (Aerosol) Date: 16 May 2007 MSDS No. 194A-12 Not classified as hazardous according to criteria of Worksafe Australia. Company: A.W. CHESTERTON COMPANY 860 Salem Street Groveland, MA , USA Tel.: Fax: customer.service@chesterton.com (Mon. - Fri. 8:30-5:00 PM EST) For Chemical Emergency: 24 hours per day, 7 days per week Call Infotrac: Outside N. America: (collect) Use: Supplier: Synthetic base. Eases assembly and disassembly of metal parts by protecting against galling, self-welding, corrosion, and galvanic attack. 2. HAZARDS IDENTIFICATION Highly flammable. Contents under pressure. Vapours may cause drowsiness and dizziness. Repeated exposure may cause skin dryness or cracking. Direct eye contact may cause eye irritation. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The Aluminum, Graphite and Mica listed do not separate from the mixture or become airborne, therefore, do not present a hazard in normal use. Do not use on oxygen systems. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Ingredients¹ % Wt. CAS No. EC No. Symbol R-phrases Graphite Stoddard Solvent* Xn Mica Aluminum F Petroleum Gases, Liquefied, Sweetened** F+ 12 Heptane F, Xn, N / Carbon Dioxide Methanol F, T 11-23/24/25-39/23/24/25 *Contains less than 0.1 % w/w Benzene. **Contains less than 0.1 % w/w 1,3-Butadiene. See section 15 for text of R-phrases on the label and section 16 for others. A.W. Chesterton Company, 2007 All Rights Reserved. ¹Classified according to: * 29 CFR , 1915, 1916, 1917 Reg. US Patent and TM Office * Mass. Right-to-Know Law (ch. 40, M.G.L..O. 111F) * Controlled Products Regulations * 67/548/EEC (2004/73/EC) and 99/45/EC * Worksafe Australia [NOHSC: 1008 (2004)] Page 1 of 6

2 4. FIRST AID MEASURES Inhalation: Remove to fresh air. If not breathing, administer artificial respiration. Contact physician. Skin Contact: Eye Contact: Ingestion: Advice to Physician: Wash skin with soap and water. Contact physician if irritation persists. Flush eyes for at least 15 minutes with large amounts of water. Contact physician if irritation persists. Do not induce vomiting. Contact physician immediately. Treat symptoms. 5. FIRE-FIGHTING MEASURES Extinguishing Methods: Unusual Fire and Explosion Hazards: Special Fire Fighting Measures: Flammability Classification: Carbon Dioxide, dry chemical, foam or water fog Pressurized containers, when heated, are a potential explosive hazard. Cool exposed containers with water. Recommend Firefighters wear self-contained breathing apparatus. HAZCHEM Emergency Action Code: 2 Y 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Evacuate area. Provide adequate ventilation. Utilize exposure controls and personal protection as specified in Section 8. Environmental Precautions: Methods of Clean Up: No special requirements. Contain spill to a small area. Keep away from sources of ignition - No smoking. If removal of ignition sources is not possible, then flush material away with water. Pick up with absorbent material (sand, sawdust, clay, etc.) and place in a suitable container for disposal. Use caution - floor may be slippery where spill has occurred. 7. HANDLING AND STORAGE Handling: Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No Smoking. Storage: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C (120 F). Do not pierce or burn, even after use. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Hazardous Ingredients OSHA ACGIH TLV AUSTRALIA ppm mg/m 3 ppm mg/m 3 ppm mg/m 3 Graphite (total) 15 (resp) 2 (resp) 3 (resp) 5 Stoddard Solvent Mica 20 mppcf (resp) 3 (insp) 2.5 Aluminum Petroleum Gases, Liquefied, Sweetened Heptane Carbon Dioxide Methanol A.W. Chesterton Company, 2007 All Rights Reserved. Reg. US Patent and TM Office Page 2 of 6

