Material Safety Data Sheet Risalah Data Keselamatan Kima

Transcription

1 Material Safety Data Sheet Risalah Data Keselamatan Kima 1. Chemical product and company identification Product name Supplier/Manufacturer Telephone no. Fax no. Use of the substance/preparation Sika Kimia Sdn. Bhd. Lot 689 Nilai Industrial Estate Nilai MY- Neeri Sembilan DK Malaysia Chemical product for construction and industry 1. Penenalpastian produk kimia dan syarikat Nama Produk Pembekal/ Penilan No. Telefon No. Faks Penunaan bahan/persediaan 2. Sika Kimia Sdn. Bhd. Lot 689 Nilai Industrial Estate Nilai MY- Neeri Sembilan DK Malaysia Composition/information on inredients reaction product bisphenol-a-(epichlorhydrin) and epoxy resin (number averae molecular weiht ) Produk kimia untuk pembinaan dan industri <60 xylene Yes. Yes. <0 4-methylpentan-2-one <10 Yes. Yes. ethylbenzene <10 Yes. Yes. Occupational exposure limit(s), if available, are listed in section 9. * Toxicoloical information, if available, is listed in section 11 No. No. 2. Komposisi / maklumat bahan reaction product bisphenol-a-(epichlorhydrin) and epoxy resin (number averae molecular weiht ) <60 xylene Ya. Ya. <0 4-methylpentan-2-one <10 Ya. Ya. ethylbenzene <10 Ya. Ya. Had Pendedahan Pekerjaan, jika tersedia, disenaraikan dalam seksyen 9. * Jika tersedia, maklumat toksikoloi disenaraikan dalam seksyen 11 No. No. Date of issue /18 Tarikh keluaran

2 . Physical and chemical properties General information Appearance Physical state Liquid. [Clear viscous liquid.] Color Clear. Odor Solvent Smell Important health, safety and environmental information Flash point Closed cup -18 to 2 C (-0.4 to 7.4 F) Other information Auto-inition temperature 465 C (869 F). Sifat-sifat fizikal dan kimia Maklumat am Rupa Keadaan fizikal Cecair. [Cecair likat jernih.] Warna Jernih. Bau Solvent Smell Maklumat-maklumat kesihatan, keselamatan dan persekitaran pentin Takat kilat Cawan tertutup -18 kepada 2 C (-0.4 kepada 7.4 F) Maklumat lain Suhu penyalaan automatik 465 C (869 F) 4. Hazards identification The product is classified as danerous accordin to Directive 1999/45/EC and its amendments. Classification F; R11 Xn; R20/21 Xi; R6/8 R4 Health hazards Physical/chemical hazards Harmful by inhalation and in contact with skin. Irritatin to eyes and skin. May cause sensitization by skin contact. Hihly flammable. See section 11 for more detailed information on health effects and symptoms. 4. Penenalpastian bahaya Produk ini dikelaskan sebaai berbahaya menurut Arahan 1999/45/EC dan pindaannya. Klasifikasi F; R11 Xn; R20/21 Xi; R6/8 R4 Bahaya Kesihatan Bahaya Fizikal/Bahan Kimia Memudaratkan melalui penyedutan dan jika bersentuhan denan kulit. Merensa kepada mata dan kulit. Boleh menyebakan pemekaan melalui sentuhan kulit. Sanat mudah terbakar. Lihat Seksyen 11 untuk maklumat lebih lanjut tentan kesan-kesan dan ejala-ejala kesihatan. 5. First aid measures First aid measures Inhalation Move exposed person to fresh air. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathin apparatus. Keep person warm and at rest. If not breathin, if breathin is irreular or if respiratory arrest occurs, provide artificial respiration or oxyen by trained personnel. It may be danerous to the person providin aid to ive mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and et medical attention immediately. Maintain an open airway. Loosen tiht clothin such as a collar, tie, belt or waistband. Date of issue /18 Tarikh keluaran

