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1 SAFETY DATA SHEET Page 1 / 7 1. IDTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Commercial Product Name Product code (ID 10752) Relevant identified uses of the substance or mixture and uses advised against Recommended use Car chemical: detergent 1.3 Details of the supplier of the safety data sheet Supplier Neste Markkinointi Oy Street address Keilaranta 21 Postcode and post office Espoo FINLAND P.O.Box P.O.B. 95 Postcode and post office FIN NESTE OIL FINLAND Telephone Telefax Business ID lubetec@nesteoil.com 1.4 Emergency telephone number Telephone number, name and address , , Poison Information Centre/HUS P.O.B 340 (Tukholmankatu 17) HUS (Helsinki, Finland) 2. HAZARDS IDTIFICATION 2.1 Classification of the substance or mixture 1272/2008 (CLP) Eye Dam. 1, H318 Skin Irrit. 2, H Label elements Contains: Hexyl D-glucoside, 2-Propylheptanolethoxylate, Disodiummetasilicate 1272/2008 (CLP) GHS05 Signal word Danger Hazard Statements H318 Causes serious eye damage. H315 Causes skin irritation. Precautionary Statements P102 Keep out of reach of children. P264 Pese kädet huolellisesti käsittelyn jälkeen. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CTER or doctor/physician. 2.3 Other hazards
2 SAFETY DATA SHEET Page 2 / 7 3. COMPOSITION/INFORMATION ON INGREDITS 3.2 Mixtures Hazardous components CAS number Chemical name of the substance Concentration Classification Hexyl D-glucoside < 5 % Eye Dam. 1; H Other information H- and R-phrase(s), See chapter FIRST AID MEASURES 4.1 Description of first aid measures 2-Propylheptanolethoxylate, 1- Heptanol, 2-propyl-, 7EO < 3 % Eye Dam. 1; H318 Tetrapotassium pyrophosphate < 10 % Eye Irrit. 2; H319 Disodiummetasilicate < 2 % Skin. Corr. 1B; H314 Eye Dam. 1; H318 STOT SE 3; H335 Met. Corr. 1, H Inhalation Move to fresh air. If symptoms persist, call a physician Skin contact Wash off with warm water and soap. If symptoms persist, call a physician Eye contact Rinse immediately with plenty of water, also under the eyelids. Continue irrigation until medical (ophthalmological) attention is obtained Ingestion If product is swallowed, give water to drink and consult a physician. 4.2 Most important symptoms and effects, both acute and delayed Eye irritation/ Redness 4.3 Indication of immediate medical attention and special treatment needed Treat symptomatically. 5. FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide Extinguishing media which must not be used for safety reasons 5.2 Special hazards arising from the substance or mixture 5.3 Advice for firefighters Self-contained breathing apparatus and full protective clothing.
3 SAFETY DATA SHEET Page 3 / Specific methods Do not allow run-off from fire fighting to enter drains or water courses. 6. ACCIDTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Provide adequate ventilation. 6.2 Environmental precautions Should not be released into the environment. 6.3 Methods and materials for containment and cleaning up Small amounts can be collected using non-combustible absorbent material. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For personal protection see section 8. Disposal considerations (item 13). 7. HANDLING AND STORAGE 7.1 Precautions for safe handling Avoid contact with skin and eyes. 7.2 Conditions for safe storage, including any incompatibilities Storage temperature: Temperatures above C. Do not freeze. 7.3 Specific end use(s) detergent 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters No limit values Other information on limit values Limit values in other countries DNELs PNECs 8.2 Exposure controls Appropriate engineering controls Provide sufficient air exchange and/or exhaust in work rooms. Ensure that eyewash stations and safety showers are close to the workstation location Individual protection measures Respiratory protection In the case of vapour formation use a respirator with an approved filter Hand protection Protective gloves: Neoprene, nitrile rubber. Change protective gloves regularly Eye/face protection Tightly fitting safety goggles..