3 Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Other: Not normally needed. If exposure limits are exceeded, use approved organic vapor respirator. Use only in well-ventilated areas. If exposure limits are exceeded, provide adequate ventilation. Not normally needed. Safety glasses Chesterton recommended limit: 5mg/m 3 oil mist 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Odour moderate Colour gray Vapour 20 C unknown Initial boiling point 94 C (201 F), product % Aromatics by weight not determined only Melting point unknown ph not applicable % Volatile (by volume) 69.5% Density 0,9 kg/l, product only Flash point 7.8 C (46 F) Weight per volume 7.52 lbs/gal., product only Method PM Closed Cup, product Coefficient (water/oil) not applicable only Viscosity not applicable Vapour density (air=1) > 1 Autoignition temp. unknown Rate of evaporation (ether=1) < 1 Explosion limits not determined Solubility in water Other 10. STABILITY AND REACTIVITY Stability: Hazardous Polymerization: Hazardous Decomposition Products: Conditions to Avoid: Materials to Avoid: Stable Will not occur. Carbon Monoxide, Carbon Dioxide, aldehydes and other toxic fumes. Open flames and red hot surfaces. Strong oxidizers like liquid Chlorine and concentrated Oxygen. 11. TOXICOLOGICAL INFORMATION Primary Route of Exposure Under Inhalation, skin and eye contact. Personnel with pre-existing skin or lung allergies Normal Use: may be aggravated by exposure. Acute Effects: Direct eye contact may cause eye irritation. Vapor may irritate the respiratory tract and cause drowsiness, unconsciousness, headache, dizziness and other central nervous system effects. Substance Test Result Stoddard Solvent LC50 inhalation, rat > 5.5 mg/l/4 h Stoddard Solvent LC50 dermal, rabbit > 3000 mg/kg Stoddard Solvent LD50, oral, rat > 5000 mg/kg Heptane LC50 inhalation, rat 103 mg/l/4 h Heptane LD50 dermal, rabbit 3400 mg/kg Heptane LD50 oral, rat >2000 mg/kg Methanol LC50 inhalation, rat ppm(v)/4 h Methanol LD50 oral, rat 5628 mg/kg Methanol Human lethal dose 143 mg/kg A.W. Chesterton Company, 2007 All Rights Reserved. Reg. US Patent and TM Office Page 3 of 6

4 Chronic Effects: Other Information: Prolonged or repeated skin contact may cause skin irritation and dermatitis. Prolonged, excessive inhalation of Graphite and Mica dust has caused emphysema and pneumoconiosis. The Graphite and Mica in this product are not in powder form and should not present a hazard in normal use. As per 29 CFR (Hazard Communication), this product contains no carcinogens as listed in the National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC) or the Occupational Safety and Health Administration (OSHA). 12. ECOLOGICAL INFORMATION Ecotoxicological data have not been determined specifically for this product. The information given below is based on a knowledge of the components and the ecotoxicology of similar substances. Mobility: Degradability: Accumulation: Ecotoxicity: Liquid. Insoluble in water. In determining environmental mobility, consider the product's physical and chemical properties (see Section 9). The solvents (Stoddard Solvent, Petroleum Gas, Heptane) will rapidly evaporate to the air if released into the environment. In aquatic systems, Heptane may adsorb to organic matter in sediments and suspended solids. Solvents (Stoddard Solvent, Petroleum Gas, Heptane): degradation is expected in the atmospheric environment within days to weeks; may biodegrade. Heptane: may bioaccumulate in fish and aquatic organisms. Petroleum Gas: bioconcentration in aquatic organisms is not expected to be significant. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 13. DISPOSAL CONSIDERATIONS Incinerate absorbed material with a properly licensed facility. Incinerate sealed containers at an appropriate facility. Check local, state and national/federal regulations and comply with the most stringent requirement. EWC-code: TRANSPORT INFORMATION TDG: AEROSOLS, FLAMMABLE, CLASS 2.1, UN1950 IMDG: IATA/ICAO: ADR/RID: *AEROSOLS, CLASS 2, UN1950 *NOTE: Shipped as DANGEROUS GOODS IN LIMITED QUANTITY OF CLASS 2 Ref: IMDG Code Chapter 3.2 Dangerous Goods List for UN1950, Aerosols, column 7 (limited quantities) page 93, special provisions 277 page186 and Chapter 3.4 (Limited quantities) page192 AEROSOLS, FLAMMABLE, CLASS 2.1, UN AEROSOLS, 2, 5F, ADR U.S. DOT : Shipping Name: 1 AEROSOLS, FLAMMABLE Hazard Class: 2.1 UN/NA #: UN1950 Packaging Group #: Not Applicable Emergency Response Guide Book No NOTE: Shipped as Consumer Commodity ORM-D in packaging having a rated capacity gross weight of 66 lb. or less (49 CFR (h)). A.W. Chesterton Company, 2007 All Rights Reserved. Reg. US Patent and TM Office Page 4 of 6

