Zeoflair 100. Silicic acid, aluminum sodium salt. Aluminium silicate. Hazards identification May cause sensitization by inhalation and skin contact.

Transcription

1 33570 Page 1 of 5 Company Zeochem AG, CH8707 Uetikon / Switzerland Telefon , Fax Commercial product name and supplier 1.1 Commercial product name / designation applies to the following products: Zeoflair 200; Zeoflair Synonym Molecular formula 1.2 Application / use 1.3 TOX emergency number 1.4 CAS No. CAS Name 1.5 EINECSNo. 1.6 Product No. Na 2 O * Al 2 O 3 * y SiO 2 * z H 2 O Additive for polymers +41 (0) (Toxicological Information Centre, CH8032 Zurich) Silicic acid, aluminum sodium salt Composition 2.1 Chemical characterisation Aluminium silicate 2.2 Hazardous components Does not contain any dangerous substances according to the criteria of the EC (Council Directive 88/379/EEC) Hazards identification May cause sensitization by inhalation and skin contact. 4 First aid measures 4.1 Eye contact Flush copiously with water for at least 15 minutes whilst keeping the eyes wide open. 4.2 Skin contact Wash thoroughly with soap and water Ingestion Inhalation Drink a lot of water if large amounts are ingested. Do not induce vomiting. Call a physician and/or transport to emergency facility immediately. Move to fresh air. The used product can obtain materials of a hazardous nature. Identify that material and treat symptomatically.

2 33570 Page 2 of Firefighting measures Suitable extinguishing media Extinguishing media to avoid Personal protecive equipment ERICards Adapt the fire extinguisher on the neighborhood. Water 5.5 Non inflammable product. 6 Accidental release measures Minimise dust generation while collecting the spill. 7 Handling and storage 7.1 Handling No specific requirements. Advise water authority if spillage has entered water course or drainage system. 7.2 Industrial hygiene Avoid breathing dust. Avoid eye and skin contact. Avoid eating, drinking and storage of foodstuffs in the working room. 7.3 Storage Ensure lids are resealed after use. Shelf life: unlimited in a closed container Place of storage Fire and explosion protection Dry place Take precautions to avoid accumulation of static charge. 8 Exposure controls / personal protection 8.1 Technical measures 8.2 Control of threshold limits 8.3 MAK value 8.4 Personal protective equipment Respiratory protection Hand protection Provide general and/or local exhaust ventilation to control airborne levels below the exposure guidelines. TLVTWA: 10mg/m 3 (PNOC) OES (UK): 10mg/m 3 total dust 4mg/m 3 resp. dust 6 mg/m3 dust mask protective gloves Eye protection Other Safety glasses. 9 Physical and chemical properties 9.1 Appearance 9.2 Color powder offwhite 9.3 Odour odorless 9.4 Change of physical state Test method:

3 33570 Page 3 of Density bulk density (tapped) 9.6 Vapour pressure n.a. 9.7 Viscosity n.a kg/m³ 9.8 Solubility in water (20 C) insoluble 9.9 ph ISO Flash point 9.11 Ignition temperature 9.12 Explosion limits Lower: Upper: Stability and reactivity 10.1 Materials to avoid 10.2 Conditions to avoid Stability noninflammable noninflammable vol.% vol.% Particle Size: 4 µm The product is stable Hazardous decomposition None under standard conditions. products 10.4 On unloading used sieve, beware of any impurities and their dangers. 11 Toxicological information 11.1 Acute toxicity Irritation / Cauterization 11.2 Subacute / chronic toxicity Ecological information The oral LD50 for rats is > 10'000mg/kg. The LD50 for skin absorption in rabbits is > 2000mg/kg. The LC50 for inhalation in rats is > 18.3mg/L. Short single exposure is not likely to cause skin irritation. May cause slight eye irritation. Eyes The product is an adsorbent. Contact with the skin will dry it out. If the MAKvalue (6 mg/m 3 as fine dust) is exceeded, then an overloading of the respiratory tract is likely. Category of water hazard CH D Toxicity to daphnia Toxicity to fish Biodegradability Indication of danger EC50 48h: mg/l LC50 96h: mg/l n.a. The product is practically insoluble so it is possible to separate by filtration or sedimentation 0

4 33570 Page 4 of Disposal considerations EC waste key 13.2 Swiss waste code 13.3 Origin The used product will have properties other than that of the fresh product. This Safety Datasheet can not give details about the used product, which should be disposed of in an approved waste disposal site in accordance with the local rules and regluations. This code depends on the industrial application for the product, and must therefore be determined by the user himself. We will be pleased to assist our customers in respect of this Transport information Dangerous Good yes no X Transport at land: RID / ADR Warning label Packing group Overland statement Transport at sea: IMDG Subsidiary Risk EMS Proper Shipping Name Air transport: ICAO / IATADGR ification code Hazard id. no. Subsidiary Risk Hazard Label(s) Packing Group Passenger Aircraft Cargo Aircraft only Packing Instruction Packing Instruction max. max Product is not classified for any mode of transportation. 15 Regulatory information Swiss toxicity class BAG T Nr. / EDVNo IndexNo Hazard symbols This product does not require classification according to the criteria of the EC and the 'Gefahrstoffverordnung' Hazard designation 15.5 Risk phrases R:

5 33570 Page 5 of Safety phrases S: CEA classification VbF (D) F6 s PN4 Non inflammable USA (TSCA) listed CAS No.: Canada (DSL) listed CAS No.: Australia (AICS) listed CAS No.: Japan (ENCS) Korea (ECL) 16 Other information Abbreviations: n.a. = not applicable; n.d. = not determined; n.cl. = not classified. The above mentioned data correspond to our present state of knowledge and experience. The safety data sheet serves as description of the products in regard to necessary safety measures. The indications do not imply any guarantee of a property. Alle vorstehenden Angaben entsprechen dem heutigen Stand unserer Kenntnisse und Erfahrungen. Das Sicherheitsdatenblatt dient der Beschreibung der Produkte im Hinblick auf Sicherheitserfordernisse. Diese Angaben stellen keine Zusicherungen von Eigenschaften dar. This safety data sheet has been generated with the safety database 'ChemManager', ASSiST, Weiherweg 3, CH4104 Oberwil, Switzerland 91/155/EEC