Material Safety Data Sheet Risalah Data Keselamatan Kimia

Transcription

1 Material Safety Data Sheet Risalah Data Keselamatan Kimia 1. Chemical product and company identification Product name Supplier/Manufacturer Telephone no. Fax no. Use of the substance/mixture Sika Kimia Sdn. Bhd. Lot 689 Nilai Industrial Estate Nilai MY- Neeri Sembilan DK Malaysia Chemical product for construction and industry 1. Penenalpastian produk kimia dan syarikat Nama Produk Pembekal/ Penilan No. Telefon No. Faks Penunaan bahan/persediaan 2. Sika Kimia Sdn. Bhd. Lot 689 Nilai Industrial Estate Nilai MY- Neeri Sembilan DK Malaysia Composition/information on inredients Chemical family/ Characteristics Produk kimia untuk pembinaan dan industri Filled reactive PUR-polymer xylene <10 Yes. Yes. naphtha (petroleum), hydrodesulfurized heavy <10 No. No. 4,4 -methylenediphenyl diisocyanate <1 Yes. Yes. Occupational exposure limit(s), if available, are listed in section 9. * Toxicoloical information, if available, is listed in section Komposisi / maklumat bahan Keluara bahan kimia/ Ciri-ciri Filled reactive PUR-polymer xylene <10 Ya. Ya. naphtha (petroleum), hydrodesulfurized heavy <10 No. No. 4,4 -methylenediphenyl diisocyanate <1 Ya. Ya. Had Pendedahan Pekerjaan, jika tersedia, disenaraikan dalam seksyen 9. * Jika tersedia, maklumat toksikoloi disenaraikan dalam seksyen Physical and chemical properties General information Appearance Physical state Color Odor Flash point Paste. Various Characteristic. Important health, safety and environmental information Closed cup >100 C (>212 F) Date of issue /12 Tarikh keluaran

2 3. Physical and chemical properties Solubility Viscosity Insoluble in the followin materials cold water. Dynamic Not applicable. 3. Sifat-sifat fizikal dan kimia Maklumat am Rupa Keadaan fizikal Warna Pes. Pelbaai Bau Ciri-ciri. Maklumat-maklumat kesihatan, keselamatan dan persekitaran pentin Takat kilat Cawan tertutup >100 C (>212 F) Kelarutan Tidak terlarutkan dalam bahan berikut air sejuk. Kelikatan Dinamik Tidak bekenaan. 4. Hazards identification The product is classified as danerous accordin to Directive 1999/45/EC and its amendments. Classification R42 Health hazards May cause sensitization by inhalation. See Section 11 for more detailed information on health effects and symptoms. 4. Penenalpastian bahaya Produk ini dikelaskan sebaai berbahaya menurut Arahan 1999/45/EC dan pindaannya. Klasifikasi R42 Bahaya Kesihatan Boleh menyebabkan pemekaan melalui penyedutan. Lihat Seksyen 11 untuk maklumat lebih lanjut tentan kesan-kesan dan ejala-ejala kesihatan. 5. First aid measures First aid measures Inhalation Inestion Skin contact Eye contact Protection of first-aiders Move exposed person to fresh air. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathin apparatus. Keep person warm and at rest. If not breathin, if breathin is irreular or if respiratory arrest occurs, provide artificial respiration or oxyen by trained personnel. It may be danerous to the person providin aid to ive mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and et medical attention immediately. Maintain an open airway. Loosen tiht clothin such as a collar, tie, belt or waistband. In the event of any complaints or symptoms, avoid further exposure. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathin. If material has been swallowed and the exposed person is conscious, ive small quantities of water to drink. Stop if the exposed person feels sick as vomitin may be danerous. Do not induce vomitin unless directed to do so by medical personnel. If vomitin occurs, the head should be kept low so that vomit does not enter the luns. Get medical attention if adverse health effects persist or are severe. Never ive anythin by mouth to an unconscious person. If unconscious, place in recovery position and et medical attention immediately. Maintain an open airway. Loosen tiht clothin such as a collar, tie, belt or waistband. Flush contaminated skin with plenty of water. Remove contaminated clothin and shoes. Continue to rinse for at least 10 minutes. Get medical attention if symptoms occur. Wash clothin before reuse. Clean shoes thorouhly before reuse. Immediately flush eyes with plenty of water, occasionally liftin the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. No action shall be taken involvin any personal risk or without suitable trainin. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathin apparatus. It may be danerous to the person providin aid to ive mouth-to-mouth resuscitation. Date of issue /12 Tarikh keluaran

3 5. First aid measures Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if lare quantities have been inested or inhaled. See Section 11 for more detailed information on health effects and symptoms. 5. Lankah-lankah pertolonan cemas Lankah-lankah pertolonan cemas Penyedutan Alih oran yan terdedah ke kawasan udara sear. Jika disyaki wasap masih ada, penyelamat hendaklah memakai pelindun (topen) yan sesuai atau menunakan peralatan pernafasan swalenkap. Biarkan oran tesebut hanat dan berehat. Jika tidak bernafas, jika bernafas tak menentu atau henti pernafasan berlaku, berikan pernafasan pemulihan atau oksien oleh kakitanan terlatih. Berkemunkinan merbahaya kepada oran yan memberi bantuan pernafasan mulut-ke-mulut Dapatkan bantuan perubatan. Jika pensan, letakkan dalam kedudukan pemulihan dan dapatkan pemeriksaan perubatan seera. Kekalkan pembukaan laluan udara. Lonarkan bahaian baju yan ketat seperti leher baju, tali leher atau tali pinan. Sekiranya terdapat aduan atau ejala-ejala, elak dedahan yan berterusan. Peninesan Basuh mulut denan air. Tanalkan ii palsu, jika ada. Pindahkan mansa ke tempat udara sear dan kekalkan rehat dalam kedudukan yan selesa untuk bernafas. Jika bahan telah ditelan dan oran yan menalami dedahan sedar, berikan sedikit air untuk minum. Hentikan jika oran tersebut rasa sakit kerana pemuntahan boleh membahayakan. Janan paksa muntahan kecuali diarahkan berbuat demikian oleh kakitanan perubatan. Jika pemuntahan berlaku, kepala hendaklah direndahkan aar muntah tidak memasuki paru-paru. Dapatkan pemeriksaan perubatan jika kesan mudarat ke atas kesihatan berterusan atau teruk. Janan sesekali memberi apa-apa ke dalam mulut seseoran yan tidak sedarkan diri. Jika pensan, letakkan dalam kedudukan pemulihan dan dapatkan pemeriksaan perubatan seera. Kekalkan pembukaan laluan udara. Lonarkan bahaian baju yan ketat seperti leher baju, tali leher atau tali pinan. Sentuhan kulit Sentuhan mata Perlindunan untuk pemberi pertolonan cemas Nota kepada doktor Curahkan pada kulit tercemar denan air yan banyak. Tanalkan pakaian dan kasut yan tercemar. Terus membilas untuk sekuran-kurannya 10 minit. Dapatkan bantuan perubatan jika ejala-ejala berlaku. Basuh pakaian sebelum dipakai semula. Bersihkan kasut sepenuhnya sebelum dipakai semula. Seera jirus mata denan air yan banyak, sekali-sekala kedipkan mata. Periksa jika memakai kanta mata dan keluarkan jika ada. Terus membilas untuk sekurankurannya 10 minit. Dapatkan bantuan perubatan jika kerensaan berlaku. Tiada tindakan yan membabitkan risiko peribadi perlu diambil atau tanpa latihan yan sewajarnya. Jika disyaki wasap masih ada, penyelamat hendaklah memakai pelindun (topen) yan sesuai atau menunakan peralatan pernafasan swalenkap. Berkemunkinan merbahaya kepada oran yan memberi bantuan pernafasan mulut-ke-mulut Rawat menikut ejala. Hubuni pakar rawatan keracunan seera jika tertelan atau tersedut dalam kuantiti yan besar. Lihat Seksyen 11 untuk maklumat lebih lanjut tentan kesan-kesan dan ejala-ejala kesihatan. 