4 SAFETY DATA SHEET Page 4 / Skin protection Protective clothing when needed Environmental exposure controls Take precautions against leakage by constructing collecting pools and sewerage systems as well as by surfacing the loading and unloading stations. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance Liquid, clear, light yellow Odour Odour threshold ph approx Melting point/freezing point approx. 0 C Initial boiling point and boiling range approx. 100 C Flash point Evaporation rate Flammability (solid, gas) Explosive properties Lower explosion limit Upper explosion limit Vapour pressure Vapour density Relative density 1, Solubility(ies) Water solubility completely soluble Fat solubility (solvent /oil to be specified) Partition coefficient: n-octanol/water log Pow 1,72-1,77 (Hexyl D-glucoside ) Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidising properties 9.2 Other information 10. STABILITY AND REACTIVITY 10.1 Reactivity Stable under normal conditions Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions No dangerous reaction known under conditions of normal use Conditions to avoid Protect from frost.
5 SAFETY DATA SHEET Page 5 / Incompatible materials Incompatible with strong acids and bases Hazardous decomposition products None known. 11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute toxicity 2-Propylheptanolethoxylate: LD50/oral/rat: > mg/kg, Inhalation: LC50: > 20 mg/l. Dermal: LD50: > mg/kg Disodium metasilicate: LD50/oral/rat: mg/kg. Inhalation: LC50: > 2,06 mg/l. Dermal: LD50: > 5000 mg/kg Tetrapotassium pyrophosphate : LD50/oral/rat: > 2000 mg/kg. Dermal: LD50 > 7940 mg/kg Irritation and corrosion Severe eye irritation Irritating to skin. May cause respiratory tract irritation Sensitisation Non-sensitizing (estimate) Subacute, subchronic and prolonged toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard No aspiration toxicity classification Other information on acute toxicity 12. ECOLOGICAL INFORMATION 12.1 Toxicity Aquatic toxicity
6 SAFETY DATA SHEET Page 6 / 7 Hexyl D-glucoside: LC50 > 100 mg/l, 96 h, Oncorhynchus mykiss ( fish) EC50 > 100 mg/l, 48 h, Daphnia magna (Water flea) EC50 > 100 mg/l, 72 h, Scenedesmus quadricauda (Green algae) EC50 > 1000 mg/l, 4 h, Bacteria 2-Propylheptanolethoxylate: LC50 > mg/l, 96 h, fish EC50 > mg/l, 48 h, Daphnia magna (Water flea) EC50 > mg/l, 72 h, alga Disodium metasilicate: LC mg/l, 96 h, Brachydanio rerio (fish) EC mg/l, 48 h, Daphnia magna (Water flea) Tetrapotassium pyrophosphate: LC50 > 750 mg/l (Leuciscus idus) LC50 > 100 mg/l, 48 h, Daphnia magna LC50 > 100 mg/l, 96 h, Onchorhynchus mykiss 12.2 Persistence and degradability Biodegradation Readily biodegradable. Hexyl D-glucoside: > 70 %, Closed Bottle Test (OECD 301D). 2-Propylheptanolethoxylate: > 60 %, Closed Bottle Test (OECD 301D) Chemical degradation 12.3 Bioaccumulative potential Not accumulative. Soluble in water. Readily biodegradable Mobility in soil Soluble in water Results of PBT and vpvb assessment This preparation contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This preparation contains no substance considered to be very persistent nor very bioaccumulating (vpvb) Other adverse effects 13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Product waste should be treated according to national regulations and local authorities advice Waste from residues / unused products Empty containers should be taken for local recycling or waste disposal. 14. TRANSPORT INFORMATION 14.1 UN number Not dangerous goods in the meaning of ADR/RID, ADNR, IMDG-Code, ICAO/IATA-DGR 14.2 UN proper shipping name Not relevant 14.3 Transport hazard class(es) Not relevant
7 SAFETY DATA SHEET Page 7 / Packing group Not relevant 14.5 Environmental hazards not hazardous 14.6 Special precautions for users Not relevant 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not relevant 15. REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety datasheet complies with the requirements of Regulation (EC) No. 1907/ Chemical safety assessment There is for this product. 16. OTHER INFORMATION 16.1 Additions, Deletions, Revisions Updated according to regulation (EU) N:o 453/2010 amending regulation (EC) N:o 1907/2006 (REACH). CLPclassification Key literature references and sources for data Regulations, databases, literature, own research List of relevant R phrases, hazard statements, safety phrases and/or precautionary statements H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H319 Causes serious eye irritation. H335 May cause respiratory irritation Recommended restrictions Car chemical detergent 16.8 Further information Neste Markkinointi Oy/Lubrication, product information, tel (0) , lubetec@nesteoil.com
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