MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product identifier Version # 02 LPS 2 (Aerosol) Issue date Revision date Supersedes date CAS # Part Number Product use Manufacturer information Supplier Mixture C30216 An industrial lubricant designed to displace moisture from equipment, provide heavy-duty lubrication and rust prevention. LPS Laboratories, a division of Illinois Tool Works, Inc Hugh Howell Rd Tucker, Georgia United States / Chemtrec Hazards Identification Emergency overview DANGER CONTENTS UNDER PRESSURE. Flammable aerosol. Pressurized container may explode when exposed to heat or flame. Potential health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Signs and symptoms Potential environmental effects Irritating to eyes and skin. Vapors may cause drowsiness and dizziness. Eye contact. Skin contact. Inhalation. Ingestion. Contact with eyes may cause irritation. Avoid contact with eyes. May cause skin irritation. Avoid contact with the skin. Avoid breathing dust/fume/gas/mist/vapors/spray. Prolonged inhalation may be harmful. May cause irritation of respiratory tract. Exposure by ingestion of an aerosol is unlikely. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Harmful: may cause lung damage if swallowed. Do not ingest. Eyes. Skin. Central nervous system. Respiratory system. Causes serious eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Drowsiness and dizziness. Narcosis. Decrease in motor functions. Behavioral changes. Ecological injuries are not known or expected under normal use. 3. Composition / Information on Ingredients Hazardous components CAS # Percent CARBON DIOXIDE n-hazardous components CAS # Percent Distillates Petroleum, Hydroteated Light Petroleum Oil / 7

2 4. First Aid Measures First aid procedures Inhalation Skin contact Eye contact Ingestion tes to physician General advice 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Fire fighting equipment/instructions Specific methods Explosion data Sensitivity to static discharge Sensitivity to mechanical impact Hazardous combustion products Remove victim to fresh air and keep at rest in a position comfortable for breathing. For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop or persist. Wash off with soap and water. Get medical attention if irritation develops and persists. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Call a physician or poison control center immediately. Only induce vomiting at the instruction of medical personnel. Never give anything by mouth to an unconscious person. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Provide general supportive measures and treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Call a POISON CENTER or doctor/physician if you feel unwell. Flammable by WHMIS criteria. Heat may cause the containers to explode. Ruptured cylinders may rocket. Powder. Alcohol resistant foam. Water. Water spray. Dry chemicals. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. Contents under pressure. Pressurized container may explode when exposed to heat or flame. Fire may produce irritating, corrosive and/or toxic gases. Firefighters should wear full protective clothing including self contained breathing apparatus. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Cool containers exposed to flames with water until well after the fire is out. ne known. May include oxides of carbon. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Other information Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. For personal protection, see section 8 of the MSDS. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Use water spray to reduce vapors or divert vapor cloud drift. Keep out of low areas. Prevent entry into waterways, sewer, basements or confined areas. Should not be released into the environment. Stop the flow of material, if this is without risk. Isolate area until gas has dispersed. Following product recovery, flush area with water. Clean up in accordance with all applicable regulations. For waste disposal, see section 13 of the MSDS. Clean up in accordance with all applicable regulations. 2 / 7

3 7. Handling and Storage Handling Storage Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get this material in contact with eyes. Do not get this material in contact with skin. Avoid prolonged or repeated contact with skin. Avoid prolonged exposure. Do not get this material on clothing. Do not use in areas without adequate ventilation. Wear positive pressure self-contained breathing apparatus (SCBA). Wear personal protective equipment. Wash thoroughly after handling. Avoid release to the environment. Contents under pressure. The pressure in sealed containers can increase under the influence of heat. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a closed container away from incompatible materials. Store in a well-ventilated place. Keep container dry. Store away from incompatible materials (see Section 10 of the MSDS). Keep out of the reach of children. 8. Exposure Controls / Personal Protection Occupational exposure limits ACGIH Form Petroleum Oil (CAS ) US. ACGIH Threshold Limit s 5 mg/m3 Oil mist Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) mg/m mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) 1 Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act) Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) mg/m3 3 / 7

