UNIOLEO FA C1214 Material Safety Data Sheet

Transcription

1 UNIOLEO FA C1214 Material Safety Data Sheet Issuance Date: - Revision Date: Nov-15 Version: 1511/1501 SECTION 1 : PRODUCT AND COMPANY IDENTIFICATION 1.1 PRODUCT IDENTIFIER Product Name: Product Description: CAS Number: Formula: UNIOLEO FA C1214 Lauric Myristic Acid , C 12H 24O 2 - C 14H 28O INTENDED USE OF THE PRODUCT Use of the Product: Intended for food industry. Production of textile, specialty soap. Intermediate. 1.3 SUPPLIER DETAIL Manufacturer: Address: PT Unilever Oleochemical Indonesia Industrial Estate of Sei Mangkei Huta VI Sei Mangkei Bosar Maligas, Simalungun North Sumatra Indonesia 1.4 EMERGENCY CONTACT Emergency Telephone: Quality Department: Tel SECTION 2 : HAZARD IDENTIFICATION 2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE Classification according to Regulation (EC) No 1272/2008 Acute toxicity: Skin Irritation/Corrosion: Eye Irritation: Acute aquatic toxicity: Chronic aquatic toxicity: LD50 oral (Rat) : Category 5, H303 LD50 skin (Rabbit) : Category 5, H313 LC50 inhalation (Rat) : Category 1, H330 Not irritating to skin. Category 2B, H320 Category 2, H401 Category 3, H402

2 SECTION 2 : HAZARD IDENTIFICATION contd. 2.2 LABEL ELEMENT Pictogram: Signal word: Hazard statement(s): H303: H313: H330: H320: H401: H402: Precautionary statement(s) P312: P260: P271: P284: P304 + P340: P310: P320: P403+P233: P4005: P501: Danger May be harmful if swallowed. May be harmful in contact with skin. Fatal if inhaled. Cause eye irritation. Toxic to aquatic life. Harmful to aquatic life. Call a poison center/doctor if you feel unwell. Do not breathe dust/fume/gas/mist/vapours/spray. Use only outdoors or in well-ventilated area. In case of inadequate ventilation-wear respiratory protection. If inhaled : Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. Specified treatment is urgent. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/container to an approved waste disposal plant in accordance with the regulations. 2.3 OTHER HAZARDS None. SECTION 3 : COMPOSITION/INFORMATION OF INGREDIENTS 3.1 COMPONENT Synonyms: Formula: Composition: Molecul weight: CAS No: EC No: Fatty Acid, C1214/Lauric-Myristic Acid/Dodecanoic-Tetradecanoic Acid C 12H 24O 2 - C 14H 28O 2 C 12H 24O 2 : 74-76%; C 14H 28O 2 : 23-26% g/mol; g/mol , ,

3 SECTION 4 : FIRST AID MEASURES 4.1 DESCRIPTION OF FIRST AID MEASURES General Advice: Inhalation: Skin contact: Eye contact: Ingestion: Consult a physician. Show this safety data sheet to doctor in attendance. Sore throat, cough. Remove to fresh air. If suffocation is serious, take to doctor. Remove contaminated clothing, flush skin with water or shower. Take to doctor. Immediately flush eyes with plenty of water, occasionally lifting the upper and eyelids. Check for and remove any contact lenses, continue to rinse for at least 10 minute. Wash out mouth with water, if material has been swallowed and the exposed person is conscious, give small quantities of water to drink. 4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED The most important known symptoms and effects are described in the labelling and or section INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED SECTION 5 : FIREFIGHTING MEASURES 5.1 EXTINGUISHING MEDIA Suitable extinguishing media: Use water spray (fog), foam,dry chemical or CO 2 Unsuitable extinguishing media: Water jet. 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE Fire Hazard: Combustible, keep away from open flame, no smoking. 5.3 ADVICE FOR FIREFIGHTERS Use self-contained breathing equipment if in confined place. SECTION 6 : ACCIDENTAL RELEASE MEASURES 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES Avoid contact with skin and eyes. Put on appropriate personal protective equipment see section 8.

