Micador Stay Anywhere Permanent Pen

Transcription

1 Micador Stay Anywhere Permanent Pen 1. Product Identifier & Identity for the Chemical Product name Micador Stay Anywhere TM Permanent Pen Other name None Product code MAW720 Recommended use Art & craft & Labelling clothing & other articles Restrictions on use Designed for adults and not suitable for use by children Company name Micador Australia Pty Ltd ABN Address 4/132 Bangholme Road, Dandenong South, VIC 3175 Emergency phone (Monday Friday from 9am 5pm) Phone Fax Hazard Identification Classification of the hazardous chemical The pen (where the ink is entirely retained within a porous material in capillary channels of the writing instrument) is non hazardous under normal use and conditions. Do not ingest. Avoid contact with eyes and skin. Do not inhale vapours. The ink in this product is classified as hazardous according to the criteria of NOHSC (National Occupational Health and Safety Council). For the ink: Hazard Classification Xn Harmful F Highly Flammable Risk phrase(s) R10 Flammable R11 Highly flammable R38 Irritating to skin R41 Risk of serious damage to eyes R67 Vapours may cause drowsiness & dizziness R68 Possible risks or irreversible effects Safety phrase(s) S2 Keep out of reach of children S7 Keep container tightly closed S16 Keep away from sources of ignition - No smoking S26 In case of contact with eyes, rinse immediately with plenty of water & seek medical advice Label Elements, including precautionary statements For the pen: Keep out of reach of children. Avoid contact with eyes as risk of serious damage. In case of contact with eyes, rinse immediately with plenty of water & seek medical advice. Avoid contact with skin. Immediately wash with soap and water and rinse thoroughly. Do not inhale vapours as they may cause drowsiness & dizziness. Keep the lid on. The ink is highly flammable, keep away from sources of ignition no smoking. Other Hazards which do not result in classification None Known Safety Data Sheet Page 1 of 6

2 3. Composition/Information on Ingredients Chemical name CAS number Concentration Ethanol % 1 - Methoxy - 2- propanol % Phosphoric acid mono-bis - (2 - ethylhexyl) - ester % C.I. Solvent Black % C.I. Solvent Violet % C.I. Solvent Orange % C.I. Solvent Blue % 4. First Aid Measures Inhalation Skin Eye Ingestion 5. Fire Fighting Measures In case of unconsciousness place patient stably in side position for transportation Immediately wash with water and soap and rinse thoroughly. Immediately rinse with water. Rinse opened eye for several minutes under running water. Then consult a doctor. If symptoms persist consult doctor Suitable extinguishing media CO2, sand, extinguishing powder. Do not use water Specific hazards arising from the chemical For safety reasons water, and water with a full jet are unsuitable extinguishing agents Special protective equipment and precautions for fire fighters No special measures required 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Environment precautions Prevent seepage into sewage system, work pits, and cellars. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers / surface or ground water. Methods and materials for containment and cleaning up Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13 of this safety data sheet. Ensure adequate ventilation. Do not flush with water or aqueous cleansing agents. 7. Handling and Storage Precautions for safe handling Ensure good ventilation / exhaustion at the workplace. Prevent formation of aerosols. Keep ignition sources away - do not smoke. Protect against electrostatic charges. Conditions for safe storage, including any incompatibilities Store in a cool location. Keep container tightly sealed. Store in cool dry conditions in well sealed receptacles. Safety Data Sheet Page 2 of 6

3 8. Exposure Controls/Personal Protection Control parameters exposure standards, biological monitoring Ingredients with limit values that require monitoring in the workplace: Methoxy - 2- propanol (10-25%) Short-tern value: 568 mg/m 3, 150ppm IOELV Long-term value: 375 mg/m 3, 100ppm Skin Appropriate engineering control None Known Personal protective equipment (PPE) General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the skin. Avoid contact with eyes and skin. Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self contained respiratory protective device. Protection of hands: Use protective gloves. The glove material has to be impermeable and resistant to the product / the substance / the preparation. Due to missing tests no recommendation to the glove material can be given for the product / the preparation / the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. Material of gloves: The selection of suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material: The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Wear tightly sealed goggles. Safety Data Sheet Page 3 of 6

4 9. Physical and Chemical Properties Appearance Black Fluid Odour Characteristic Odour threshold ph 5 at 20% Melting point/freezing point Boiling point and boiling range 78 o C Flash point 13 o C Evaporation rate Flammability High Upper/lower flammability or explosive limits 1.7 Vol % - Lower 15.0 Vol% - Upper Danger of explosion Product is not explosive. However, formation of explosive air/vapour mixtures are possible Vapour pressure 59hPa Vapour density Relative density Solubility (ies) Not miscible or difficult to mix Partition coefficient: n-octanol/water Auto-ignition temperature Product is not self igniting Decomposition temperature Viscosity 40mPas (Dynamic at 20 o c) Specific heat value Particle size Volatile organic compounds content % volatile Saturated vapour concentration Release of invisible flammable vapours and gases Additional parameters Shape and aspect ratio Crystallinity Dustiness Surface area Degree of aggregation or agglomeration Ionisation (redox potential) Biodurability or biopersistence 10. Stability and reactivity Reactivity Chemical stability Conditions to avoid Incompatible materials and possible hazardous reactions Hazardous decomposition products No decomposition if used according to specifications No dangerous reactions known No dangerous decomposition products known Safety Data Sheet Page 4 of 6

5 11. Toxicological information Potential adverse health effects and symptoms associated with exposure to the material Acute health effect Acute Toxicity: LD/LC50 values relevant for classification C. I Solvent Violet 8 Oral LD50 700mg/kg (rat) Primary irritant effects: Swallowed listed above Eyes Strong irritant with the danger of severe eye injury Skin Irritant to skin and mucous membranes Inhaled Sensitisation No sensitizing effects known This product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Irritant. Chronic health effect 12. Ecological information Ecotoxicology Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects Toxic for fish Water hazard class 3 (German Regulation) (Self assessment): extremely hazardous for water. Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms 13. Disposal considerations Safe handling and disposal methods Disposal of any contaminated packaging Environmental regulations Must not be disposed together with household garbage. Do not allow product to reach sewage system. Disposal must be made according to official regulations European waste catalogue: Wastes from the manufacture, formulation, supply and use (MFSU) of coatings (pains, varnishes, and vitreous enamels), adhesives, sealants, and printing inks Wastes from MFSU and removal of paint and varnish * Sludges from paint or varnish containing organic solvents or other dangerous substances Safety Data Sheet Page 5 of 6

6 14. Transport information UN number Proper shipping name Transport hazard class(es) Packing group Environmental hazard Special precautions during transport Hazchem code 15. Regulatory information Safety, health environmental regulations specific for the product in question This product is classified as hazardous according to the criteria of NOHSC (National Occupational Health and Safety Council). Poisons schedule number 16. Other information Date of preparation or review 15th April 2010 Key abbreviation or acronyms used N/A Revision number 1 Name of version that this document supersedes N/A Safety Data Sheet Page 6 of 6