4 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) 9000 mg/m3 U.S. - OSHA Form Petroleum Oil (CAS ) PEL 5 mg/m3 Oil mist US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Biological limit values Engineering controls Personal protective equipment Eye/face protection Skin protection Respiratory protection Hand protection PEL 9000 mg/m3 biological exposure limits noted for the ingredient(s). Ensure adequate ventilation, especially in confined areas. Wear safety glasses with side shields (or goggles). Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Chemical resistant gloves are recommended. 9. Physical & Chemical Properties Appearance Odor Physical state Form Color Odor threshold ph Vapor pressure Liquid. Gas. Aerosol. Brown Slight petroleum odor, Cherry t established t applicable Vapor density 4.7 (air = 1) Boiling point Melting point/freezing point Solubility (water) < 3 % < 0.05 mm 20ºC (dispensed liquid) 383 F ( kpa < -58 F (< -50 C) Specific gravity 20 C Relative density Flash point Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Auto-ignition temperature Evaporation rate Viscosity Viscosity temperature F (79.0 C) Tag Closed Cup (dispensed liquid) 7 % 0.6 % > F (> 228 C) < 0.1 BuAc < 7 cst 77 F (25 C) Percent volatile % Partition coefficient (n-octanol/water) Other data Decomposition temperature Flammability (solid, gas) < 1 t established Flammable gas. 4 / 7

5 Heat of combustion > 30 kj/g 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions Material is stable under normal conditions. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Strong oxidizing agents. Carbon oxides. Hazardous polymerization does not occur. 11. Toxicological Information Toxicological data Species Petroleum Oil (CAS ) Acute Dermal LD50 Rabbit Inhalation LC50 Rat Oral LD50 Rat Test Results > 2000 mg/kg > 2000 mg/kg, 24 Hours 8 mg/l, 4 Hours 5000 mg/kg Acute effects Sensitization Local effects Chronic effects Carcinogenicity Skin corrosion/irritation Serious eye damage/irritation Mutagenicity Reproductive effects Teratogenicity Symptoms and target organs Synergistic materials Narcotic effects. Based on available data, the classification criteria are not met. Irritating to eyes and skin. Irritating to respiratory system. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Prolonged inhalation may be harmful. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Causes skin irritation. Causes serious eye irritation. data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. This product is not expected to cause reproductive or developmental effects. Irritating to eyes, respiratory system and skin. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Exposure may cause temporary irritation, redness, or discomfort. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. 12. Ecological Information Ecotoxicological data Ecotoxicity Environmental effects Aquatic toxicity Persistence and degradability ecotoxicity data noted for the ingredient(s). The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. t inherently biodegradable. Partition coefficient LPS 2 (Aerosol) < 1 Other adverse effects ne known. 5 / 7

6 13. Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging 14. Transport Information Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Dispose in accordance with all applicable regulations. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. TDG UN number UN1950 UN proper shipping name Aerosols, flammable Transport hazard class(es) Class Subsidiary risk - Packing group t applicable. Environmental hazards Special precautions for user IATA UN number UN1950 UN proper shipping name Aerosols, flammable Transport hazard class(es) Class Subsidiary risk - Label(s) Packing group t applicable. Environmental hazards. ERG Code 10L Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, MSDS and emergency procedures before handling. Other information Passenger and cargo Allowed. aircraft Cargo aircraft only Allowed. IMDG UN number UN1950 UN proper shipping name AEROSOLS, flammable Transport hazard class(es) Class Subsidiary risk - Label(s) Packing group t applicable. Environmental hazards Marine pollutant EmS Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, MSDS and emergency procedures before handling. IATA; IMDG; TDG 6 / 7

7 15. Regulatory Information Canadian regulations WHMIS status WHMIS classification WHMIS labeling This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. Controlled A - Compressed Gas B5 - Flammable Aerosols D2B - Other Toxic Effects-TOXIC International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other Information Disclaimer Prepared by This data sheet contains changes from the previous version in section(s): The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Product and Company Identification: Alternate Trade Names 7 / 7