4 6.2 ENVIRONMENTAL PRECAUTIONS Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. 6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP Collect leakage in sealable containers, soak up with sand or other inert absorbent and remove to safe place. Wash site with sodium bicarbonate solution or soda ash. Can also allow spillage to solidity, the shovel into containers. Clean up around immediately. SECTION 7 : HANDLING AND STORAGE 7.1 PRECAUTIONS FOR SAFE HANDLING Handle with care and dispose in a safe manner. Use gloves and wear googles when handling. 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES Keep in a cool and dry place, avoid extreme heat and cold. Store in clean, dry preferably stainless steel vessels. Storage temperature: In flake, store at maximum 35 C Suitable material for storage: In bulk, store at about 10 C above melting point or ambient. Temperature higher than necessary degrades quality at rates dependent on time and temperature of exposure. Exposure to ultraviolet light and sunlight must be minimized to prevent quality loss. SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 CONTROL PARAMETERS No occupational Exposure Limits (OELs) have been establish for this product or its chemical components. 8.2 EXPOSURE CONTROLS Appropriate engineering controls: Emergency eye wash should be available in the immediate vicinity or any potential exposure Personal Protective Equipment: Safety glasses Dust formation: dust mask Hand gloves Eye/Face protection: Skin protection: Respiratory protection Other Information: Safety glasses or chemical goggles. Chemically resistant protective gloves are recommended. In case of inadequate ventilation wear respiratory protection. When using, do not eat, drink or smoke.

5 SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES 9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES Physical state: Appearance: Odour: Odour Threshold: ph: Melting point: Freezing point: Boiling point: Flash point: Evaporation rate: Flammability (solid, gas): Upper/lower flammability or explosive limits: Vapour pressure: Vapour density: Relative density: Water solubility: Partition coefficient : n-octanol/water: Auto-ignition temperature: Decomposition temperature: Solid. White Crystalline. Mild Odour C C C at 760 mmhg > 100 C mmhg (at 25 C) g/cm 3 (at 75 C) 113 mg/l at 25 C log Pow 3.3 at 23 C > 250 C SECTION 10 : STABILITY AND REACTIVITY 10.1 REACTIVITY 10.2 CHEMICAL STABILITY 10.3 POSSIBILITY OF HAZARDOUS REACTIONS 10.4 CONDITION TO AVOID 10.5 INCOMPATIBLE MATERIAL 10.6 HAZARDOUS DECOMPOSITION PRODUCTS Stable under recommended storage conditions. Bases, Oxidizing agents. In event of fire : see section 5.

6 SECTION 11 : TOXICOLOGICAL INFORMATION 11.1 INFORMATION ON TOXICOLOGICAL EFFECTS Acute toxicity: LD50 Oral-Rat LD50 Dermal-Rabbit LC50 Inhalation-Rat Skin corrosion/irritation: Serious eye damage/eye irritation: Respiratory or skin sensitization: Germ cell mutagenicity: Carcinogenicity: Reproductive toxicity: Specific target organ toxicity= single exposure: Specific target organ toxicity= repeat exposure: Aspiration hazard: Additional Information: > mg/kg > 2000 mg/kg > mg/l vapour (nominal), duration : 4 hours, vapour. No skin irritation-72 hours (Rabbit). Cause eye irritation-21 days (Rabbit). No sensitising (Guinea Pig). RTECS : OE SECTION 12 : ECOLOGICAL INFORMATION 12.1 TOXICITY LC50 Fish: EC50 Invertebrata: EC50 Algae: 3.2 mg/l (exposure time : 96 h, Species : Oryzias latipes, semi-static test) 3.6 mg/l (exposure time : 48 h, Species : Dapnia magna, semi-static test) 7,6 mg/l (exposure time : 72 h, Species : Pseudokirchnerella subcapitata, static test) 12.2 PERSISTANCE AND DEGRADABILITY Biodegradability: 75 % readily biodegradable (exposure time : 28 day) BIOACCUMULATIVE POTENTIAL Bio-accumulative Potential: 20 mg/l to whole body w.w MOBILITY IN SOIL 12.5 OTHER ADVERSE EFFECTS Toxic to aquatic life. Avoid release to the environment.

7 SECTION 13 : DISPOSAL CONSIDERATIONS 13.1 WASTE TREATMENT METHODS Waste disposal recommendation: Disposal must be made according to official regulation. Do not dump into any sewers, on the ground, or into any body of water. SECTION 14 : TRANSPORTATION INFORMATION 14.1 UN NUMBER Not regulated. Not regulated. Not regulated UN PROPER SHIPPING NAME 14.3 TRANSPORT HAZARD CLASS(ES) 14.4 PACKAGING GROUP) 14.5 ENVIRONMENTAL HAZARDS No No No 14.6 SPECIAL PRECAUTIONS FOR USE

8 SECTION 15 : REGULATORY INFORMATION INVENTORY STATUS Listed on NZIoC, TSCA, DSL, EINECS. SECTION 16 : OTHER INFORMATION MSDS updated on: MSDS creation date: MSDS No: Nov-15 1-Jan-15: UOI-MSDS-QA-009