6. Fire-fihtin measures Flash point Extinuishin media Suitable Not suitable Special exposure hazards Hazardous combustion products Closed cup >100 C (>212 F) Use an extinuishin aent suitable for the surroundin fire. None known. In a fire or if heated, a pressure increase will occur and the container may burst. Promptly isolate the scene by removin all persons from the vicinity of the incident if there is a fire. No action shall be taken involvin any personal risk or without suitable trainin. Decomposition products may include the followin materials carbon dioxide carbon monoxide haloenated compounds metal oxide/oxides Date of issue /12 Tarikh keluaran

4 6. Fire-fihtin measures Special protective equipment for fire-fihters Fire-fihters should wear appropriate protective equipment and self-contained breathin apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothin for fire-fihters (includin helmets, protective boots and loves) conformin to European standard EN 469 will provide a basic level of protection for chemical incidents. 6. Lankah-lankah pemadaman kebakaran Takat kilat Media pemadam kebakaran Sesuai Cawan tertutup >100 C (>212 F) Guna aen pemadaman sesuai untuk linkunan api. Tidak sesuai Tiada yan diketahui. Bahaya pendedahan khas Ketika kebakaran atau jika dipanaskan, peninkatan tekanan akan berlaku dan bekas boleh pecah. Produk pembakaran berbahaya Alat perlindunan khas untuk ahli bomba 7. Accidental release measures Kosonkan kawasan serta-merta denan meneluarkan semua oran daripada kawasan sekelilin jika kebakaran berlaku. Tiada tindakan yan membabitkan risiko peribadi perlu diambil atau tanpa latihan yan sewajarnya. Produk penuraian munkin termasuk bahan berikut karbon dioksida karbon monoksida sebatian berhaloen oksida loam Ahli bomba perlulah memakai peralatan perlindunan bersesuaian dan peralatan pernafasan serba lenkap denan penutup muka penuh dalam operasi mod tekanan positif. Pakaian ahli bomba (termasuk topi keledar, but dan sarun tanan pelindun) yan mematuhi Piawai Eropah EN 469 akan memberikan tahap perlindunan asas bai kejadian nahas kimia. Personal precautions Environmental precautions Lare spill No action shall be taken involvin any personal risk or without suitable trainin. Evacuate surroundin areas. Keep unnecessary and unprotected personnel from enterin. Do not touch or walk throuh spilled material. Avoid breathin vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillaes into an effluent treatment plant or proceed as follows. Contain and collect spillae with non-combustible, absorbent material e.. sand, earth, vermiculite or diatomaceous earth and place in container for disposal accordin to local reulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note see section 1 for emerency contact information and section 13 for waste disposal. Small spill Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Note see section 9 for personal protective equipment and section 13 for waste disposal. 7. Lankah-lankah penawalan pelepasan tidak senaja Lankah berjaa-jaa diri Tiada tindakan yan membabitkan risiko peribadi perlu diambil atau tanpa latihan yan sewajarnya. Kosonkan kawasan persekitaran. Halan kakitanan tidak berkaitan dan tidak dilinduni daripada masuk. Janan sentuh atah jalan melalui bahan tertumpah. Elakkan menyedut wap atau kabus. Sediakan ventilasi yan mecukupi. Pakai alat pernafasan yan sesuai apabila ventilasi tidak mencukupi. Pakai kelenkapan perlindunan peribadi bersesuaian (Lihat Seksyen 8). Date of issue /12 Tarikh keluaran