3 5. First aid measures Inestion Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, ive small quantities of water to drink. Stop if the exposed person feels sick as vomitin may be danerous. Do not induce vomitin unless directed to do so by medical personnel. If vomitin occurs, the head should be kept low so that vomit does not enter the luns. Get medical attention if adverse health effects persist or are severe. Never ive anythin by mouth to an unconscious person. If unconscious, place in recovery position and et medical attention immediately. Maintain an open airway. Loosen tiht clothin such as a collar, tie, belt or waistband. Skin contact Eye contact Protection of first-aiders Notes to physician Flush contaminated skin with plenty of water. Remove contaminated clothin and shoes. Wash contaminated clothin thorouhly with water before removin it, or wear loves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothin before reuse. Clean shoes thorouhly before reuse. Immediately flush eyes with plenty of water, occasionally liftin the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. No action shall be taken involvin any personal risk or without suitable trainin. It may be danerous to the person providin aid to ive mouth-to-mouth resuscitation. Wash contaminated clothin thorouhly with water before removin it, or wear loves. No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if lare quantities have been inested or inhaled. See section 11 for more detailed information on health effects and symptoms. 5. Lankah-lankah pertolonan cemas Lankah-lankah pertolonan cemas Penyedutan Peninesan Alih oran yan terdedah ke kawasan udara sear. Jika disyaki wasap masih ada, penyelamat hendaklah memakai pelindun (topen) yan sesuai atau menunakan peralatan pernafasan swalenkap. Biarkan oran tesebut hanat dan berehat. Jika tidak bernafas, jika bernafas tak menentu atau henti pernafasan berlaku, berikan pernafasan pemulihan atau oksien oleh kakitanan terlatih. Berkemunkinan merbahaya kepada oran yan memberi bantuan pernafasan mulut-ke-mulut Dapatkan bantuan perubatan. Jika pensan, letakkan dalam kedudukan pemulihan dan dapatkan pemeriksaan perubatan seera. Kekalkan pembukaan laluan udara. Lonarkan bahaian baju yan ketat seperti leher baju, tali leher atau tali pinan. Basuh mulut denan air. Tanalkan ii palsu, jika ada. Alih oran yan terdedah ke kawasan udara sear. Biarkan oran tesebut hanat dan berehat. Jika bahan telah ditelan dan oran yan menalami dedahan sedar, berikan sedikit air untuk minum. Hentikan jika oran tersebut rasa sakit kerana pemuntahan boleh membahayakan. Janan paksa muntahan kecuali diarahkan berbuat demikian oleh kakitanan perubatan. Jika pemuntahan berlaku, kepala hendaklah direndahkan aar muntah tidak memasuki paru-paru. Dapatkan pemeriksaan perubatan jika kesan mudarat ke atas kesihatan berterusan atau teruk. Janan sesekali memberi apa-apa ke dalam mulut seseoran yan tidak sedarkan diri. Jika pensan, letakkan dalam kedudukan pemulihan dan dapatkan pemeriksaan perubatan seera. Kekalkan pembukaan laluan udara. Lonarkan bahaian baju yan ketat seperti leher baju, tali leher atau tali pinan. Sentuhan kulit Sentuhan mata Perlindunan untuk pemberi pertolonan cemas Curahkan pada kulit tercemar denan air yan banyak. Tanalkan pakaian dan kasut yan tercemar. Basuh pakaian yan tercemar denan teliti menunakan air sebelum menanalkannya, atau pakai sarun tanan. Terus membilas untuk sekuran-kurannya 10 minit. Dapatkan bantuan perubatan. Sekiranya terdapat aduan atau ejala-ejala, elak dedahan yan berterusan. Basuh pakaian sebelum dipakai semula. Bersihkan kasut sepenuhnya sebelum dipakai semula. Seera jirus mata denan air yan banyak, sekali-sekala kedipkan mata. Periksa jika memakai kanta mata dan keluarkan jika ada. Terus membilas untuk sekurankurannya 10 minit. Dapatkan bantuan perubatan. Tiada tindakan yan membabitkan risiko peribadi perlu diambil atau tanpa latihan yan sewajarnya. Berkemunkinan merbahaya kepada oran yan memberi bantuan pernafasan mulut-ke-mulut Basuh pakaian yan tercemar denan teliti menunakan air sebelum menanalkannya, atau pakai sarun tanan. Date of issue /18 Tarikh keluaran

4 5. Lankah-lankah pertolonan cemas Nota kepada doktor Tiada rawatan spesifik. Rawat menikut ejala. Hubuni pakar rawatan keracunan seera jika tertelan atau tersedut dalam kuantiti yan besar. Lihat Seksyen 11 untuk maklumat lebih lanjut tentan kesan-kesan dan ejala-ejala kesihatan. 6. Fire-fihtin measures Flash point Extinuishin media Suitable Not suitable Special exposure hazards Hazardous combustion products Special protective equipment for fire-fihters Closed cup -18 to 2 C (-0.4 to 7.4 F) Use dry chemical, CO2, water spray (fo) or foam. Do not use water jet. Hihly flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Promptly isolate the scene by removin all persons from the vicinity of the incident if there is a fire. No action shall be taken involvin any personal risk or without suitable trainin. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Decomposition products may include the followin materials carbon dioxide carbon monoxide haloenated compounds metal oxide/oxides Fire-fihters should wear appropriate protective equipment and self-contained breathin apparatus (SCBA) with a full face-piece operated in positive pressure mode. 6. Lankah-lankah pemadaman kebakaran Takat kilat Media pemadam kebakaran Sesuai Tidak sesuai Bahaya pendedahan khas Produk pembakaran berbahaya Alat perlindunan khas untuk ahli bomba 7. Accidental release measures Cawan tertutup -18 kepada 2 C (-0.4 kepada 7.4 F) Guna bahan kimia kerin, CO2, semburan air (kabut) atau busa. Janan una jet air. Cecair sanat mudah terbakar. Ketika kebakaran atau jika dipanaskan, peninkatan tekanan akan berlaku dan bekas boleh pecah, denan risiko letupan selepas itu. Larian ke pembetun boleh menyebabkan bahaya kebakaran atau letupan. Kosonkan kawasan serta-merta denan meneluarkan semua oran daripada kawasan sekelilin jika kebakaran berlaku. Tiada tindakan yan membabitkan risiko peribadi perlu diambil atau tanpa latihan yan sewajarnya. Alih bekas daripada kawasan kebakaran jika ini boleh dilakukan tanpa risiko. Guna semburan air untuk menyejukkan bekas yan terdedah kepada api. Produk penuraian munkin termasuk bahan berikut karbon dioksida karbon monoksida sebatian berhaloen oksida loam Ahli bomba perlulah memakai peralatan perlindunan bersesuaian dan peralatan pernafasan serba lenkap denan penutup muka penuh dalam operasi mod tekanan positif. Personal precautions Environmental precautions No action shall be taken involvin any personal risk or without suitable trainin. Evacuate surroundin areas. Keep unnecessary and unprotected personnel from enterin. Do not touch or walk throuh spilled material. Shut off all inition sources. No flares, smokin or flames in hazard area. Avoid breathin vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see section 8). Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Date of issue /18 Tarikh keluaran

