MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product identifier Version # 01 Issue date CAS # Part Number Product use Manufacturer information Supplier LPS Precision Clean (Aerosol) Mixture 02720, C02720 An industrial cleaner designed to remove grime, oils and light grease from metal, concrete and other durable surfaces. ITW Pro Brands 4647 Hugh Howell Rd Tucker, GA United States lpssds@itwprobrands.com / Chemtrec Hazards Identification Emergency overview Potential health effects Routes of exposure Eyes Skin Inhalation Ingestion Signs and symptoms Potential environmental effects WARNING Causes skin and eye irritation. Eye contact. Skin contact. Inhalation. Ingestion. Avoid contact with eyes. May irritate eyes. Avoid contact with the skin. May cause skin irritation. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Do not breathe dust/fume/gas/mist/vapors/spray. May cause irritation of respiratory tract. Do not ingest. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Irritant effects. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Ecological injuries are not known or expected under normal use. 3. Composition / Information on Ingredients Non-hazardous components CAS # Percent Petroleum Gases, Liquified, Sweetened First Aid Measures First aid procedures Inhalation Skin contact Eye contact Ingestion Notes to physician General advice 5. Fire Fighting Measures Flammable properties Move to fresh air. Call a physician if symptoms develop or persist. Wash off with soap and water. Get medical attention if irritation develops and persists. Rinse with water. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur. In case of shortness of breath, give oxygen. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Heat may cause the containers to explode. 1 / 6

2 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Fire fighting equipment/instructions Specific methods Explosion data Sensitivity to static discharge Sensitivity to mechanical impact Hazardous combustion products General fire hazards Dry chemical powder. Carbon dioxide (CO2). Water spray, fog or regular foam. None known. Pressurized container may explode when exposed to heat or flame. Firefighters should wear full protective clothing including self contained breathing apparatus. Structural firefighters protective clothing will only provide limited protection. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire involving Tanks: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not direct water at source of leak or safety devices as icing may occur. Containers should be cooled with water to prevent vapor pressure build up. Some of these materials, if spilled, may evaporate leaving a flammable residue. Cool containers exposed to flames with water until well after the fire is out. Yes None known. May include oxides of carbon. None known. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection, see section 8 of the MSDS. Do not contaminate water. Stop leak if you can do so without risk. Dike the spilled material, where this is possible. Prevent entry into waterways, sewer, basements or confined areas. Should not be released into the environment. This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Other information 7. Handling and Storage Handling Storage Never return spills to original containers for re-use. Clean up in accordance with all applicable regulations. For waste disposal, see section 13 of the MSDS. Clean up in accordance with all applicable regulations. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get this material in contact with eyes. Do not get this material in contact with skin. Do not get this material on clothing. Do not use in areas without adequate ventilation. Wash thoroughly after handling. Contents under pressure. Do not expose to heat or store at temperatures above 120 F/49 C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a closed container away from incompatible materials. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the MSDS). Keep out of the reach of children. Keep in an area equipped with sprinklers. 2 / 6

3 8. Exposure Controls / Personal Protection Occupational exposure limits Biological limit values Engineering controls Personal protective equipment Eye/face protection No exposure limits noted for ingredient(s). No biological exposure limits noted for the ingredient(s). Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Ensure adequate ventilation, especially in confined areas. Wear safety glasses with side shields (or goggles). Eye wash fountain is recommended. Skin protection Respiratory protection Hand protection Wear suitable protective clothing. Wear protective gloves. Use a positive-pressure air-supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air-purifying respirators may not provide adequate protection. Wear protective gloves. 9. Physical & Chemical Properties Appearance Odor Physical state Form Color Odor threshold Gas. Aerosol. Compressed gas. Greenish-blue. Citrus ph 12.9 Vapor pressure Vapor density > 1 Boiling point Melting point/freezing point Solubility (water) < 17.5 mm C 212 F (100 C) 100 % (in water) Specific gravity 20 C Relative density Flash point Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Auto-ignition temperature VOC Evaporation rate Viscosity Viscosity temperature Not Established Not Established Not Established 5.8 % per U.S. State and Federal Consumer Product Regulations 1 BuAc < 3 cst 77 F (25 C) Percent volatile > 97 % Partition coefficient (n-octanol/water) Other data Heat of combustion < 20 kj/g 10. Chemical Stability & Reactivity Information Reactivity Chemical stability Conditions to avoid Incompatible materials This product may react with oxidizing agents. Reacts violently with strong acids. Material is stable under normal conditions. Avoid heat, sparks, open flames and other ignition sources. Strong oxidizing agents. Acids. 3 / 6

4 Hazardous decomposition products Possibility of hazardous reactions Carbon oxides. Hazardous polymerization does not occur. 11. Toxicological Information Toxicological data Components Species Petroleum Gases, Liquified, Sweetened (CAS ) Acute Inhalation LC50 Mouse Rat Test Results 1237 mg/l, 120 Minutes 52 %, 120 Minutes 1355 mg/l Acute effects Sensitization Local effects Chronic effects Carcinogenicity Skin corrosion/irritation Serious eye damage/irritation Mutagenicity Reproductive effects Teratogenicity Synergistic materials Not expected to be acutely toxic. Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Prolonged or repeated contact may cause drying, cracking, or irritation. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Causes skin irritation. Causes serious eye irritation. No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. This product is not expected to cause reproductive or developmental effects. No data available for this product. No data available for this product. 12. Ecological Information Ecotoxicological data Ecotoxicity Environmental effects Aquatic toxicity Persistence and degradability Mobility in environmental media 13. Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging No ecotoxicity data noted for the ingredient(s). Contains a substance which causes risk of hazardous effects to the environment. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Expected to biodegrade. This product is miscible in water. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Dispose in accordance with all applicable regulations. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport Information TDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk UN1950 AEROSOLS, non-flammable - 4 / 6

5 Packing group Environmental hazards Special precautions for user IATA Not applicable. Read safety instructions, MSDS and emergency procedures before handling. UN number UN1950 UN proper shipping name AEROSOLS, non-flammable Transport hazard class(es) Class Subsidiary risk - Label(s) Packing group Not applicable. Environmental hazards No. Special precautions for user Read safety instructions, MSDS and emergency procedures before handling. Other information Passenger and cargo Allowed. aircraft Cargo aircraft only Allowed. IMDG UN number UN1950 UN proper shipping name AEROSOLS, non-flammable Transport hazard class(es) Class Subsidiary risk - Label(s) Packing group Not applicable. Environmental hazards Marine pollutant No. EmS F-D, S-U Special precautions for user Read safety instructions, MSDS and emergency procedures before handling. IATA; IMDG; TDG 15. Regulatory Information Canadian regulations WHMIS status WHMIS classification WHMIS labeling This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. Controlled A - Compressed Gas D2B - Other Toxic Effects-TOXIC 16. Other Information 5 / 6

6 Disclaimer Prepared by This data sheet contains changes from the previous version in section(s): The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Product and Company Identification: Product and Company Identification Hazards Identification: Emergency overview Composition / Information on Ingredients: Disclosure Overrides Physical & Chemical Properties: Multiple Properties Toxicological Information: Acute effects 6 / 6