5 7. Lankah-lankah penawalan pelepasan tidak senaja Perinatan alam sekitar Tumpahan besar Tumpahan kecil Elakkan penyebaran bahan tertumpah dan aliran dan bersentuh denan tanah, jalan air, lonkan dan pembentun. Beritahu pihak berkuasa yan berkaitan jika produk menyebabkan pencemaran persekitaran (pembentun, aliran air, tanah atau udara). Hentikan kebocoran jika tidak berisiko. Alih bekas daripada kawasan tumpahan. Pendekatan lepas dari arah anin bertiup jauh dari kamu, bukan ke arah kamu. Ceah kemasukan ke dalam pembentun, aliran air, basemen atau ruan terbatas. Siram tumpahan ke dalam loji perawatan efluen atau teruskan seperti berikut. Bendun dan kumpul tumpahan denan bahan serap tidak mampu bakar seperti pasir, tanah, vermikulit dan tanah diatom, dan letakkan dalam bekas untuk pembuanan menikut peraturan tempatan (lihat seksyen 13). Gunakan alat kalis percikan dan peralatan kalis letupan. Buan melalui kontraktor pelupusan sisa yan berlesen. Bahan penyerap yan tercemar boleh mendatankan bahaya yan sama seperti produk tertumpah. Nota Lihat seksyen 1 untuk maklumat hubunan kecemasan dan seksyen 13 untuk pelupusan sisa. Hentikan kebocoran jika tidak berisiko. Alih bekas daripada kawasan tumpahan. Cairkan denan air dan lap/kerinkan jika larut air atau serapkan denan bahan kerin lenai dan tempatkan dalam bekas pelupusan sisa yan sesuai. Gunakan alat kalis percikan dan peralatan kalis letupan. Buan melalui kontraktor pelupusan sisa yan berlesen. Nota Lihat seksyen 9 untuk peralatan perlindunan peribadi dan seksyen 13 untuk pelupusan sisa. 8. Exposure controls/personal protection Exposure limit values Inredient name Recommended monitorin procedures Occupational exposure controls Occupational exposure limits xylene DOSH USECHH (Malaysia, 4/2000). TWA 434 m/m³ 8 hour(s). TWA 100 ppm 8 hour(s). 4,4 -methylenediphenyl diisocyanate DOSH USECHH (Malaysia, 4/2000). TWA m/m³ 8 hour(s). TWA ppm 8 hour(s). Safety phrases Exposure controls Hyiene measures Respiratory protection Hand protection Eye protection Skin protection S23- Do not breathe as/fumes/vapor/spray. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If this product contains inredients with exposure limits, personal, workplace atmosphere or bioloical monitorin may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Use only with adequate ventilation. If user operations enerate dust, fumes, as, vapor or mist, use process enclosures, local exhaust ventilation or other enineerin controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Wash hands, forearms and face thorouhly after handlin chemical products, before eatin, smokin and usin the lavatory and at the end of the workin period. Appropriate techniques should be used to remove potentially contaminated clothin. Wash contaminated clothin before reusin. Ensure that eyewash stations and safety showers are close to the workstation location. Use a properly fitted, air-purifyin or air-fed respirator complyin with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe workin limits of the selected respirator. Chemical-resistant, impervious loves complyin with an approved standard should be worn at all times when handlin chemical products if a risk assessment indicates this is necessary. Safety eyewear complyin with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, ases or dusts. Personal protective equipment for the body should be selected based on the task bein performed and the risks involved and should be approved by a specialist before handlin this product. Date of issue /12 Tarikh keluaran