5 7. Accidental release measures Lare spill Small spill Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillaes into an effluent treatment plant or proceed as follows. Contain and collect spillae with non-combustible, absorbent material e.. sand, earth, vermiculite or diatomaceous earth and place in container for disposal accordin to local reulations (see section 1). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note see section 1 for emerency contact information and section 1 for waste disposal. Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Note see section 9 for personal protective equipment and section 1 for waste disposal. 7. Lankah-lankah penawalan pelepasan tidak senaja Lankah berjaa-jaa diri Tiada tindakan yan membabitkan risiko peribadi perlu diambil atau tanpa latihan yan sewajarnya. Kosonkan kawasan persekitaran. Halan kakitanan tidak berkaitan dan tidak dilinduni daripada masuk. Janan sentuh atah jalan melalui bahan tertumpah. Tutup semua sumber pencucuhan. Tiada menyala, merokok atau nyalaan di kawasan bahaya. Elakkan menyedut wap atau kabus. Sediakan ventilasi yan mecukupi. Pakai alat pernafasan yan sesuai apabila ventilasi tidak mencukupi. Pakai kelenkapan perlindunan peribadi bersesuaian (Lihat Seksyen 8). Perinatan alam sekitar Elakkan penyebaran bahan tertumpah dan aliran dan bersentuh denan tanah, jalan air, lonkan dan pembentun. Beritahu pihak berkuasa yan berkaitan jika produk menyebabkan pencemaran persekitaran (pembentun, aliran air, tanah atau udara). Tumpahan besar Hentikan kebocoran jika tidak berisiko. Alih bekas daripada kawasan tumpahan. Hampiri pelepasan dari arah hadapan anin. Ceah kemasukan ke dalam pembentun, aliran air, basemen atau ruan terbatas. Siram tumpahan ke dalam loji perawatan efluen atau teruskan seperti berikut. Bendun dan kumpul tumpahan denan bahan serap tidak mampu bakar seperti pasir, tanah, vermikulit dan tanah diatom, dan letakkan dalam bekas untuk pembuanan menikut peraturan tempatan (lihat seksyen 1). Gunakan alat kalis percikan dan peralatan kalis letupan. Buan melalui kontraktor pelupusan sisa yan berlesen. Bahan penyerap yan tercemar boleh mendatankan bahaya yan sama seperti produk tertumpah. Nota Lihat seksyen 1 untuk maklumat hubunan kecemasan dan seksyen 1 untuk pelupusan sisa. Tumpahan kecil Hentikan kebocoran jika tidak berisiko. Alih bekas daripada kawasan tumpahan. Cairkan denan air dan seka bersih jika terlarut air. Sebaai alternatif, atau jika tidak terlarut air, serap denan bahan kerin yan lenai dan isikan dalam bekas pelupusan bahan buanan yan wajar. Gunakan alat kalis percikan dan peralatan kalis letupan. Buan melalui kontraktor pelupusan sisa yan berlesen. Nota Lihat seksyen 9 untuk peralatan perlindunan peribadi dan seksyen 1 untuk pelupusan sisa. 8. Handlin and storae Handlin Put on appropriate personal protective equipment (see section 8). Eatin, drinkin and smokin should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eatin, drinkin and smokin. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not et in eyes or on skin or clothin. Do not inest. Avoid breathin vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storae areas and confined spaces unless adequately ventilated. Keep in the oriinal container or an approved alternative made from a compatible material, kept tihtly closed when not in use. Store and use away from heat, sparks, open flame or any other inition source. Use explosion-proof electrical (ventilatin, lihtin and material handlin) equipment. Use non-sparkin tools. Take precautionary measures aainst electrostatic dischares. To avoid fire or explosion, dissipate static electricity durin transfer by roundin and bondin containers and equipment before transferrin material. Empty containers retain product residue and can be hazardous. Do not reuse container. Date of issue /18 Tarikh keluaran