5 15. REGULATORY INFORMATION European Classification¹: F - Highly flammable, N - Dangerous for the environment R-Phrase(s): R67 Vapours may cause drowsiness and dizziness. R66 Repeated exposure may cause skin dryness or cracking. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.* S-Phrase(s): S16 Keep away from sources of ignition - No smoking. S23 Do not breathe vapour/spray. S24 Avoid contact with skin. S51 Use only in well-ventilated areas. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Name of the substances on the label: Other information: Canadian Classification¹: Risk Phrase(s): Precautionary and First Aid Measure(s): Other Information: 16. OTHER INFORMATION Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C (120 F). Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. A: Compressed gases; B5: Flammable aerosols; D2B: Toxic materials causing other effects Flammable aerosol. Vapours may cause drowsiness and dizziness. Repeated exposure may cause skin dryness or cracking. Direct eye contact may cause eye irritation. Keep away from sources of ignition - No smoking. Do not breathe vapour/spray. Wear eye protection. Avoid contact with skin. Use only in well-ventilated areas. If affected by vapour, move to fresh air. In case of contact with eyes, rinse with plenty of water and seek medical advice. After contact with skin, wash with soap and water. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C (120 F). Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. US EPA SARA TITLE III Hazardous Materials Identification System (HMIS) 312 Hazards : 313 Chemicals : 4 = Severe Hazard HEALTH 2 3 = Serious Hazard Immediate Aluminum % 2 = Moderate Hazard FLAMMABILITY 3 Fire 1 = Slight Hazard TSCA: All chemical components are REACTIVITY 1 0 = Minimal Hazard listed * = See Section 8 Pressure Release in the TSCA inventory. Personal Protection * JAPAN PRTR Class I Chemicals : Class II Chemicals : A.W. Chesterton Company, 2007 All Rights Reserved. Reg. US Patent and TM Office Page 5 of 6

6 Risk phrases in section 2: Changes to the MSDS in this revision: R10: Flammable. R11: Highly flammable. R12: Extremely flammable. R15: Contact with water liberates extremely flammable gases. R23/24/25: Toxic by inhalation, in contact with skin and if swallowed. R38: Irritating to skin. R39/23/24/25: Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. R50: Very toxic to aquatic organisms. R53: May cause long-term adverse effects in the aquatic environment. R65: Harmful: may cause lung damage if swallowed. R66: Repeated exposure may cause skin dryness or cracking. R67: Vapours may cause drowsiness and dizziness. sections 2, 3, 8, 11, 12, 15; updated to new format. *R65: not applicable according to criteria This information is based solely on data provided by suppliers of the materials used, not on the mixture itself. No warranty is expressed or implied regarding the accuracy of the data or the suitability of the product for the user s particular purpose. The user must make their own determination as to suitability. A.W. Chesterton Company, 2007 All Rights Reserved. Reg. US Patent and TM Office Page 6 of 6