6 8. Exposure controls/personal protection Environmental exposure controls Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection leislation. In some cases, fume scrubbers, filters or enineerin modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 8. Kawalan pendedahan dan perlindunan diri Nilai-nilai had pendedahan Nama Ramuan Lankah pemantauan yan disyorkan Kawalan-kawalan pendedahan Kawalan pendedahan pekerjaan Had Pendedahan Pekerjaan xylene DOSH USECHH (Malaysia, 4/2000). Purata berpemberat lapan jam 434 m/m³ 8 jam. Purata berpemberat lapan jam 100 ppm 8 jam. 4,4 -methylenediphenyl diisocyanate DOSH USECHH (Malaysia, 4/2000). Purata berpemberat lapan jam m/m³ 8 jam. Purata berpemberat lapan jam ppm 8 jam. Unkapan keselamatan Lankah-lankah kebersihan Perlindunan respiratori Perlindunan tanan Perlindunan mata Perlindunan kulit Kawalan pendedahan alam sekitar S23- Janan menyedut as/wasap/wap/semburan. S45- Dalam hal kemalanan atau jika anda merasa kuran sihat, dapatkan nasihat perubatan denan seera (tunjukkan label jika perlu). Jika produk ini menanduni ramuan denan had pendedahan, pemantauan peribadi, suasana tempat kerja atau bioloi munkin perlu untuk menentukan keberkesanan penudaraan (untuk peredaran udara) atau lain-lain lankah kawalan dan/atau keperluan menunakan peralatan perlindunan pernafasan. Guna hanya denan ventilasi mencukupi. Jika penendalian bahan menhasilkan debu, wasap, as, wap atau kabut, una penutup proses, penalihudaraan ekzos setempat atau kawalan kejuruteraan lain untuk memastikan pekerja hanya terdedah kepada bahan cemar bawaan udara di bawah apa-apa had yan dicadankan atau had statutori. Basun kedua tanan, lenan dan muka sehina bersih setelah menendali produk kimia, sebelum makan, merokok dan menunakan tandas dan pada akhir waktu kerja. Teknik yan sesuai harus diunakan apabila menanalkan pakaian yan munkin tercemar. Basuh pakaian tercemar sebelum memakai semula. Pastikan tempat mencuci mata dan pancuran air keselamatan berdekatan denan lokasi tempat kerja. Guna alat penulen udara atau alat pernafasan bekal udara yan muat denan baik yan mendapat kelulusan piawai jika risiko penilaian menunjukkan ianya perlu. Pemilihan alat pernafasan mesti berdasarkan tahap pendedahan diketahui atau dijanka, bahaya produk dan had pekerjaan selamat alat pernafasan yan dipilih itu. Sarun tanan kedap penentan bahan kimia, yan mematuhi piawaian yan diluluskan hendaklah dipakai pada setiap masa apabila menendalikan produk kimia jika penilaian risiko menunjukkan ini adalah perlu. Kacamata keselamatan yan mematuhi kelulusan piawai perlu diunakan apabila penilaian risiko menunjukkan ianya perlu untuk menelakkan pendedahan kepada percikan cecair, kabu, as atau debu. Peralatan perlindunan peribadi untuk badan perlu dipilih berdasarkan tuas yan dilakukan dan melibatkan risiko dan perlulah diluluskan oleh pakar sebelum menendali produk ini. Peneluaran daripada penudaraan atau peralatan proses kerja hendaklah diperiksa untuk memastikan ianya mematuhi keperluan perundanan perlindunan alam sekitar. Bai sesetenah kes, penyental wasap, penuras atau penubahsuaian kejuruteraan terhadap peralatan proses adalah perlu bai menurankan peneluaran ke tahap yan dibenarkan. 9. Handlin and storae Handlin Put on appropriate personal protective equipment (see Section 8). Eatin, drinkin and smokin should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eatin, drinkin and smokin. Persons with a history of asthma, alleries or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Do not et in eyes or on skin or clothin. Do not breathe vapor or mist. Do not inest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storae areas and confined spaces unless adequately ventilated. Keep in the oriinal container or an approved alternative Date of issue /12 Tarikh keluaran