6 8. Handlin and storae Storae Packain materials Recommended use Store in accordance with local reulations. Store in a sereated and approved area. Store in oriinal container protected from direct sunliht in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all inition sources. Separate from oxidizin materials. Keep container tihtly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upriht to prevent leakae. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Use oriinal container. 8. Penendalian dan penyimpanan Penendalian Penyimpanan Bahan pembunkusan Penunaan yan disyorkan Pakai kelenkapan perlindunan peribadi bersesuaian (Lihat Seksyen 8). Makan, minum dan menhisap rokok harus dilaran dalam kawasan di mana bahan ini dikendalikan, disimpan dan diproses. Para pekerja harus membasuh tanan dan muka sebelum makan, minum dan menhisap rokok. Oran yan mempunyai latar belakan masalah pemekaan kulit tidak harus diambil bekerja dalam mana-mana proses yan menunakan produk ini. Janan terkena mata atau pada kulit atau pakaian. Janan ines. Elakkan menyedut wap atau kabus. Guna hanya denan ventilasi mencukupi. Pakai alat pernafasan yan sesuai apabila ventilasi tidak mencukupi. Janan masuki kawasan simpanan dan ruan-ruan terkurun kecuali ia mempunyai ventilasi yan mencukupi. Simpan di dalam bekas asal atau bekas lain yan diluluskan yan diperbuat daripada bahan yan sesuai, tutup ketat apabila tidak diunakan. Simpan dan una jauh daripada haba, percikan api, nyalaan terbuka atau sebaran punca penyalaan lain. Guna peralatan elektrik kalis letupan (ventilasi, pencahayaan dan menendali bahan). Guna alat tidak menhasilkan percikan. Ambil lankah perinatan terhadap nyahcas elektrostatik. Untuk elakkan kebakaran dan letupan, sinkirkan elektrostatik semasa pemindahan denan membumikan dan menikat bekas dan peralatan sebelum memindahkan bahan. Bekas koson menanduni sisa produk dan boleh menjadi berbahaya. Janan una semula bekas. Simpan menikut peraturan tempatan. Simpan di dalam kawasan yan berasinan dan dibenarkan. Simpan di dalam bekas asal yan terlindun dari pancaran terus cahaya matahari dalam kawasan kerin, sejuk dan penudaraan yan baik, jauh daripada bahan tidak sesuai (lihat seksyen 10) dan makanan dan minuman. Hapuskan semua sumber nyalaan. Asinkan daripada bahan penoksida. Simpan bekas tertutup rapat dan terkedap sehina sedia untuk diuna. Bekas yan telah dibuka mesti dikedap semula denan teliti dan disimpan meneak untuk menceah kebocoran. Janan simpan dalam bekas tidak berlabel. Gunakan kaedah penurunan yan sesuai untuk menelakkan pencemaran alam sekitar. Guna bekas asal. 9. Exposure controls/personal protection Exposure limit values Inredient name Occupational exposure limits xylene DOSH USECHH (Malaysia, 4/2000). TWA 44 m/m³ 8 hour(s). TWA 100 ppm 8 hour(s). 4-methylpentan-2-one DOSH USECHH (Malaysia, 4/2000). TWA 205 m/m³ 8 hour(s). TWA 50 ppm 8 hour(s). ethylbenzene DOSH USECHH (Malaysia, 4/2000). TWA 100 ppm 8 hour(s). TWA 44 m/m³ 8 hour(s). Safety phrases Recommended monitorin procedures Exposure controls S6/7- Wear suitable protective clothin and loves. If this product contains inredients with exposure limits, personal, workplace atmosphere or bioloical monitorin may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Date of issue /18 Tarikh keluaran

7 9. Exposure controls/personal protection Occupational exposure controls Hyiene measures Respiratory protection Hand protection Eye protection Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other enineerin controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The enineerin controls also need to keep as, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thorouhly after handlin chemical products, before eatin, smokin and usin the lavatory and at the end of the workin period. Appropriate techniques should be used to remove potentially contaminated clothin. Wash contaminated clothin before reusin. Ensure that eyewash stations and safety showers are close to the workstation location. Use a properly fitted, air-purifyin or air-fed respirator complyin with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe workin limits of the selected respirator. Chemical-resistant, impervious loves complyin with an approved standard should be worn at all times when handlin chemical products if a risk assessment indicates this is necessary. Safety eyewear complyin with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Skin protection Personal protective equipment for the body should be selected based on the task bein performed and the risks involved and should be approved by a specialist before handlin this product. Environmental exposure controls Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection leislation. In some cases, fume scrubbers, filters or enineerin modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 9. Kawalan pendedahan dan perlindunan diri Nilai-nilai had pendedahan Nama Ramuan Lankah pemantauan yan disyorkan Kawalan pendedahan pekerjaan Had Pendedahan Pekerjaan xylene DOSH USECHH (Malaysia, 4/2000). Purata berpemberat lapan jam 44 m/m³ 8 jam. Purata berpemberat lapan jam 100 ppm 8 jam. 4-methylpentan-2-one DOSH USECHH (Malaysia, 4/2000). Purata berpemberat lapan jam 205 m/m³ 8 jam. Purata berpemberat lapan jam 50 ppm 8 jam. ethylbenzene DOSH USECHH (Malaysia, 4/2000). Purata berpemberat lapan jam 100 ppm 8 jam. Purata berpemberat lapan jam 44 m/m³ 8 jam. Unkapan keselamatan Kawalan-kawalan pendedahan Lankah-lankah kebersihan S6/7- Pakailah pakaian perlindunan dan sarun tanan yan sesuai. Jika produk ini menanduni ramuan denan had pendedahan, pemantauan peribadi, suasana tempat kerja atau bioloi munkin perlu untuk menentukan keberkesanan penudaraan (untuk peredaran udara) atau lain-lain lankah kawalan dan/atau keperluan menunakan peralatan perlindunan pernafasan. Guna hanya denan ventilasi mencukupi. Guna penutup proses, penalihudaraan ekzos setempat atau kawalan kejuruteraan lain untuk memastikan pekerja hanya terdedah kepada bahan cemar bawaan udara di bawah apa-apa had yan dicadankan atau had statutori. Kawalan kejuruteraan jua perlu memastikan kepekatan as, wap atau debu di bawah sebaran had bahan letupan yan lebih rendah. Guna peralatan ventilasi kalis letupan. Basun kedua tanan, lenan dan muka sehina bersih setelah menendali produk kimia, sebelum makan, merokok dan menunakan tandas dan pada akhir waktu kerja. Teknik yan sesuai harus diunakan apabila menanalkan pakaian yan munkin tercemar. Basuh pakaian tercemar sebelum memakai semula. Pastikan tempat mencuci mata dan pancuran air keselamatan berdekatan denan lokasi tempat kerja. Date of issue /18 Tarikh keluaran

8 9. Kawalan pendedahan dan perlindunan diri Perlindunan respiratori Perlindunan tanan Perlindunan mata Perlindunan kulit Kawalan pendedahan alam sekitar 10. Stability and reactivity Guna alat penulen udara atau alat pernafasan bekal udara yan muat denan baik yan mendapat kelulusan piawai jika risiko penilaian menunjukkan ianya perlu. Pemilihan alat pernafasan mesti berdasarkan tahap pendedahan diketahui atau dijanka, bahaya produk dan had pekerjaan selamat alat pernafasan yan dipilih itu. Sarun tanan kedap penentan bahan kimia, yan mematuhi piawaian yan diluluskan hendaklah dipakai pada setiap masa apabila menendalikan produk kimia jika penilaian risiko menunjukkan ini adalah perlu. Kacamata keselamatan yan mematuhi kelulusan piawai perlu diunakan apabila risiko penilaian menunjukkan ianya perlu untuk menelakkan pendedahan kepada percikan cecair, kabus atau debu. Peralatan perlindunan peribadi untuk badan perlu dipilih berdasarkan tuas yan dilakukan dan melibatkan risiko dan perlulah diluluskan oleh pakar sebelum menendali produk ini. Peneluaran daripada penudaraan atau peralatan proses kerja hendaklah diperiksa untuk memastikan ianya mematuhi keperluan perundanan perlindunan alam sekitar. Bai sesetenah kes, penyental wasap, penuras atau penubahsuaian kejuruteraan terhadap peralatan proses adalah perlu bai menurankan peneluaran ke tahap yan dibenarkan. Stability Conditions to avoid Materials to avoid Hazardous decomposition products The product is stable. Avoid all possible sources of inition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, rind or expose containers to heat or sources of inition. Hihly reactive or incompatible with the followin materials oxidizin materials Under normal conditions of storae and use, hazardous decomposition products should not be produced. 10. Kestabilan dan kereaktifan Kestabilan Keadaan-keadaan yan mesti dielak Bahan yan harus dielak Produk pereputan berbahaya 11. Toxicoloical information Potential acute health effects Inhalation Inestion Skin contact Eye contact Acute toxicity Produk ini stabil. Elakkan semua sumber penyalaan yan munkin (percikan api atau nyalaan). Janan kenakan tekanan, poton, kimpal, pateri keras, pateri, erudi, kisar atau dedahkan bekas kepada kepanasan atau sumber penyalaan. Sanat reaktif atau tidak serasi denan bahan yan berikut bahan penoksida Di bawah keadaan penyimpanan dan penunaan normal, produk penuraian berbahaya tidak boleh dihasilkan. Harmful by inhalation. Irritatin to mouth, throat and stomach. Harmful in contact with skin. Irritatin to skin. May cause sensitization by skin contact. Irritatin to eyes. Product/inredient name Result Species Dose Exposure xylene Dermal Rabbit >1700 m/k - Rat 2459 m/k - Intraperitoneal Mouse >1548 m/k - Intraperitoneal Oral Rat 400 m/k - Oral Mouse 2119 m/k - Rat 1700 m/k - Subcutaneous LDLo Rabbit 129 m/k - Intravenous LC50 Inhalation Rat 5000 ppm 4 hours Gas. 4-methylpentan-2-one LD Dermal Rabbit > /k - Date of issue /18 Tarikh keluaran