7 9. Handlin and storae Storae Packain materials Recommended use made from a compatible material, kept tihtly closed when not in use. Store and use away from heat, sparks, open flame or any other inition source. Use explosionproof electrical (ventilatin, lihtin and material handlin) equipment. Use nonsparkin tools. Take precautionary measures aainst electrostatic dischares. To avoid fire or explosion, dissipate static electricity durin transfer by roundin and bondin containers and equipment before transferrin material. Empty containers retain product residue and can be hazardous. Do not reuse container. Store in accordance with local reulations. Store in a sereated and approved area. Store in oriinal container protected from direct sunliht in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all inition sources. Separate from oxidizin materials. Keep container tihtly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upriht to prevent leakae. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Use oriinal container. 9. Penendalian dan penyimpanan Penendalian Pakai kelenkapan perlindunan peribadi bersesuaian (Lihat Seksyen 8). Makan, minum dan menhisap rokok harus dilaran dalam kawasan di mana bahan ini dikendalikan, disimpan dan diproses. Para pekerja harus membasuh tanan dan muka sebelum makan, minum dan menhisap rokok. Oran yan mempunyai latar belakan lelah, aleri atau penyakit pernafasan yan kronik atau berulan, tidak boleh diunakan dalam mana-mana proses yan menunakan produk ini. Janan terkena mata atau pada kulit atau pakaian. Janan menyedut wap atau kabus. Janan ines. Guna hanya denan ventilasi mencukupi. Pakai alat pernafasan yan sesuai apabila ventilasi tidak mencukupi. Janan masuki kawasan simpanan dan ruan-ruan terkurun kecuali ia mempunyai ventilasi yan mencukupi. Simpan di dalam bekas asal atau bekas lain yan diluluskan yan diperbuat daripada bahan yan sesuai, tutup ketat apabila tidak diunakan. Simpan dan una jauh daripada haba, percikan api, nyalaan terbuka atau sebaran punca penyalaan lain. Guna peralatan elektrik kalis letupan (ventilasi, pencahayaan dan menendali bahan). Guna alat tidak menhasilkan percikan. Ambil lankah perinatan terhadap nyahcas elektrostatik. Untuk elakkan kebakaran dan letupan, sinkirkan elektrostatik semasa pemindahan denan membumikan dan menikat bekas dan peralatan sebelum memindahkan bahan. Bekas koson menanduni sisa produk dan boleh menjadi berbahaya. Janan una semula bekas. Penyimpanan Bahan pembunkusan Penunaan yan disyorkan Simpan menikut peraturan tempatan. Simpan di dalam kawasan yan berasinan dan dibenarkan. Simpan di dalam bekas asal yan terlindun dari pancaran terus cahaya matahari dalam kawasan kerin, sejuk dan penudaraan yan baik, jauh daripada bahan tidak sesuai (lihat seksyen 10) dan makanan dan minuman. Hapuskan semua sumber nyalaan. Asinkan daripada bahan penoksida. Simpan bekas tertutup rapat dan terkedap sehina sedia untuk diuna. Bekas yan telah dibuka mesti dikedap semula denan teliti dan disimpan meneak untuk menceah kebocoran. Janan simpan dalam bekas tidak berlabel. Gunakan kaedah penurunan yan sesuai untuk menelakkan pencemaran alam sekitar. Guna bekas asal. 10. Stability and reactivity Stability Hazardous decomposition products The product is stable. Under normal conditions of storae and use, hazardous decomposition products should not be produced. 10. Kestabilan dan kereaktifan Kestabilan Produk pereputan berbahaya Produk ini stabil. Di bawah keadaan penyimpanan dan penunaan normal, produk penuraian berbahaya tidak boleh dihasilkan. Date of issue /12 Tarikh keluaran