9 11. Taret orans Toxicoloical information Rat 400 m/k - Intraperitoneal Mouse 268 m/k - Intraperitoneal Oral Rat 4600 m/k - Oral Mouse 2850 m/k - Oral Rat 2080 m/k - Oral Mouse 1900 m/k - TDLo Oral Rat 500 m/k - ethylbenzene Dermal Rabbit >5000 m/k - Dermal Rabbit ul/k - Mouse 2624 ul/k - Intraperitoneal Oral Rat 500 m/k - TDLo Intraperitoneal Rat 1062 m/k - Potential chronic health effects Chronic effects Once sensitized, a severe alleric reaction may occur when subsequently exposed to very low levels. Over-exposure sins/symptoms Skin Eyes Adverse symptoms may include the followin irritation redness Adverse symptoms may include the followin irritation waterin redness Contains material which may cause damae to the followin orans blood, kidneys, luns, liver, astrointestinal tract, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. 11. Maklumat toksikoloi Kesan Kesihatan Akut Berpotensi Penyedutan Memudaratkan melalui penyedutan. Peninesan Sentuhan kulit Sentuhan mata Ketoksikan akut Merensa mulut, keronkon dan perut. Memudaratkan jika bersentuhan denan kulit. Merensa kepada kulit. Boleh menyebakan pemekaan melalui sentuhan kulit. Merensa kepada mata. Nama produk/bahan Keputusan Spesis Dos Pendedahan xylene Derma Arnab >1700 m/k - Tikus 2459 m/k - Intraperitoneum Tikus >1548 m/k - Intraperitoneum Oral Tikus 400 m/k - Oral Tikus 2119 m/k - Tikus 1700 m/k - Subkutaneus LDLo Intravena Arnab 129 m/k - LC50 Tikus 5000 ppm 4 jam Penyedutan Gas. 4-methylpentan-2-one LD Derma Arnab > /k - Tikus 400 m/k - Intraperitoneum Tikus 268 m/k - Intraperitoneum Oral Tikus 4600 m/k - Oral Tikus 2850 m/k - Oral Tikus 2080 m/k - Oral Tikus 1900 m/k - TDLo Oral Tikus 500 m/k - ethylbenzene Derma Arnab >5000 m/k - Date of issue /18 Tarikh keluaran

10 11. Maklumat toksikoloi Kesan Kesihatan Kronik Berpotensi Oran Sasaran Derma Arnab ul/k - Tikus 2624 ul/k - Intraperitoneum Oral Tikus 500 m/k - TDLo Intraperitoneum Tikus 1062 m/k - Kesan-kesan kronik Sebaik sahaja menjadi peka, tindak balas alahan yan teruk boleh berlaku apabila selepas itu terdedah kepada bahan kepada paras yan sanat rendah. Gejala-ejala/tanda-tanda lampau terdedah Kulit Mata 12. Ecoloical information Environmental effects Aquatic ecotoxicity Gejala yan teruk boleh termasuk yan berikut kerensaan kemerahan Gejala yan teruk boleh termasuk yan berikut kerensaan berair kemerahan Menanduni bahan yan boleh menyebabkan kerosakan kepada oran-oran berikut darah, buah pinan, paru-paru, hati, saluran astrousus, saluran atas pernafasan, kulit, sistem saraf utama (CNS), mata, kanta atau kornea. No known sinificant effects or critical hazards. Product/inredient name Test Result Species xylene 8.5 ppm Marine water Crustaceans - Daerblade rass shrimp - Palaemonetes puio - Adult 1500 to u/l 1500 to 1504 u/l 1500 to u/l 1400 u/l Fresh water 100 to u/l to 1762 u/l to u/l 8600 to 9591 u/l Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss Fish - Blueill - macrochirus Fish - Blueill - macrochirus Fish - Fathead promelas - 1 days mm Fish - Blueill - macrochirus Fish - Blueill - macrochirus Fish - Blueill - macrochirus Fish - Blueill - macrochirus Exposure Date of issue /18 Tarikh keluaran