8 11. Toxicoloical information Potential acute health effects Inhalation Inestion Acute toxicity Taret orans May cause sensitization by inhalation. No known sinificant effects or critical hazards. Product/inredient name Result Species Dose Exposure xylene LD50 Dermal Rabbit >1700 m/k - LD50 Rat 2459 m/k - Intraperitoneal LD50 Mouse >1548 m/k - Intraperitoneal LD50 Oral Mouse 2119 m/k - LD50 Oral Rat 4300 m/k - LD50 Rat 1700 m/k - Subcutaneous LDLo Rabbit 129 m/k - Intravenous 4,4'-methylenediphenyl diisocyanate LD50 Oral Rat 9200 m/k - LD50 Oral Mouse 2200 m/k - Potential chronic health effects Chronic effects Once sensitized, a severe alleric reaction may occur when subsequently exposed to very low levels. Over-exposure sins/symptoms Inhalation Adverse symptoms may include the followin wheezin and breathin difficulties asthma Contains material which may cause damae to the followin orans blood, kidneys, luns, liver, astrointestinal tract, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. 11. Maklumat toksikoloi Kesan Kesihatan Akut Berpotensi Penyedutan Peninesan Ketoksikan akut Boleh menyebabkan pemekaan melalui penyedutan. Tiada kesan yan pentin atau bahaya kritikal yan diketahui. Nama produk/bahan Keputusan Spesis Dos Pendedahan xylene LD50 Derma Arnab >1700 m/k - LD50 Tikus 2459 m/k - Intraperitoneum LD50 Tikus >1548 m/k - Intraperitoneum LD50 Oral Tikus 2119 m/k - LD50 Oral Tikus 4300 m/k - LD50 Tikus 1700 m/k - Subkutaneus LDLo Intravena Arnab 129 m/k - 4,4'-methylenediphenyl diisocyanate LD50 Oral Tikus 9200 m/k - LD50 Oral Tikus 2200 m/k - Kesan Kesihatan Kronik Berpotensi Kesan-kesan kronik Gejala-ejala/tanda-tanda lampau terdedah Penyedutan Oran Sasaran Sebaik sahaja menjadi peka, tindak balas alahan yan teruk boleh berlaku apabila selepas itu terdedah kepada bahan kepada paras yan sanat rendah. Gejala yan teruk boleh termasuk yan berikut semput dan susah bernafas asma Menanduni bahan yan boleh menyebabkan kerosakan kepada oran-oran berikut darah, buah pinan, paru-paru, hati, saluran astrousus, saluran atas pernafasan, kulit, sistem saraf utama (CNS), mata, kanta atau kornea. Date of issue /12 Tarikh keluaran

9 12. Ecoloical information Environmental effects Aquatic ecotoxicity Product/inredient name Test Result Species xylene 8.5 ppm Marine water Crustaceans - Daerblade rass shrimp - Palaemonetes puio - Adult Other ecoloical information Bioaccumulative potential No known sinificant effects or critical hazards u/l Fresh water to u/l Fresh water to u/l Fresh water to u/l Fresh water u/l Fresh water to u/l Fresh water to u/l Fresh water 8600 to 9591 u/l Fresh water 8500 u/l Marine water 8200 to u/l Fresh water 3300 to 4093 u/l Fresh water Fish - Blueill - Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss Fish - Blueill - macrochirus Fish - Blueill - Fish - Fathead minnow - Pimephales promelas - 31 days mm Fish - Blueill - Fish - Blueill - Fish - Blueill - macrochirus Crustaceans - Daerblade rass shrimp - Palaemonetes puio Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss Product/inredient name LoPow BCF Potential xylene hih Exposure 48 hours 48 hours 12. Maklumat ekoloi Date of issue /12 Tarikh keluaran

10 12. Maklumat ekoloi Kesan-Kesan Alam Sekitar Keekotoksikan akuatik Nama produk/bahan Ujian Keputusan Spesis xylene - Akut LC ppm Air laut Crustacea - Daerblade rass shrimp - Palaemonetes puio - Adult Maklumat Ekoloi Lain Potensi bioakumulasi Tiada kesan yan pentin atau bahaya kritikal yan diketahui. - Akut LC u/l Air tawar - Akut LC kepada u/l Air tawar - Akut LC kepada u/l Air tawar - Akut LC kepada u/l Air tawar - Akut LC u/l Air tawar - Akut LC kepada u/l Air tawar - Akut LC kepada u/l Air tawar - Akut LC kepada 9591 u/l Air tawar - Akut LC u/l Air laut - Akut LC kepada u/l Air tawar - Akut LC kepada 4093 u/l Air tawar Ikan - Blueill - Ikan - Rainbow trout,donaldson trout - Oncorhynchus mykiss Ikan - Blueill - macrochirus Ikan - Blueill - Ikan - Fathead minnow - Pimephales promelas - 31 hari mm Ikan - Blueill - Ikan - Blueill - Ikan - Blueill - macrochirus Crustacea - Daerblade rass shrimp - Palaemonetes puio Ikan - Rainbow trout,donaldson trout - Oncorhynchus mykiss Ikan - Rainbow trout,donaldson trout - Oncorhynchus mykiss Nama produk/bahan LoPow BCF Berpotensi xylene tini Pendedahan 48 jam 48 jam Date of issue /12 Tarikh keluaran