11 12. Ecoloical information 8500 u/l Marine water 8200 to 1002 u/l 00 to 409 u/l 4-methylpentan-2-one to u/l to u/l to u/l ethylbenzene - Acute EC to u/l - Acute EC to 9460 u/l - Acute EC to 4400 u/l - Acute EC to 4400 u/l 150 to 200 m/l 280 to 290 ppm Marine water to u/l Crustaceans - Daerblade rass shrimp - Palaemonetes puio Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss Fish - Fathead promelas - 1 days - 20 mm Fish - Fathead promelas - Juvenile (Fledlin, Hatchlin, Weanlin) - 28 to 4 days Fish - Fathead promelas - 29 days - 21 mm Crustaceans - Brine shrimp - Artemia sp. - Nauplii Crustaceans - Brine shrimp - Artemia sp. - Nauplii Daphnia - Water mana - Neonate Daphnia - Water mana - Neonate Fish - Blueill - macrochirus - Youn of the year to 1.2 Fish - Sheepshead Cyprinodon varieatus - Juvenile (Fledlin, Hatchlin, Weanlin) - 8 to 15 mm Daphnia - Water mana Date of issue /18 Tarikh keluaran

12 12. Ecoloical information u/l Marine water to u/l 1900 to u/l 100 to u/l 9600 u/l 9100 to u/l 9090 to u/l 8780 to 1700 u/l >5200 u/l Marine water 5100 to 5700 u/l Marine water 4200 u/l 4. to 4.7 ul/l Marine water - Chronic NOEC 88 ppm Marine water - Chronic NOEC 00 u/l Marine water Crustaceans - Duneness or edible crab - Cancer maister - Zoea Daphnia - Water mana - Neonate Daphnia - Water mana - Neonate Crustaceans - Brine shrimp - Artemia sp. - Nauplii Fish - Guppy - Poecilia reticulata Fish - Fathead promelas - 0 days Fish - Fathead promelas - 28 to 2 days mm Crustaceans - Brine shrimp - Artemia sp. - Nauplii Crustaceans - Opossum shrimp - Americamysis bahia Fish - Atlantic silverside - Menidia menidia Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss Fish - Striped bass - Morone saxatilis - Juvenile (Fledlin, Hatchlin, Weanlin) - 6 Fish - Sheepshead Cyprinodon varieatus - Juvenile (Fledlin, Hatchlin, Weanlin) - 8 to 15 mm Fish - Atlantic silverside - Menidia menidia 12. Maklumat ekoloi Date of issue /18 Tarikh keluaran

13 12. Maklumat ekoloi Kesan-Kesan Alam Sekitar Keekotoksikan akuatik Tiada kesan yan pentin atau bahaya kritikal yan diketahui. Nama produk/bahan Ujian Keputusan Spesis xylene - Akut LC ppm Air laut Crustacea - Daerblade rass shrimp - Palaemonetes puio - Adult - Akut LC kepada Akut LC kepada Akut LC kepada Akut LC Akut LC kepada Akut LC kepada Akut LC kepada Akut LC kepada Akut LC u/l Air laut - Akut LC kepada Akut LC50 00 kepada methylpentan-2-one - Akut LC kepada u/l Air tawar - Akut LC kepada u/l Air Ikan - Rainbow trout,donaldson trout - Oncorhynchus mykiss Ikan - Blueill - macrochirus Ikan - Blueill - macrochirus Ikan - Fathead promelas - 1 hari mm Ikan - Blueill - macrochirus Ikan - Blueill - macrochirus Ikan - Blueill - macrochirus Ikan - Blueill - macrochirus Crustacea - Daerblade rass shrimp - Palaemonetes puio Ikan - Rainbow trout,donaldson trout - Oncorhynchus mykiss Ikan - Rainbow trout,donaldson trout - Oncorhynchus mykiss Ikan - Fathead promelas - 1 hari - 20 mm Ikan - Fathead Pendedahan Date of issue /18 Tarikh keluaran

14 12. Maklumat ekoloi - Akut LC kepada u/l Air tawar tawar promelas - Juvenile (Fledlin, Hatchlin, Weanlin) - 28 kepada 4 hari ethylbenzene - Akut EC kepada Akut EC kepada Akut EC kepada Akut EC kepada Akut LC kepada 200 m/l Air tawar - Akut LC kepada 290 ppm Air laut - Akut LC kepada Akut LC u/l Air laut - Akut LC kepada Akut LC kepada Akut LC kepada Akut LC Akut LC kepada Akut LC kepada Ikan - Fathead promelas - 29 hari - 21 mm Crustacea - Brine shrimp - Artemia sp. - Nauplii Crustacea - Brine shrimp - Artemia sp. - Nauplii Dafnia - Water mana - Neonate Dafnia - Water mana - Neonate Ikan - Blueill - macrochirus - Youn of the year kepada 1.2 Ikan - Sheepshead Cyprinodon varieatus - Juvenile (Fledlin, Hatchlin, Weanlin) - 8 kepada 15 mm Dafnia - Water mana Crustacea - Duneness or edible crab - Cancer maister - Zoea Dafnia - Water mana - Neonate Dafnia - Water mana - Neonate Crustacea - Brine shrimp - Artemia sp. - Nauplii Ikan - Guppy - Poecilia reticulata Ikan - Fathead promelas - 0 hari Ikan - Fathead Date of issue /18 Tarikh keluaran