11 13. Disposal considerations Waste must be disposed of in accordance with federal, state and local environmental control reulations. Methods of disposal The eneration of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal leislation and any reional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. 13. Maklumat pembuanan Sisa harus dibuankan menikut peraturan persekutuan, neeri dan kawalan alam sekitar tempatan. Kaedah pembuanan Penhasilan sisa perlulah dielakkan atau diminimumkan sekiranya boleh. Bekas atau pelapik koson munkin menanduni sisa-sisa produk. Bahan ini dan bekasnya hendaklah dilupuskan denan cara yan selamat. Pembuanan lebihan dan hasilan yan tidak boleh dikitar semula melalui kontraktor pelupusan sisa yan berlesen. Pelupusan produk ini, larutan dan sebaran produk sampinan perlulah pada setiap masa mematuhi keperluan perlindunan alam sekitar dan perundanan pelupusan sisa dan sebaran keperluan pihak berkuasa serantau tempatan. Elakkan penyebaran bahan tertumpah dan aliran dan bersentuh denan tanah, jalan air, lonkan dan pembentun. 14. Transport information International transport reulations ADR Not reulated. IMDG Not reulated. Marine pollutant IATA Not reulated. No. 14. Maklumat penankutan Peraturan penankutan antarabansa ADR No danerous oods. IMDG Not reulated. Marine pollutant IATA Not reulated. No. 15. Reulatory information EU reulations Hazard symbol or symbols Risk phrases Safety phrases Contains Product use Harmful R42- May cause sensitization by inhalation. S23- Do not breathe as/fumes/vapor/spray. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 4,4'-methylenediphenyl diisocyanate Professional applications. Date of issue /12 Tarikh keluaran

12 15. Reulatory information Other EU reulations Additional warnin phrases Contains isocyanates. See information supplied by the manufacturer. 15. Maklumat penawalan Peraturan-Peraturan EU Simbol bahaya Unkapan risiko Unkapan keselamatan Menanduni Keunaan Produk Peraturan EU Lain Unkapan Amaran Tambahan Memudaratkan R42- Boleh menyebabkan pemekaan melalui penyedutan. S23- Janan menyedut as/wasap/wap/semburan. S45- Dalam hal kemalanan atau jika anda merasa kuran sihat, dapatkan nasihat perubatan denan seera (tunjukkan label jika perlu). 4,4'-methylenediphenyl diisocyanate Aplikasi profesional. Menanduni isosianat. Lihat maklumat diberikan oleh penilan. 16. Other information History Date of printin Date of issue Date of previous issue Version Notice to reader No previous validation. 1 Indicates information that has chaned from previously issued version. The information contained in this Safety Data Sheet corresponds to our level of knowlede at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the product data sheet prior to any use and processin. 16. Maklumat lain Sejarah Tarikh cetakan Tarikh keluaran Tarikh Keluaran Terdahulu Versi Notis kepada pembaca Tiada Penesahan Terdahulu. 1 Menunjukkan maklumat yan telah berubah daripada versi isu terdahulu. Informasi yan terkandun di dalam Risalah Data Keselamatan Kimia ini adalah sejajar denan tahap penetahuan kami pada masa ianya diterbitkan. Sebaran jaminan adalah dikecualikan. Syarat - syarat Penjualan Am kami yan terkini tertakluk. Sila rujuk Risalah Data Teknikal kami sebelum sebaran penunaan dan pemprosesan. Date of issue /12 Tarikh keluaran