15 12. Maklumat ekoloi - Akut LC kepada Akut LC50 >5200 u/l Air laut - Akut LC kepada 5700 u/l Air laut - Akut LC Akut LC50 4. kepada 4.7 ul/l Air laut - Kronik NOEC 88 ppm Air laut - Kronik NOEC 00 u/l Air laut promelas - 28 kepada 2 hari mm Crustacea - Brine shrimp - Artemia sp. - Nauplii Crustacea - Opossum shrimp - Americamysis bahia Ikan - Atlantic silverside - Menidia menidia Ikan - Rainbow trout,donaldson trout - Oncorhynchus mykiss Ikan - Striped bass - Morone saxatilis - Juvenile (Fledlin, Hatchlin, Weanlin) - 6 Ikan - Sheepshead Cyprinodon varieatus - Juvenile (Fledlin, Hatchlin, Weanlin) - 8 kepada 15 mm Ikan - Atlantic silverside - Menidia menidia 1. Disposal considerations Waste must be disposed of in accordance with federal, state and local environmental control reulations. Methods of disposal The eneration of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal leislation and any reional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. 1. Maklumat pembuanan Sisa harus dibuankan menikut peraturan persekutuan, neeri dan kawalan alam sekitar tempatan. Kaedah pembuanan Penhasilan sisa perlulah dielakkan atau diminimumkan sekiranya boleh. Bekas atau pelapik koson munkin menanduni sisa-sisa produk. Bahan ini dan bekasnya hendaklah dilupuskan denan cara yan selamat. Pembuanan lebihan dan hasilan yan tidak boleh dikitar semula melalui kontraktor pelupusan sisa yan berlesen. Pelupusan produk ini, larutan dan sebaran produk sampinan perlulah pada setiap masa mematuhi keperluan perlindunan alam sekitar dan perundanan pelupusan sisa dan sebaran keperluan pihak berkuasa serantau tempatan. Elakkan penyebaran bahan tertumpah dan aliran dan bersentuh denan tanah, jalan air, lonkan dan pembentun. Date of issue /18 Tarikh keluaran

16 14. Transport information International transport reulations ADR UN number ADR Class Classification code Packin roup Proper shippin name Label No. IMDG UN number IMDG Class Packin roup Proper shippin name Emerency schedules (EmS) Marine pollutant Label no. IATA UN number IATA Class Packin roup Proper shippin name Label no. UN126 F1 III Paint UN126 III Paint F-E, S-E No. UN126 III Paint 14. Maklumat penankutan Peraturan penankutan antarabansa ADR Nombor UN Kelas ADR Kod klasifikasi Kumpulan Pembunkusan Nama penhantaran betul Label No. IMDG UN number IMDG Class UN126 F1 III Paint UN126 Packin roup Proper shippin name Emerency schedules (EmS) Marine pollutant Label no. IATA UN number IATA Class Packin roup Proper shippin name Label no. III Paint F-E, S-E No. UN126 III Paint Date of issue /18 Tarikh keluaran

17 15. Reulatory information EU reulations Hazard symbol or symbols Risk phrases Safety phrases Contains Product use Hihly flammable, Harmful R11- Hihly flammable. R20/21- Harmful by inhalation and in contact with skin. R6/8- Irritatin to eyes and skin. R4- May cause sensitization by skin contact. S6/7- Wear suitable protective clothin and loves. reaction product bisphenol-a-(epichlorhydrin) and epoxy resin (number averae molecular weiht ) xylene Industrial applications. 15. Maklumat penawalan Peraturan-Peraturan EU Simbol bahaya Unkapan risiko Unkapan keselamatan Menanduni Keunaan Produk Sanat mudah terbakar, Memudaratkan R11- Sanat mudah terbakar. R20/21- Memudaratkan melalui penyedutan dan jika bersentuhan denan kulit. R6/8- Merensa kepada mata dan kulit. R4- Boleh menyebakan pemekaan melalui sentuhan kulit. S6/7- Pakailah pakaian perlindunan dan sarun tanan yan sesuai. reaction product bisphenol-a-(epichlorhydrin) and epoxy resin (number averae molecular weiht ) xylene Aplikasi perindustrian. 16. Other information History Date of printin Date of issue Date of previous issue Version 1.01 Indicates information that has chaned from previously issued version. Notice to reader The information contained in this Safety Data Sheet corresponds to our level of knowlede at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the product data sheet prior to any use and processin. 16. Maklumat lain Sejarah Tarikh cetakan Tarikh keluaran Tarikh Keluaran Terdahulu Versi 1.01 Menunjukkan maklumat yan telah berubah daripada versi isu terdahulu. Notis kepada pembaca Date of issue /18 Tarikh keluaran

18 16. Maklumat lain Informasi yan terkandun di dalam Risalah Data Keselamatan Kimia ini adalah sejajar denan tahap penetahuan kami pada masa ianya diterbitkan. Sebaran jaminan adalah dikecualikan. Syarat - syarat Penjualan Am kami yan terkini tertakluk. Sila rujuk Risalah Data Teknikal kami sebelum sebaran penunaan dan pemprosesan. Date of issue /18 Tarikh keluaran